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searching for Migratory insertion 13 found (49 total)

Cativa process (380 words) [view diff] exact match in snippet view article find links to article

iodide. After ligand exchange (iodide for carbon monoxide), the migratory insertion of carbon monoxide into the iridium-carbon bond, step (3) to (4)

Hydrovinylation (806 words) [view diff] case mismatch in snippet view article find links to article

Hydroalkenylation of Styrenes with alpha-Olefins: Regioselective Migratory Insertion Controlled by a Nickel/N-Heterocyclic Carbene". Angew. Chem. Int

Larock indole synthesis (1,203 words) [view diff] exact match in snippet view article find links to article

Pd(II). The alkyne coordinates to the Pd(II) by ligand exchange. A migratory insertion causes the alkyne to undergo regioselective syn-insertion into arylpalladium

Organocobalt chemistry (1,095 words) [view diff] exact match in snippet view article find links to article

Coordination of another equivalent of CO give alkyl tetracarbonyl (step 4). Migratory insertion of CO gives the 16e acyl in step 5. In step 6, oxidative addition

Tris(pentafluorophenyl)borane (1,100 words) [view diff] exact match in snippet view article

site on the zirconium allows for coordination of alkenes, whereupon migratory insertion into the remaining carbon-methyl ligand gives rise to a propyl ligand

Wilkinson's catalyst (1,209 words) [view diff] exact match in snippet view article find links to article

addition of H2 to the metal. Subsequent π-complexation of alkene, migratory insertion (intramolecular hydride transfer or olefin insertion), and reductive

Murai reaction (1,146 words) [view diff] exact match in snippet view article find links to article

decoordination of the ketone results in complex 4 which then undergoes migratory insertion of ethylene into the hydride to give 5. Following oxidative addition

Hydrogenation (4,109 words) [view diff] exact match in snippet view article find links to article

LnMH2(CH2=CHR) transfer of one hydrogen atom from the metal to carbon (migratory insertion): LnMH2(CH2=CHR) → LnM(H)(CH2−CH2R) transfer of the second hydrogen

Metal-catalysed hydroboration (1,811 words) [view diff] exact match in snippet view article find links to article

coordination of the alkene to the 16e− Rh(III) hydride complex. Subsequent migratory insertion of the alkene into the rhodium-hydride bond can give two regioisomeric

John P. Wolfe (1,535 words) [view diff] exact match in snippet view article find links to article

palladium(aryl)amido complex 2, which then undergoes intramolecular syn-migratory insertion of the alkene into the Pd-N bond to yield 3 to generate the product

Fausto Calderazzo (807 words) [view diff] exact match in snippet view article find links to article

discovered V(CO)6. He made seminal contributions to the mechanism of migratory insertion reactions, with emphasis on the stereochemical course of the carbonylation

Cascade reaction (2,852 words) [view diff] exact match in snippet view article find links to article

naphthyl group into the olefin to yield intermediate 79. A second migratory insertion into the remaining olefin group followed by a β-elimination then

Carboboration (1,642 words) [view diff] exact match in snippet view article find links to article

is delivered to the substrate: whether the C–C bond is formed via migratory insertion from the catalyst (inner sphere) or attack by an external nucleophile