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Find link is a tool written by Edward Betts.searching for migratory insertion 14 found (49 total)
alternate case: Migratory insertion
Cativa process
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iodide. After ligand exchange (iodide for carbon monoxide), the migratory insertion of carbon monoxide into the iridium-carbon bond, step (3) to (4)Hydrovinylation (814 words) [view diff] case mismatch in snippet view article find links to article
Hydroalkenylation of Styrenes with alpha-Olefins: Regioselective Migratory Insertion Controlled by a Nickel/N-Heterocyclic Carbene". Angew. Chem. IntLarock indole synthesis (1,203 words) [view diff] exact match in snippet view article find links to article
Pd(II). The alkyne coordinates to the Pd(II) by ligand exchange. A migratory insertion causes the alkyne to undergo regioselective syn-insertion into arylpalladiumOrganocobalt chemistry (1,095 words) [view diff] exact match in snippet view article find links to article
Coordination of another equivalent of CO give alkyl tetracarbonyl (step 4). Migratory insertion of CO gives the 16e acyl in step 5. In step 6, oxidative additionWilkinson's catalyst (1,227 words) [view diff] exact match in snippet view article find links to article
addition of H2 to the metal. Subsequent π-complexation of alkene, migratory insertion (intramolecular hydride transfer or olefin insertion), and reductiveTris(pentafluorophenyl)borane (1,103 words) [view diff] exact match in snippet view article
site on the zirconium allows for coordination of alkenes, whereupon migratory insertion into the remaining carbon-methyl ligand gives rise to a propyl ligandMurai reaction (1,146 words) [view diff] exact match in snippet view article find links to article
decoordination of the ketone results in complex 4 which then undergoes migratory insertion of ethylene into the hydride to give 5. Following oxidative additionHydrogenation (4,117 words) [view diff] exact match in snippet view article find links to article
LnMH2(CH2=CHR) transfer of one hydrogen atom from the metal to carbon (migratory insertion): LnMH2(CH2=CHR) → LnM(H)(CH2−CH2R) transfer of the second hydrogenMetal-catalysed hydroboration (1,811 words) [view diff] exact match in snippet view article find links to article
coordination of the alkene to the 16e− Rh(III) hydride complex. Subsequent migratory insertion of the alkene into the rhodium-hydride bond can give two regioisomericJohn P. Wolfe (1,535 words) [view diff] exact match in snippet view article find links to article
palladium(aryl)amido complex 2, which then undergoes intramolecular syn-migratory insertion of the alkene into the Pd-N bond to yield 3 to generate the productFausto Calderazzo (807 words) [view diff] exact match in snippet view article find links to article
discovered V(CO)6. He made seminal contributions to the mechanism of migratory insertion reactions, with emphasis on the stereochemical course of the carbonylationCascade reaction (2,852 words) [view diff] exact match in snippet view article find links to article
naphthyl group into the olefin to yield intermediate 79. A second migratory insertion into the remaining olefin group followed by a β-elimination thenCarboboration (1,649 words) [view diff] exact match in snippet view article find links to article
is delivered to the substrate: whether the C–C bond is formed via migratory insertion from the catalyst (inner sphere) or attack by an external nucleophileTransition metal catalytic asymmetric dearomatization reactions (2,698 words) [view diff] exact match in snippet view article find links to article
step. This study found that the reaction was determined through the migratory insertion of the alkyne; however in contrast, the final product is obtained