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Longer titles found: Electrochemical reaction mechanism (view), European Union rapid reaction mechanism (view)

searching for Reaction mechanism 373 found (814 total)

alternate case: reaction mechanism

Dieckmann condensation (286 words) [view diff] exact match in snippet view article find links to article

Dieckmann condensation reaction mechanism for the example given

Doebner reaction (361 words) [view diff] exact match in snippet view article find links to article

reaction serves as an alternative to the Pfitzinger reaction. The reaction mechanism is not exactly known; two proposals are presented here. One possibility

Nierenstein reaction (354 words) [view diff] exact match in snippet view article find links to article

The Nierenstein reaction mechanism

Baeyer–Emmerling indole synthesis (165 words) [view diff] exact match in snippet view article find links to article

Baeyer-Emmerling indole reaction mechanism

Gewald reaction (334 words) [view diff] exact match in snippet view article find links to article

reaction is named after the German chemist Karl Gewald (born 1930). The reaction mechanism of the Gewald reaction was elucidated 30 years after the reaction

Prévost reaction (210 words) [view diff] no match in snippet view article find links to article

The Prévost reaction is chemical reaction in which an alkene is converted by iodine and the silver salt of benzoic acid to a vicinal diol with anti stereochemistry

Bohn–Schmidt reaction (408 words) [view diff] exact match in snippet view article find links to article

2-aminoanthraquinone and thus laid the basis for a new group of dyes. The postulated reaction mechanism is explained below for the example of 2-hydroxyanthraquinone: The

Madelung synthesis (1,278 words) [view diff] exact match in snippet view article find links to article

substitution) because of vigorous reaction conditions. A detailed reaction mechanism for the Madelung synthesis follows. The reaction begins with the extraction

Chan rearrangement (192 words) [view diff] no match in snippet view article find links to article

The Chan rearrangement is a chemical reaction that involves rearranging an acyloxy acetate (1) in the presence of a strong base to a 2-hydroxy-3-keto-ester

Reissert indole synthesis (251 words) [view diff] no match in snippet view article find links to article

The Reissert indole synthesis is a series of chemical reactions designed to synthesize indole or substituted-indoles (4 and 5) from ortho-nitrotoluene

Urech hydantoin synthesis (77 words) [view diff] no match in snippet view article find links to article

The Urech hydantoin synthesis is the chemical reaction of amino acids with potassium cyanate and hydrochloric acid to give hydantoins. Bucherer–Bergs reaction

Algar–Flynn–Oyamada reaction (214 words) [view diff] no match in snippet view article find links to article

The Algar–Flynn–Oyamada reaction is a chemical reaction whereby a chalcone undergoes an oxidative cyclization to form a flavonol. There are several possible

McFadyen–Stevens reaction (280 words) [view diff] no match in snippet view article find links to article

The McFadyen–Stevens reaction is a chemical reaction best described as a base-catalyzed thermal decomposition of acylsulfonylhydrazides to aldehydes.[1][2]

Bobbitt reaction (200 words) [view diff] no match in snippet view article find links to article

The Bobbitt reaction is a name reaction in organic chemistry. It is named after the American chemist James M. Bobbitt. The reaction allows the synthesis

Bamberger rearrangement (331 words) [view diff] no match in snippet view article find links to article

The Bamberger rearrangement is the chemical reaction of phenylhydroxylamines with strong aqueous acid, which will rearrange to give 4-aminophenols. It

Lossen rearrangement (339 words) [view diff] no match in snippet view article find links to article

The Lossen rearrangement is the conversion of a hydroxamate ester to an isocyanate. Typically O-acyl, sulfonyl, or phosphoryl O-derivative are employed

Von Braun amide degradation (219 words) [view diff] no match in snippet view article find links to article

The von Braun amide degradation is the chemical reaction of a monosubstituted amide with phosphorus pentachloride or thionyl chloride to give a nitrile

Hemetsberger indole synthesis (172 words) [view diff] no match in snippet view article find links to article

The Hemetsberger indole synthesis (also called the Hemetsberger–Knittel synthesis) is a chemical reaction that thermally decomposes a 3-aryl-2-azido-propenoic

Kowalski ester homologation (135 words) [view diff] no match in snippet view article find links to article

The Kowalski ester homologation is a chemical reaction for the homologation of esters. This reaction was designed as a safer alternative to the Arndt–Eistert

Pfitzinger reaction (244 words) [view diff] no match in snippet view article find links to article

The Pfitzinger reaction (also known as the Pfitzinger-Borsche reaction) is the chemical reaction of isatin with base and a carbonyl compound to yield substituted

Fritsch–Buttenberg–Wiechell rearrangement (385 words) [view diff] no match in snippet view article find links to article

The Fritsch–Buttenberg–Wiechell rearrangement, named for Paul Ernst Moritz Fritsch (1859–1913), Wilhelm Paul Buttenberg, and Heinrich G. Wiechell, is a

Corey–Kim oxidation (481 words) [view diff] exact match in snippet view article find links to article

The reaction mechanism of Corey–Kim oxidation

Zinin reaction (318 words) [view diff] no match in snippet view article find links to article

Zinin reaction or Zinin reduction involves reduction of nitro aromatic compounds to the amines using sodium sulfide. It is used to convert nitrobenzenes

Pomeranz–Fritsch reaction (351 words) [view diff] no match in snippet view article find links to article

The Pomeranz–Fritsch reaction, also named Pomeranz–Fritsch cyclization, is a named reaction in organic chemistry. It is named after Paul Fritsch (1859–1913)

Carroll rearrangement (461 words) [view diff] exact match in snippet view article find links to article

reaction mechanism

Ferrier carbocyclization (684 words) [view diff] exact match in snippet view article find links to article

Several reviews have been published. Ferrier proposed the following reaction mechanism: In this mechanism, the terminal olefin undergoes hydroxymercuration

Schmidt reaction (909 words) [view diff] exact match in snippet view article find links to article

which after deprotonation loses carbon dioxide to the amine. In the reaction mechanism for the Schmidt reaction of ketones, the carbonyl group is activated

Bouveault aldehyde synthesis (290 words) [view diff] no match in snippet view article find links to article

The Bouveault aldehyde synthesis (also known as the Bouveault reaction) is a one-pot substitution reaction that replaces an alkyl or aryl halide with a

Hammick reaction (459 words) [view diff] no match in snippet view article find links to article

The Hammick reaction, named after Dalziel Hammick, is a chemical reaction in which the thermal decarboxylation of α-picolinic (or related) acids in the

Yamaguchi esterification (270 words) [view diff] no match in snippet view article find links to article

The Yamaguchi esterification is the chemical reaction of an aliphatic carboxylic acid and 2,4,6-trichlorobenzoyl chloride (TCBC, Yamaguchi reagent) to

Kolbe–Schmitt reaction (372 words) [view diff] exact match in snippet view article find links to article

reaction. English title: 'On the syntheses of salicylic acid'; German title "Ueber Synthese der Salicylsäure". [2] An animation of the reaction mechanism.

Fischer indole synthesis (449 words) [view diff] no match in snippet view article find links to article

The Fischer indole synthesis is a chemical reaction that produces the aromatic heterocycle indole from a (substituted) phenylhydrazine and an aldehyde

Heck reaction (1,355 words) [view diff] case mismatch in snippet view article find links to article

Heck Reaction Mechanism

Étard reaction (660 words) [view diff] exact match in snippet view article find links to article

Alexandre Léon Étard (5 January 1852, Alençon – 1 May 1910). The reaction mechanism proceeds via an ene reaction with chromyl chloride, forming the precipitated

Dakin–West reaction (575 words) [view diff] exact match in snippet view article find links to article

This reaction should not be confused with the Dakin reaction. The reaction mechanism involves the acylation and activation of the acid 1 to the mixed anhydride

Bucherer–Bergs reaction (783 words) [view diff] exact match in snippet view article find links to article

Reaction mechanism for the Bucherer–Bergs reaction

Mutarotation (427 words) [view diff] exact match in snippet view article find links to article

Reaction mechanism for the interconversion of α and β anomers

Leimgruber–Batcho indole synthesis (473 words) [view diff] no match in snippet view article find links to article

The Leimgruber–Batcho indole synthesis is a series of organic reactions that produce indoles from o-nitrotoluenes 1.[1][2][3] The first step is the formation

Pschorr cyclization (391 words) [view diff] no match in snippet view article find links to article

The Pschorr cyclization is a name reaction in organic chemistry, which was named after its discoverer, the German chemist Robert Pschorr (1868-1930). It

Favorskii reaction (605 words) [view diff] no match in snippet view article find links to article

The Favorskii reaction is an organic chemistry reaction between an alkyne and a carbonyl group, under basic conditions. The reaction was discovered in

Corey–Fuchs reaction (378 words) [view diff] no match in snippet view article find links to article

The Corey–Fuchs reaction, also known as the Ramirez–Corey–Fuchs reaction, is a series of chemical reactions designed to transform an aldehyde into an alkyne

Demjanov rearrangement (755 words) [view diff] no match in snippet view article find links to article

The Demjanov rearrangement is the chemical reaction of primary amines with nitrous acid to give rearranged alcohols.[1][2][3] It involves substitution

Blaise ketone synthesis (470 words) [view diff] no match in snippet view article find links to article

The Blaise ketone synthesis (named after Edmond Blaise) is the chemical reaction of acid chlorides with organozinc compounds to give ketones.[1][2] The

Boord olefin synthesis (209 words) [view diff] exact match in snippet view article find links to article

alkoxy group is a poor leaving group and therefore an E1cB elimination reaction mechanism is proposed. The original publication describes the organic synthesis

Reimer–Tiemann reaction (796 words) [view diff] no match in snippet view article find links to article

The Reimer–Tiemann reaction is a chemical reaction used for the ortho-formylation of phenols. with the simplest example being the conversion of phenol

Bouveault–Blanc reduction (736 words) [view diff] no match in snippet view article find links to article

The Bouveault–Blanc reduction is a chemical reaction in which an ester is reduced to primary alcohols using absolute ethanol and sodium metal. It was first

Biginelli reaction (1,074 words) [view diff] exact match in snippet view article find links to article

antagonists. Including highly selective tricyclic compounds. The reaction mechanism of the Biginelli reaction is a series of bimolecular reactions leading

Prilezhaev reaction (844 words) [view diff] exact match in snippet view article find links to article

(14): 3385–3386. doi:10.1021/ja963656u. Most textbooks depict the reaction mechanism using only four curly arrows, so that the O–H bond is used as the

Piancatelli rearrangement (674 words) [view diff] no match in snippet view article find links to article

In 1976, the Italian chemist, Giovanni Piancatelli and coworkers developed a new method to synthesize 4-hydroxycyclopentenone derivatives from 2-furylcarbinols

1,2-rearrangement (652 words) [view diff] no match in snippet view article find links to article

A 1,2-rearrangement or 1,2-migration or 1,2-shift or Whitmore 1,2-shift is an organic reaction where a substituent moves from one atom to another atom

Peterson olefination (727 words) [view diff] no match in snippet view article find links to article

The Peterson olefination (also called the Peterson reaction) is the chemical reaction of α-silyl carbanions (1 in diagram below) with ketones (or aldehydes)

McMurry reaction (758 words) [view diff] no match in snippet view article find links to article

The McMurry reaction is an organic reaction in which two ketone or aldehyde groups are coupled to form an alkene using a titanium chloride compound such

Aminolevulinic acid synthase (1,308 words) [view diff] exact match in snippet view article find links to article

Lysine acts as a general base during this mechanism,. In the detailed reaction mechanism, the hydronium atoms that are added in come from a variety of residues

Darzens reaction (717 words) [view diff] no match in snippet view article find links to article

The Darzens reaction (also known as the Darzens condensation or glycidic ester condensation) is the chemical reaction of a ketone or aldehyde with an α-haloester

Grignard reaction (1,099 words) [view diff] no match in snippet view article find links to article

The Grignard reaction (French: [ɡʁiɲaʁ]) is an organometallic chemical reaction in which, according to the classical definition, carbon alkyl, allyl, vinyl

Ozonolysis (1,743 words) [view diff] exact match in snippet view article find links to article

The reaction mechanism of ozonolysis.

Seyferth–Gilbert homologation (529 words) [view diff] no match in snippet view article find links to article

The Seyferth–Gilbert homologation is a chemical reaction of an aryl ketone 1 (or aldehyde) with dimethyl (diazomethyl)phosphonate 2 and potassium tert-butoxide

Bartoli indole synthesis (761 words) [view diff] exact match in snippet view article find links to article

difficult to do with the Leimgruber-Batcho indole synthesis. The reaction mechanism of the Bartoli indole synthesis is illustrated below using o-nitrotoluene

Wittig reaction (1,600 words) [view diff] exact match in snippet view article find links to article

Gilheany, Declan G. (2013). "The modern interpretation of the Wittig reaction mechanism". Chemical Society Reviews. 42 (16): 6670–96. doi:10.1039/c3cs60105f

Shapiro reaction (964 words) [view diff] no match in snippet view article find links to article

The Shapiro reaction or tosylhydrazone decomposition is an organic reaction in which a ketone or aldehyde is converted to an alkene through an intermediate

Ribose-phosphate diphosphokinase (1,500 words) [view diff] exact match in snippet view article find links to article

Experiments using oxygen 18 labelled water demonstrate that the reaction mechanism proceeds with the nucleophilic attack of the anomeric hydroxyl group

Arndt–Eistert reaction (1,002 words) [view diff] no match in snippet view article find links to article

In organic chemistry, the Arndt–Eistert reaction is the conversion of a carboxylic acid to its homologue. Named for the German chemists Fritz Arndt (1885–1969)

Jacobsen rearrangement (293 words) [view diff] exact match in snippet view article find links to article

sulfonic acid derived from a polyalkyl- or polyhalobenzene: The exact reaction mechanism is not completely clear, but evidence indicates that the rearrangement

FFC Cambridge process (856 words) [view diff] no match in snippet view article find links to article

The FFC Cambridge process is an electrochemical method for producing Titanium (Ti) from titanium oxide by electrolysis in molten calcium salts. A process

Debus–Radziszewski imidazole synthesis (351 words) [view diff] exact match in snippet view article find links to article

stage, this diimine condenses with the aldehyde: However, the actual reaction mechanism is not certain. This reaction is named after Heinrich Debus and Bronisław

Robinson–Gabriel synthesis (1,112 words) [view diff] no match in snippet view article find links to article

The Robinson–Gabriel synthesis is an organic reaction in which a 2-acylamino-ketone reacts intramolecularly followed by a dehydration to give an oxazole

Bamford–Stevens reaction (1,481 words) [view diff] exact match in snippet view article find links to article

Reaction mechanism follows the same steps as a standard organometallic coupling reaction.

Horner–Wadsworth–Emmons reaction (963 words) [view diff] no match in snippet view article find links to article

The Horner–Wadsworth–Emmons (HWE) reaction is a chemical reaction used in organic chemistry of stabilized phosphonate carbanions with aldehydes (or ketones)

Sharpless asymmetric dihydroxylation (2,175 words) [view diff] exact match in snippet view article find links to article

ligands to create an asymmetric environment around the oxidant. The reaction mechanism of the Sharpless dihydroxylation begins with the formation of the

Larock indole synthesis (1,203 words) [view diff] no match in snippet view article find links to article

The Larock indole synthesis is a heteroannulation reaction that uses palladium as a catalyst to synthesize indoles from an ortho-iodoaniline and a disubstituted

Bischler–Möhlau indole synthesis (759 words) [view diff] no match in snippet view article find links to article

The Bischler–Möhlau indole synthesis, also often referred to as the Bischler indole synthesis, is a chemical reaction that forms a 2-aryl-indole from an

Reformatsky reaction (1,269 words) [view diff] no match in snippet view article find links to article

The Reformatsky reaction (sometimes transliterated as Reformatskii reaction) is an organic reaction which condenses aldehydes or ketones with α-halo esters

Nozaki–Hiyama–Kishi reaction (664 words) [view diff] no match in snippet view article find links to article

The Nozaki–Hiyama–Kishi reaction is a nickel/chromium coupling reaction forming an alcohol from the reaction of an aldehyde with an allyl or vinyl halide

Lipid peroxidation (1,323 words) [view diff] no match in snippet view article find links to article

Lipid peroxidation, or lipid oxidation, is a complex chemical process that leads to oxidative degradation of lipids, resulting in the formation of peroxide

Mannich reaction (1,013 words) [view diff] no match in snippet view article find links to article

In organic chemistry, the Mannich reaction is a three-component organic reaction that involves the amino alkylation of an acidic proton next to a carbonyl

Williamson ether synthesis (1,339 words) [view diff] exact match in snippet view article find links to article

chemistry because it helped prove the structure of ethers. The general reaction mechanism is as follows: An example is the reaction of sodium ethoxide with

Julia olefination (1,302 words) [view diff] no match in snippet view article find links to article

The Julia olefination (also known as the Julia–Lythgoe olefination) is the chemical reaction used in organic chemistry of phenyl sulfones (1) with aldehydes

Ornithine decarboxylase (2,082 words) [view diff] exact match in snippet view article find links to article

Brooks HB, Phillips MA (December 1997). "Characterization of the reaction mechanism for Trypanosoma brucei ornithine decarboxylase by multiwavelength

Perkin reaction (385 words) [view diff] exact match in snippet view article find links to article

be used instead. Several reviews have been written. Clear from the reaction mechanism, the anhydride of aliphatic acid must contain at least 2 α-H for the

Name reaction (337 words) [view diff] exact match in snippet view article find links to article

Although systematic approaches for naming reactions based on the reaction mechanism or the overall transformation exist (such as the IUPAC Nomenclature

Dakin oxidation (1,519 words) [view diff] no match in snippet view article find links to article

The Dakin oxidation (or Dakin reaction) is an organic redox reaction in which an ortho- or para-hydroxylated phenyl aldehyde (2-hydroxybenzaldehyde or

Tebbe's reagent (907 words) [view diff] no match in snippet view article find links to article

Tebbe's reagent is the organometallic compound with the formula (C5H5)2TiCH2ClAl(CH3)2. It is used in the methylidenation of carbonyl compounds, that is

Curtius rearrangement (1,746 words) [view diff] no match in snippet view article find links to article

The Curtius rearrangement (or Curtius reaction or Curtius degradation), first defined by Theodor Curtius in 1885, is the thermal decomposition of an acyl

Amidophosphoribosyltransferase (1,568 words) [view diff] no match in snippet view article find links to article

Amidophosphoribosyltransferase (ATase), also known as glutamine phosphoribosylpyrophosphate amidotransferase (GPAT), is an enzyme responsible for catalyzing

Nucleophilic conjugate addition (625 words) [view diff] no match in snippet view article find links to article

Nucleophilic conjugate addition is a type of organic reaction. Ordinary nucleophilic additions or 1,2-nucleophilic additions deal mostly with additions

Tetrahydrocannabinolic acid synthase (1,303 words) [view diff] exact match in snippet view article find links to article

Reaction mechanism of THCA synthase. Modified from Shoyama et al. J. Mol. Bio. 2012.

CTP synthetase (1,977 words) [view diff] no match in snippet view article find links to article

CTP synthase is an enzyme (EC 6.3.4.2) involved in pyrimidine biosynthesis that interconverts UTP and CTP. CTP (cytidine triphosphate) synthetase catalyzes

Ornithine transcarbamylase (2,570 words) [view diff] exact match in snippet view article find links to article

Reaction mechanism:. The side-chain amino group of Orn attacks the carbonyl carbon of CP nucleophilically, left, to form a tetrahedral transition state

Vilsmeier–Haack reaction (447 words) [view diff] no match in snippet view article find links to article

The Vilsmeier–Haack reaction (also called the Vilsmeier reaction) is the chemical reaction of a substituted formamide (1) with phosphorus oxychloride and

Acetoacetate decarboxylase (2,274 words) [view diff] exact match in snippet view article find links to article

acetoacetate to yield acetone and carbon dioxide (Figure 1). The reaction mechanism proceeds via the formation of a Schiff base intermediate, which is

Sommelet reaction (221 words) [view diff] no match in snippet view article find links to article

The Sommelet reaction is an organic reaction in which a benzyl halide is converted to an aldehyde by action of hexamine and water. It is named after the

Birch reduction (2,144 words) [view diff] no match in snippet view article find links to article

The Birch reduction is an organic reaction that is used to convert arenes to 1,4-cyclohexadienes. The reaction is named after the Australian chemist Arthur

Strecker amino acid synthesis (1,069 words) [view diff] no match in snippet view article find links to article

The Strecker amino acid synthesis, also known simply as the Strecker synthesis, is a method for the synthesis of amino acids by the reaction of an aldehyde

Strecker amino acid synthesis (1,069 words) [view diff] no match in snippet view article find links to article

The Strecker amino acid synthesis, also known simply as the Strecker synthesis, is a method for the synthesis of amino acids by the reaction of an aldehyde

Heterogeneous metal catalyzed cross-coupling (2,307 words) [view diff] case mismatch in snippet view article find links to article

for Cross-Couplings in Continuous Flow-A Critical Assessment of the Reaction Mechanism and Metal Leaching". ChemCatChem. 6 (12): 3286–3305. doi:10.1002/cctc

Hydration reaction (651 words) [view diff] exact match in snippet view article find links to article

include phosphoric acid and several solid acids. Here an example reaction mechanism of the hydration of 1-methylcyclohexene to 1-methylcyclohexanol: Many

Japp–Klingemann reaction (468 words) [view diff] exact match in snippet view article find links to article

The Japp-Klingemann reaction mechanism

Porphobilinogen deaminase (1,617 words) [view diff] no match in snippet view article find links to article

Porphobilinogen deaminase (hydroxymethylbilane synthase, or uroporphyrinogen I synthase) is an enzyme (EC 2.5.1.61) that in humans is encoded by the HMBS

Gassman indole synthesis (356 words) [view diff] exact match in snippet view article find links to article

group is often removed using Raney nickel to give the 3-H-indole. The reaction mechanism of the Gassman indole synthesis is divided among three steps. The

3-Hydroxybutyrate dehydrogenase (1,132 words) [view diff] no match in snippet view article find links to article

In enzymology, 3-hydroxybutyrate dehydrogenase (EC 1.1.1.30) is an enzyme that catalyzes the chemical reaction: (R)-3-hydroxybutanoate + NAD+ ⇌ {\displaystyle

Robinson annulation (1,743 words) [view diff] no match in snippet view article find links to article

The Robinson annulation is a chemical reaction used in organic chemistry for ring formation. It was discovered by Robert Robinson in 1935 as a method to

Eschenmoser fragmentation (798 words) [view diff] exact match in snippet view article find links to article

The reaction mechanism of the Eschenmoser fragmentation

Thiolase (2,117 words) [view diff] exact match in snippet view article find links to article

carbon–carbon-bond formation via a thioester-dependent Claisen condensation reaction mechanism. Thiolases are a family of evolutionarily related enzymes. Two different

Dipeptidase 1 (1,794 words) [view diff] no match in snippet view article find links to article

Dipeptidase 1 (DPEP1), or renal dipeptidase, is a membrane-bound glycoprotein responsible for hydrolyzing dipeptides. It is found in the microsomal fraction

Hexadehydro Diels–Alder reaction (2,202 words) [view diff] no match in snippet view article find links to article

In organic chemistry, the hexadehydro-Diels–Alder (HDDA) reaction is an organic chemical reaction between a diyne (2 alkyne functional groups arranged

Pan amalgamation (602 words) [view diff] no match in snippet view article find links to article

The pan amalgamation process is a method to extract silver from ore, using salt and copper(II) sulfate in addition to mercury. The process was widely used

Friedel–Crafts reaction (1,988 words) [view diff] no match in snippet view article find links to article

The Friedel–Crafts reactions are a set of reactions developed by Charles Friedel and James Crafts in 1877 to attach substituents to an aromatic ring. Friedel–Crafts

Aza-Cope rearrangement (5,704 words) [view diff] exact match in snippet view article find links to article

atom distorts the sigmatropic rearrangement from a purely concerted reaction mechanism (as expected in the Cope rearrangement), to one with partial diradical/dipolar

Delépine reaction (279 words) [view diff] no match in snippet view article find links to article

The Delépine reaction is the organic synthesis of primary amines (4) by reaction of benzyl or alkyl halides (1) with hexamethylenetetramine (2) followed

Baylis–Hillman reaction (2,788 words) [view diff] no match in snippet view article find links to article

Berthe, Marie Christine; Caubere, Paul (1992). "The 'Baylis - Hillman Reaction' mechanism and applications revisited". Tetrahedron. 48 (31): 6371–6384. doi:10

Urate oxidase (1,755 words) [view diff] no match in snippet view article find links to article

The enzyme urate oxidase (UO), uricase or factor-independent urate hydroxylase, absent in humans, catalyzes the oxidation of uric acid to 5-hydroxyisourate:

Nicholas reaction (423 words) [view diff] no match in snippet view article find links to article

The Nicholas reaction is an organic reaction where a dicobalt octacarbonyl-stabilized propargylic cation is reacted with a nucleophile. Oxidative demetallation

6-phosphogluconate dehydrogenase deficiency (822 words) [view diff] no match in snippet view article find links to article

6-Phosphogluconate dehydrogenase deficiency (6PGD deficiency), or partial deficiency, is an autosomal hereditary disease characterized by abnormally low

Α-Galactosidase (3,140 words) [view diff] exact match in snippet view article find links to article

A double displacement reaction mechanism of α-GAL's catalytic action.The ligand (black) when bound in the active site of the enzyme (blue). The two key

Conrad–Limpach synthesis (1,046 words) [view diff] exact match in snippet view article find links to article

Perhaps the most important step (and the rate-determining step) in the reaction mechanism is the annulation of the molecule via an electrocyclic ring closing

Stephen aldehyde synthesis (471 words) [view diff] exact match in snippet view article find links to article

ammonium chloride is also produced. The following scheme shows the reaction mechanism: By addition of hydrogen chloride the used nitrile (1) reacts to its

Pyruvate carboxylase (2,678 words) [view diff] exact match in snippet view article find links to article

the individual catalytic and regulatory sites of the enzyme. The reaction mechanism can be subdivided into two partial reactions (see figure to the right)

Myeloperoxidase (1,879 words) [view diff] no match in snippet view article find links to article

Myeloperoxidase (MPO) is a peroxidase enzyme that in humans is encoded by the MPO gene on chromosome 17. MPO is most abundantly expressed in neutrophils

Sandmeyer reaction (1,738 words) [view diff] no match in snippet view article find links to article

The Sandmeyer reaction is a chemical reaction used to synthesize aryl halides from aryl diazonium salts using copper salts as reagents or catalysts. It

Cyanohydrin reaction (347 words) [view diff] no match in snippet view article find links to article

A cyanohydrin reaction is an organic chemical reaction in which an aldehyde or ketone reacts with a cyanide anion or a nitrile to form a cyanohydrin. This

Sodium methoxide (1,497 words) [view diff] no match in snippet view article find links to article

Sodium methoxide is the simplest sodium alkoxide. With the formula CH3ONa, it is a white solid, which is formed by the deprotonation of methanol. It is

Coenzyme Q – cytochrome c reductase (2,330 words) [view diff] exact match in snippet view article find links to article

membrane space (IM) and two electrons are passed to cytochrome c. The reaction mechanism for complex III (cytochrome bc1, coenzyme Q: cytochrome C oxidoreductase)

Carbonyl condensation (471 words) [view diff] no match in snippet view article find links to article

In organic chemistry, alkylimino-de-oxo-bisubstitution is the organic reaction of carbonyl compounds with amines to imines. The reaction name is based

Phosphoglucomutase (2,346 words) [view diff] no match in snippet view article find links to article

Phosphoglucomutase (EC 5.4.2.2) is an enzyme that transfers a phosphate group on an α-D-glucose monomer from the 1 to the 6 position in the forward direction

NADH peroxidase (1,069 words) [view diff] no match in snippet view article find links to article

In enzymology, a NADH peroxidase (EC 1.11.1.1) is an enzyme that catalyzes the chemical reaction NADH + H+ + H2O2 ⇌ {\displaystyle \rightleftharpoons }

Tropinone (1,032 words) [view diff] no match in snippet view article find links to article

Tropinone is an alkaloid, famously synthesised in 1917 by Robert Robinson as a synthetic precursor to atropine, a scarce commodity during World War I.

Schöllkopf method (444 words) [view diff] exact match in snippet view article find links to article

Reaction mechanism for the Schöllkopf method

Catellani reaction (1,156 words) [view diff] exact match in snippet view article find links to article

reaction to proceed at a reasonable rate. The generally accepted reaction mechanism, as outlined below, is intricate and believed to proceed via a series

Pulak Sengupta (794 words) [view diff] exact match in snippet view article find links to article

of Jadavpur University. He is known for his studies on grain-scale reaction mechanism and ultra-high temperature regional scale metamorphism and his studies

Michaelis–Arbuzov reaction (1,524 words) [view diff] no match in snippet view article find links to article

The Michaelis–Arbuzov reaction (also called the Arbuzov reaction) is the chemical reaction of a trivalent phosphorus ester with an alkyl halide to form

Rubottom oxidation (3,396 words) [view diff] no match in snippet view article find links to article

The Rubottom oxidation is a useful, high-yielding chemical reaction between silyl enol ethers and peroxyacids to give the corresponding α-hydroxy carbonyl

Fumarylacetoacetate hydrolase (2,540 words) [view diff] no match in snippet view article find links to article

Fumarylacetoacetase is an enzyme that in humans is encoded by the FAH gene located on chromosome 15. The FAH gene is thought to be involved in the catabolism

Dienone–phenol rearrangement (549 words) [view diff] exact match in snippet view article find links to article

present at the 4th position or the process is otherwise blocked. The reaction mechanism of 4,4-disubstituted cyclohexadienones to 3,4-disubstituted phenol

Zincke reaction (1,027 words) [view diff] no match in snippet view article find links to article

The Zincke reaction is an organic reaction, named after Theodor Zincke, in which a pyridine is transformed into a pyridinium salt by reaction with 2,4

Trimethylamine N-oxide reductase (1,527 words) [view diff] no match in snippet view article find links to article

Trimethylamine N-oxide reductase (TOR or TMAO reductase, EC 1.7.2.3) is a microbial enzyme that can reduce trimethylamine N-oxide (TMAO) into trimethylamine

Von Richter reaction (582 words) [view diff] no match in snippet view article find links to article

The von Richter reaction, also named von Richter rearrangement, is a name reaction in the organic chemistry. It is named after Victor von Richter, who

Negishi coupling (3,996 words) [view diff] exact match in snippet view article find links to article

on "palladium-catalyzed cross couplings in organic synthesis". The reaction mechanism is thought to proceed via a standard Pd catalyzed cross-coupling pathway

Dihydrolipoyl transacetylase (2,483 words) [view diff] exact match in snippet view article find links to article

is the second of the three enzyme components participating in the reaction mechanism for conversion of pyruvate into acetyl CoA, it is sometimes referred

Albright–Goldman oxidation (281 words) [view diff] exact match in snippet view article find links to article

proceed further to the carboxylic acid. The following figure shows the reaction mechanism: First, dimethyl sulfoxide (1) reacts with acetic anhydride to form

Hydrothermal explosion (916 words) [view diff] exact match in snippet view article find links to article

Hydrothermal explosions are caused by the same instability and chain reaction mechanism as geysers but are so violent that rocks and mud are expelled along

Criegee rearrangement (234 words) [view diff] exact match in snippet view article find links to article

because the p-nitrobenzoic acid anion is a good leaving group. The reaction mechanism has similarities with the Baeyer-Villiger oxidation where the intermediate

Passerini reaction (1,603 words) [view diff] case mismatch in snippet view article find links to article

Romain; Morokuma, Keiji (5 June 2015). "Revisiting the Passerini Reaction Mechanism: Existence of the Nitrilium, Organocatalysis of Its Formation, and

Lysine 2,3-aminomutase (549 words) [view diff] exact match in snippet view article find links to article

radical. This radical then acts as the "stable" radical carrier in the reaction mechanism which transfers the radical to the amino acid. The generalized reaction

Adenylosuccinate lyase (2,387 words) [view diff] exact match in snippet view article find links to article

β-elimination superfamily of enzymes and it proceeds through an E1cb reaction mechanism. The enzyme is a homotetramer with three domains in each monomer and

Tipson–Cohen reaction (727 words) [view diff] no match in snippet view article find links to article

The Tipson–Cohen reaction is a name reaction first discovered by Stuart Tipson and Alex Cohen at the National Bureau of Standards in Washington D.C. The

GPX4 (2,303 words) [view diff] no match in snippet view article find links to article

Glutathione peroxidase 4, also known as GPX4, is an enzyme that in humans is encoded by the GPX4 gene. GPX4 is a phospholipid hydroperoxidase that protects

Arthur Lapworth (393 words) [view diff] exact match in snippet view article find links to article

of the field of physical organic chemistry. His proposal for the reaction mechanism for the benzoin condensation is the basis for our modern-day understanding

Max Bodenstein (1,169 words) [view diff] exact match in snippet view article find links to article

his work in chemical kinetics. He was first to postulate a chain reaction mechanism and that explosions are branched chain reactions, later applied to

W. Wallace Cleland (819 words) [view diff] exact match in snippet view article find links to article

Wisconsin-Madison biochemistry professor. His research was concerned with enzyme reaction mechanism and enzyme kinetics, especially multiple-substrate enzymes. He was

Detailed balance (5,888 words) [view diff] exact match in snippet view article find links to article

the reaction mechanism and 0 if it is not; w r − {\displaystyle w_{r}^{-}} is the reaction rate for the reverse reaction if it is in the reaction mechanism

Atherton–Todd reaction (488 words) [view diff] exact match in snippet view article find links to article

methyl groups other alkyl or benzyl groups may be present. A possible reaction mechanism for the Atherton-Todd reaction is presented here for the example of

Improved Military Rifle (1,228 words) [view diff] no match in snippet view article find links to article

Improved military rifle propellants are tubular nitrocellulose propellants evolved from World War I through World War II for loading military and commercial

Tsuji–Wilkinson decarbonylation reaction (746 words) [view diff] exact match in snippet view article find links to article

CO above 200 °C, thereby regenerating RhCl(PPh3)n. Otherwise, the reaction mechanism halts by formation of this thermodynamically stable carbonyl complex

Cytochrome b6f complex (2,121 words) [view diff] no match in snippet view article find links to article

The cytochrome b6f complex (plastoquinol/plastocyanin reductase or plastoquinol/plastocyanin oxidoreductase; EC 7.1.1.6) is an enzyme found in the thylakoid

Kharasch addition (414 words) [view diff] exact match in snippet view article find links to article

value because of narrow substrate scope and demanding conditions. The reaction mechanism involves free radicals of the general formula CXCl2 (X = Cl, H). For

Lactoylglutathione lyase (4,553 words) [view diff] exact match in snippet view article find links to article

glyoxalase I is its inconsistent stereospecificity. The first step of its reaction mechanism (the abstraction of the proton from C1 and subsequent protonation

Glutathione reductase (3,709 words) [view diff] exact match in snippet view article find links to article

PMID 13271446. Massey V, Williams CH (November 1965). "On the reaction mechanism of yeast glutathione reductase". J. Biol. Chem. 240 (11): 4470–80

Combustion (6,216 words) [view diff] no match in snippet view article find links to article

Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen

Manganese peroxidase (1,476 words) [view diff] no match in snippet view article find links to article

In enzymology, a manganese peroxidase (EC 1.11.1.13) is an enzyme that catalyzes the chemical reaction 2 Mn(II) + 2 H+ + H2O2 ⇌ {\displaystyle \rightleftharpoons

Patio process (2,533 words) [view diff] no match in snippet view article find links to article

The patio process is a process for extracting silver from ore. Smelting, or refining, is most often necessary because silver is only infrequently found

SpyCatcher (2,514 words) [view diff] exact match in snippet view article find links to article

rate constant of 1.4 ± 0.4 × 103 M−1 s−1. It is postulated that the reaction mechanism proceeds by a nucleophilic attack of D556 from K470, mediated by E516

Bailey peptide synthesis (579 words) [view diff] exact match in snippet view article find links to article

or hydrogen atoms, R3 is the used amino acid or peptide ester: The reaction mechanism is not known in detail. Supposedly, the reaction begins with a nucleophilic

Kynureninase (939 words) [view diff] exact match in snippet view article find links to article

but does not hydrolyze the tautomerized Schiff base. The proposed reaction mechanism involves an attack of an enzyme nucleophile on the carbonyl carbon

Thorpe reaction (210 words) [view diff] exact match in snippet view article find links to article

The reaction mechanism of the Thorpe–Ziegler reaction

Sarcosine dehydrogenase (1,589 words) [view diff] exact match in snippet view article find links to article

Figure 1: First step in sarcosine dehydrogenase catalyzed reaction mechanism

Carbonyl α-substitution reactions (982 words) [view diff] no match in snippet view article find links to article

Alpha-substitution reactions occur at the position next to the carbonyl group, the α-position, and involve the substitution of an α hydrogen atom by an

Cysteine protease (1,278 words) [view diff] exact match in snippet view article find links to article

nucleophile (C denoting cysteine proteases). The first step in the reaction mechanism by which cysteine proteases catalyze the hydrolysis of peptide bonds

Photoelectrochemical cell (3,997 words) [view diff] no match in snippet view article find links to article

A "photoelectrochemical cell" is one of two distinct classes of device. The first produces electrical energy similarly to a dye-sensitized photovoltaic

Cyanopolyyne (1,361 words) [view diff] exact match in snippet view article find links to article

}}n=4,6,8} The reaction mechanism that occurs in the present day depends on the environment of the cloud. For the first reaction mechanism to take place

Oxalyl-CoA decarboxylase (1,145 words) [view diff] exact match in snippet view article find links to article

of formyl-CoA to regenerate the carbanion form of TPP. While the reaction mechanism is shared with other TPP-dependent enzymes, the residues found in

Fischer–Tropsch process (5,748 words) [view diff] no match in snippet view article find links to article

The Fischer–Tropsch process (FT) is a collection of chemical reactions that converts a mixture of carbon monoxide and hydrogen, known as syngas, into liquid

Aminocyclopropanecarboxylate oxidase (512 words) [view diff] no match in snippet view article find links to article

In enzymology, an aminocyclopropanecarboxylate oxidase (EC 1.14.17.4) is an enzyme that catalyzes the chemical reaction 1-aminocyclopropane-1-carboxylate

Tetrahedral carbonyl addition compound (2,329 words) [view diff] no match in snippet view article find links to article

A tetrahedral intermediate is a reaction intermediate in which the bond arrangement around an initially double-bonded carbon atom has been transformed

Chronoamperometry (1,878 words) [view diff] exact match in snippet view article find links to article

electrode processes of coupled chemical reactions, especially the reaction mechanism of organic electrochemistry. Anthracene in deoxygenated dimethylformamide

Hofmann–Löffler reaction (5,291 words) [view diff] no match in snippet view article find links to article

The Hofmann–Löffler reaction (also referred to as Hofmann–Löffler–Freytag reaction, Löffler–Freytag reaction, Löffler–Hofmann reaction, as well as Löffler's

Fumarase (1,482 words) [view diff] exact match in snippet view article find links to article

is a part of the class II fumarases. Figure 1 depicts the fumarase reaction mechanism. Two residues catalyze proton transfer and the ionization state of

Muconate lactonizing enzyme (2,057 words) [view diff] exact match in snippet view article find links to article

classes depending on whether it is bacterial or eukaryotic. The reaction mechanism that MLEs undergo are the reverse of beta-elimination in which the

Propagation (140 words) [view diff] exact match in snippet view article find links to article

dictionary. Propagation can refer to: Chain propagation in a chemical reaction mechanism Crack propagation, the growth of a crack during the fracture of materials

Barton reaction (2,125 words) [view diff] no match in snippet view article find links to article

The Barton reaction, also known as the Barton nitrite ester reaction, is a photochemical reaction that involves the photolysis of an alkyl nitrite to form

Pellizzari reaction (417 words) [view diff] exact match in snippet view article find links to article

Pellizzari reaction mechanism

Haruo Hosoya (321 words) [view diff] case mismatch in snippet view article find links to article

D. thesis, "Study on the Structure of Reactive Intermediates and Reaction Mechanism". After postdoc work abroad (Ann Arbor, Michigan, with prof. John

Nef isocyanide reaction (281 words) [view diff] no match in snippet view article find links to article

(2011-09-08). "A Density Functional Theory Study of the Nef-Isocyanide Reaction: Mechanism, Influence of Parameters and Scope". The Journal of Physical Chemistry

Carnitine 3-dehydrogenase (207 words) [view diff] exact match in snippet view article find links to article

Carnitindehydrogenase aus Pseudomonas aeruginosa" [Kinetic studies of the reaction mechanism of carnitine dehydrogenase of Pseudomonas aeruginosa]. Eur. J. Biochem

Jacobsen's catalyst (1,217 words) [view diff] no match in snippet view article find links to article

Jacobsen's catalyst is the common name for N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride, a coordination compound

Büchner–Curtius–Schlotterbeck reaction (1,953 words) [view diff] exact match in snippet view article find links to article

Initial steps in the Buchner–Curtius–Schlotterbeck reaction mechanism

Inulinase (1,225 words) [view diff] no match in snippet view article find links to article

Inulinase (EC 3.2.1.7 and EC 3.2.1.8, inulase, endoinulinase, endo-inulinase, exoinulinase, 2,1-β-D-fructan fructanohydrolase) is an enzyme with systematic

Methionine gamma-lyase (1,573 words) [view diff] exact match in snippet view article find links to article

γ-replacement, as well as deamination and γ-addition of L-vinylglycine. The reaction mechanism initially consists of the amino group of the substrate connected by

Selective chemistry of single-walled nanotubes (1,702 words) [view diff] no match in snippet view article find links to article

Selective chemistry of single-walled nanotubes is a field in Carbon nanotube chemistry devoted specifically to the study of functionalization of single-walled

Electrophilic substitution (244 words) [view diff] exact match in snippet view article find links to article

carbanion then quickly recombines with the electrophile. The SE2 reaction mechanism has a single transition state in which the old bond and the newly

Ulvan lyase (1,441 words) [view diff] exact match in snippet view article find links to article

of chemical bonds through an elimination reaction mechanism, rather than a substitution reaction mechanism (hydrolysis and oxidation). Ulvan lyase belongs

Dielectric spectroscopy (3,096 words) [view diff] exact match in snippet view article find links to article

microstructural characterization. Often, EIS reveals information about the reaction mechanism of an electrochemical process: different reaction steps will dominate

Charles Shoppee (391 words) [view diff] exact match in snippet view article find links to article

chemistry, with special reference to the investigation of problems of reaction mechanism, the establishment of the structures of the adreno-cortical hormones

Glycine cleavage system (1,267 words) [view diff] exact match in snippet view article find links to article

Kikuchi G (June 1973). "The glycine cleavage system: composition, reaction mechanism, and physiological significance". Mol. Cell. Biochem. 1 (2): 169–87

Amadori rearrangement (366 words) [view diff] exact match in snippet view article find links to article

Reactions in Organic Synthesis (Paperback) by Laszlo Kurti, BN 0-12-429785-4 Amadori Rearrangement, PowerPoint presentation detailing the reaction mechanism

Wolff–Kishner reduction (4,211 words) [view diff] exact match in snippet view article find links to article

Nikolai Kischner in 1911 and Ludwig Wolff in 1912. In general, the reaction mechanism first involves the in situ generation of a hydrazone by condensation

Protodeboronation (1,438 words) [view diff] no match in snippet view article find links to article

Protodeboronation, or protodeborylation is a chemical reaction involving the protonolysis of a boronic acid (or other organoborane compound) in which a

4EGI-1 (920 words) [view diff] no match in snippet view article find links to article

4EGI-1 is a synthetic chemical compound which has been found to interfere with the growth of certain types of cancer cells in vitro. Its mechanism of action

2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate synthase (888 words) [view diff] no match in snippet view article find links to article

2-Succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate synthase (EC 4.2.99.20), also known as SHCHC synthase is encoded by the menH gene in Escherichia

Bargellini reaction (1,048 words) [view diff] exact match in snippet view article find links to article

shown in the two possible scenarios below: Reaction mechanism for Bargellini reaction: The reaction mechanism proceeds when a sterically accessible ketone

Aminomethanol (185 words) [view diff] exact match in snippet view article find links to article

J.; Ćmikiewicz, Agnieszka (2018-02-01). "Characterisation of the reaction mechanism between ammonia and formaldehyde from the topological analysis of

Chen-Kao reaction (1,055 words) [view diff] no match in snippet view article find links to article

The Chen-Kao reaction (named after Ko Kuei Chen and Chung-Hsi Kao, Madison, Wisconsin 1926) is a chemical method for determining the presence of pseudoephedrine

Adenosine-phosphate deaminase (915 words) [view diff] no match in snippet view article find links to article

In enzymology, an adenosine-phosphate deaminase (EC 3.5.4.17) is an enzyme that catalyzes the chemical reaction 5'-AMP + H2O ⇌ {\displaystyle \rightleftharpoons

Carboxylate (602 words) [view diff] no match in snippet view article find links to article

with alkyl halides to form esters. The following reaction shows the reaction mechanism.: 398–9 The nucleophilicity of carboxylate ions is much weaker than

Eflornithine (3,966 words) [view diff] exact match in snippet view article find links to article

following the release of the second fluoride atom and transimination. The reaction mechanism of Trypanosoma brucei's ODC with ornithine was characterized by UV-VIS

2,3-dihydro-2,3-dihydroxybenzoate dehydrogenase (829 words) [view diff] no match in snippet view article find links to article

In enzymology, a 2,3-dihydro-2,3-dihydroxybenzoate dehydrogenase (EC 1.3.1.28) is an enzyme that catalyzes the chemical reaction 2,3-dihydro-2,3-dihydroxybenzoate

Krapcho decarboxylation (792 words) [view diff] exact match in snippet view article find links to article

The suggested reaction mechanism of α,α-disubstituted esters in the Krapcho decarboxylation reaction. R1, R2, and R3 are any carbon containing substituents

DNA-deoxyinosine glycosylase (1,301 words) [view diff] no match in snippet view article find links to article

DNA-deoxyinosine glycosylase (EC 3.2.2.15, DNA(hypoxanthine) glycohydrolase, deoxyribonucleic acid glycosylase, hypoxanthine-DNA glycosylase) is an enzyme

Glycerol-3-phosphate dehydrogenase (2,206 words) [view diff] case mismatch in snippet view article find links to article

GPD1 Reaction Mechanism

Dom (407 words) [view diff] exact match in snippet view article find links to article

manufacture of surfactants Directed ortho metalation, a chemical reaction mechanism Disk-on-a-module, an alternative to traditional computer hard disk

Glutamate 2,3-aminomutase (632 words) [view diff] exact match in snippet view article find links to article

3-aminomutase (LAM) and is thought to use similar cofactors and has a similar reaction mechanism. Experimental evidence suggests that glutamate 2,3 aminomutase uses

Fukuyama coupling (901 words) [view diff] exact match in snippet view article find links to article

cross-coupling reaction has been widely used in natural product synthesis, the reaction mechanism remains unclear. Various catalysts have been shown to promote reactivity

Iron–nickel clusters (2,075 words) [view diff] exact match in snippet view article find links to article

single to hundreds of atoms are used in catalysis, depending on the reaction mechanism. Additionally, Fe–Ni clusters, usually of one or two metal atoms,

Sobrerol (190 words) [view diff] exact match in snippet view article find links to article

dehydrated at the isopropyl) and sobrerol, making it possible to determine reaction mechanism and the structural properties of pinene and of other terpenes. Henderson

Carboxypeptidase (816 words) [view diff] exact match in snippet view article find links to article

A, Mlcochová P, Konvalinka J, Rulísek L, Lubkowski J (May 2009). "Reaction mechanism of glutamate carboxypeptidase II revealed by mutagenesis, X-ray crystallography

PFP (enzyme) (401 words) [view diff] exact match in snippet view article

(pyrophosphate). Properties of the enzyme from Entamoeba histolytica and its reaction mechanism". J. Biol. Chem. 251 (10): 2958–62. PMID 178659. Portal: Biology

Juliá–Colonna epoxidation (2,152 words) [view diff] no match in snippet view article find links to article

The Juliá–Colonna epoxidation is an asymmetric poly-leucine catalyzed nucleophilic epoxidation of electron deficient olefins in a triphasic system. The

Cannizzaro reaction (930 words) [view diff] exact match in snippet view article find links to article

Animated reaction mechanism

Indoleacetate decarboxylase (1,042 words) [view diff] no match in snippet view article find links to article

Indoleacetate decarboxylase (IAD) is a glycyl radical enzyme (therefore member of the GRE superfamily ) that catalyses the decarboxylation of indoleacetate

Enone–alkene cycloadditions (1,024 words) [view diff] exact match in snippet view article find links to article

allows closure to the cyclobutane. As an alternative a pericyclic reaction mechanism is proposed, in which after intersystem crossing a radical cation

Gamma-glutamyl carboxylase (1,001 words) [view diff] exact match in snippet view article find links to article

experimental structure is known for GGCX, limiting understanding of its reaction mechanism. Based on the fact that the two reactions are coupled, a computational

Off-stoichiometry thiol-ene polymer (1,751 words) [view diff] no match in snippet view article find links to article

An off-stoichiometry thiol-ene polymer is a polymer platform comprising off-stoichiometry thiol-enes (OSTE) and off-stoichiometry thiol-ene-epoxies (OSTE+)

Bilirubin oxidase (443 words) [view diff] exact match in snippet view article find links to article

PMID 21544308. Jones SM, Solomon EI (March 2015). "Electron transfer and reaction mechanism of laccases". Cellular and Molecular Life Sciences. 72 (5): 869–883

Ornithine (818 words) [view diff] exact match in snippet view article find links to article

Reaction mechanism:. The side-chain amino group of ornithine (Orn) attacks the carbonyl carbon of carbamoyl phosphate (CP) nucleophilically, left, to form

UTP—glucose-1-phosphate uridylyltransferase (2,932 words) [view diff] exact match in snippet view article find links to article

Suh SW, Hwang HY, Kim KK (April 2010). "Structural basis for the reaction mechanism of UDP-glucose pyrophosphorylase". Molecules and Cells. 29 (4): 397–405

Hypervalent molecule (4,483 words) [view diff] exact match in snippet view article find links to article

with the silane during hydrolysis and from this a binucleophilic reaction mechanism was proposed. Corriu and coworkers then measured the rates of hydrolysis

William H. Green (2,046 words) [view diff] case mismatch in snippet view article find links to article

engineering faculty at MIT. His research group developed the open-source Reaction Mechanism Generator software, which allows anyone to rapidly construct accurate

Petasis reagent (396 words) [view diff] exact match in snippet view article find links to article

or THF. The Tebbe reagent and the Petasis reagent share a similar reaction mechanism. The active olefinating reagent, Cp2TiCH2, is generated in situ upon

Dihydroxylation (1,996 words) [view diff] exact match in snippet view article find links to article

The Prevost reaction mechanism.

Prostaglandin G2 (143 words) [view diff] exact match in snippet view article find links to article

Donk; Tsai Ah-Lim; Kulmacz Richard J. (2002). "The cyclooxygenase reaction mechanism". Biochemistry. 41 (52): 15451–8. doi:10.1021/bi026938h. PMID 12501173

Tscherniak-Einhorn reaction (347 words) [view diff] no match in snippet view article find links to article

The Tscherniak-Einhorn reaction is an organic chemistry name reaction initiated in 1901 by Joseph Tscherniak. It involves the condensation of N- hydroxymethylphthalimide

Nitric oxide dioxygenase (2,188 words) [view diff] no match in snippet view article find links to article

Nitric oxide dioxygenase (EC 1.14.12.17) is an enzyme that catalyzes the conversion of nitric oxide (NO) to nitrate (NO− 3) . The net reaction for the

Taber's reagent (411 words) [view diff] exact match in snippet view article find links to article

and because the acyl group of the compound does not influence the reaction mechanism, the transformation of aldehydes to alkynes by Taber's reagent is

Diethylphosphite (851 words) [view diff] no match in snippet view article find links to article

György; Bálint, Erika (1 November 2012). "The Kabachnik–Fields Reaction: Mechanism and Synthetic Use". Molecules. 17 (11): 12821–12835. doi:10.3390/molecules171112821

Organic chemistry (4,203 words) [view diff] exact match in snippet view article find links to article

describe many common or useful reactions. Each reaction has a stepwise reaction mechanism that explains how it happens in sequence—although the detailed description

Wohl–Ziegler bromination (1,161 words) [view diff] exact match in snippet view article find links to article

reaction proceeds was proposed by Paul Goldfinger in 1953, and his reaction mechanism is one of two proposed pathways through which aliphatic, allylic,

Iodolactonization (1,072 words) [view diff] exact match in snippet view article find links to article

addition product can be rapidly produced as in bromolactonization. The reaction mechanism involves the formation of a positively charged halonium ion in a molecule

Methylmalonyl-CoA mutase (2,921 words) [view diff] exact match in snippet view article find links to article

studying the effects of MMA, and potential treatment methods. The MCM reaction mechanism begins with homolytic cleavage of AdoB12's C-Co(III) bond, the C and

Tryptophan 2,3-dioxygenase (2,094 words) [view diff] exact match in snippet view article find links to article

Thackray SJ, Handa S, Mowat CG, Raven EL (April 2011). "Structure and reaction mechanism in the heme dioxygenases". Biochemistry. 50 (14): 2717–2724. doi:10

Bischler–Napieralski reaction (836 words) [view diff] no match in snippet view article find links to article

mechanisms have appeared in the literature for the Bischler–Napieralski reaction. Mechanism I involves a dichlorophosphoryl imine-ester intermediate, while Mechanism

LISE++ (895 words) [view diff] exact match in snippet view article find links to article

blocks. Many physical phenomena are incorporated in this program, from reaction mechanism models, cross section systematics, electron stripping models, energy

Non-linear effects (3,183 words) [view diff] exact match in snippet view article find links to article

two decades, the study of non-linear effects has shown to elucidate reaction mechanism and guide in synthetic applications. A positive non-linear effect

Yttrium(III) nitrate (437 words) [view diff] exact match in snippet view article

PMID 25123272. Zhuang, R.F.; Qiu, J.B.; Zhu, Y.P. (1990). "A study on reaction mechanism in preparation of Y-Ba-Cu-O superconducting material from the thermoreaction

Anthraquinone (878 words) [view diff] exact match in snippet view article find links to article

the Soda-AQ processes. The anthraquinone is a redox catalyst. The reaction mechanism may involve single electron transfer (SET). The anthraquinone oxidizes

Maleate isomerase (1,480 words) [view diff] exact match in snippet view article find links to article

racemase members, though have not been fully understood. One proposed reaction mechanism of Nocardia farcinia maleate isomerase is as follows. At the active

Homogentisate 1,2-dioxygenase (602 words) [view diff] exact match in snippet view article find links to article

S2CID 6219553. Borowski T, Georgiev V, Siegbahn PE (Dec 2005). "Catalytic reaction mechanism of homogentisate dioxygenase: a hybrid DFT study". Journal of the

Ketone halogenation (812 words) [view diff] exact match in snippet view article find links to article

Reaction mechanism for the bromination of acetone while in the presence of acetic acid

Lowry protein assay (615 words) [view diff] exact match in snippet view article find links to article

acid and phosphomolybdic acid in the Folin–Ciocalteu reaction). The reaction mechanism is not well understood, but involves reduction of the Folin–Ciocalteu

Phenylsodium (981 words) [view diff] exact match in snippet view article find links to article

implicates radical intermediates like those proposed in the Wurtz-Fittig reaction mechanism. The reaction of phenylsodium with benzoyl chloride yields, after

Trehalase (1,512 words) [view diff] exact match in snippet view article find links to article

Nishimoto M, Ohguchi M, Kim D, et al. (November 2009). "Catalytic reaction mechanism based on alpha-secondary deuterium isotope effects in hydrolysis of

Maltase-glucoamylase (1,287 words) [view diff] exact match in snippet view article find links to article

hydrolase family 31. Molecular properties, substrate specificity, reaction mechanism, and comparison with family members of different origin". Plant Molecular

Glybuzole (872 words) [view diff] exact match in snippet view article find links to article

the final product of interest, glybuzole, is produced. Figure 2: Reaction mechanism of the bimolecular nucleophilic substitution reaction in the synthesis

Zinc nitride (744 words) [view diff] case mismatch in snippet view article find links to article

G. (2002), "The Electrochemistry of Zn3 N 2 and LiZnN - A Lithium Reaction Mechanism for Metal Nitride Electrodes", Journal of the Electrochemical Society

Acetyl-CoA carboxylase (2,988 words) [view diff] exact match in snippet view article find links to article

acetyl-CoA. In contrast to the BC domain, little is known about the reaction mechanism of CT. A proposed mechanism is the release of CO2 from biotin, which

Sonochemistry (1,812 words) [view diff] case mismatch in snippet view article find links to article

Piezo-Photocatalysis: Catalysts Classification and Modification Strategy, Reaction Mechanism, and Practical Application https://doi.org/10.1002/adfm.202005158

Hoesch reaction (310 words) [view diff] exact match in snippet view article find links to article

Hoesch reaction mechanism

Dihydroxyphenylglycine (506 words) [view diff] exact match in snippet view article find links to article

heme, flavin, or pterin cofactors. Chen et al suggest the following reaction mechanism to explain the reactivity of DpgC. This mechanism is supported by

Pyruvate synthase (971 words) [view diff] exact match in snippet view article find links to article

JC (1971). "Pyruvate-ferredoxin oxidoreductase. IV. Studies on the reaction mechanism". J. Biol. Chem. 246 (10): 3120–5. doi:10.1016/S0021-9258(18)62203-3

Bromous acid (1,013 words) [view diff] exact match in snippet view article find links to article

in a concentrated silver nitrate (AgNO3) resulted in a different reaction mechanism. From numbers of equivalent portions of acid bromine formed from the

Grigoriy Yablonsky (2,355 words) [view diff] exact match in snippet view article find links to article

components be constant. Then the law of mass action gives for this reaction mechanism a system of three ordinary differential equations that describe kinetics

Ion-selective electrode (663 words) [view diff] no match in snippet view article find links to article

the ion-selective electrode scope. Such an electrode has a "double reaction" mechanism - an enzyme reacts with a specific substance, and the product of

Terpentedienyl-diphosphate synthase (205 words) [view diff] exact match in snippet view article find links to article

switching, deuterium hyperlabeling, and 1H NMR spectroscopy. The reaction mechanism of a novel streptomyces diterpene cyclase". The Journal of Organic

Nucleotide pyrophosphatase/phosphodiesterase (1,857 words) [view diff] exact match in snippet view article find links to article

figure at right. The above three cases represent archetypes for the reaction mechanism, and the actual mechanism probably falls somewhere in between them

Uroporphyrinogen III decarboxylase (1,236 words) [view diff] exact match in snippet view article find links to article

Proposed reaction mechanism of uroporphyrinogen III decarboxylase

Ribonuclease (2,001 words) [view diff] exact match in snippet view article find links to article

"Bovine pancreatic ribonuclease: fifty years of the first enzymatic reaction mechanism". Biochemistry. 50 (37): 7835–41. doi:10.1021/bi201075b. PMC 3172371

Procollagen-proline dioxygenase (1,799 words) [view diff] exact match in snippet view article find links to article

combination, which yields hydroxyproline. As a consequence of the reaction mechanism, one molecule of 2-oxoglutarate is decarboxylated, forming succinate

Arginine:glycine amidinotransferase (1,603 words) [view diff] exact match in snippet view article find links to article

Transamidination reaction mechanism of AGAT

DNA ligase 3 (3,804 words) [view diff] exact match in snippet view article find links to article

ligases in eukaryotes. These enzymes utilize the same three step reaction mechanism; (i) formation of a covalent enzyme-adenylate intermediate; (ii) transfer

Kabachnik–Fields reaction (356 words) [view diff] no match in snippet view article find links to article

Keglevich, Gyorgy; Balint, Erika (2012). "The Kabachnik-Fields reaction: mechanism and synthetic use". Molecules. 17 (11): 12821–12835. doi:10.3390/molecules171112821

Biliverdin reductase (1,269 words) [view diff] exact match in snippet view article find links to article

higher concentrations of ROS. Rigney E, Mantle TJ (Nov 1988). "The reaction mechanism of bovine kidney biliverdin reductase". Biochimica et Biophysica Acta

Prostaglandin H2 (505 words) [view diff] exact match in snippet view article find links to article

Donk WA, Tsai AL, Kulmacz RJ (December 2002). "The cyclooxygenase reaction mechanism". Biochemistry. 41 (52): 15451–8. doi:10.1021/bi026938h. PMID 12501173

ALPL (2,059 words) [view diff] exact match in snippet view article find links to article

1074/jbc.M009250200. PMID 11124260. Kim EE, Wyckoff HW (March 1991). "Reaction mechanism of alkaline phosphatase based on crystal structures. Two-metal ion

Ethylbenzene hydroxylase (663 words) [view diff] exact match in snippet view article find links to article

histidine residue (His192) of the active site seems to be involved in the reaction mechanism. Kloer, Daniel P.; Hagel, Corina; Heider, Johann; Schulz, Georg E

Industrial catalysts (3,063 words) [view diff] exact match in snippet view article find links to article

reasons that companies keep doing research and catalyst development. A reaction mechanism for methanol synthesis has been suggested by Chinchen et al.: Today

Vinylcyclopropane (5+2) cycloaddition (1,523 words) [view diff] exact match in snippet view article

activated dienophiles such as tetracyanoethylene (TCNE). The proposed reaction mechanism involves an initial [2+2] cycloaddition between the vinylcyclopropane

Riboflavin synthase (1,086 words) [view diff] exact match in snippet view article find links to article

Huber R, Steinbacher S, Fischer M (October 2002). "Studies on the reaction mechanism of riboflavin synthase: X-ray crystal structure of a complex with

Varrentrapp reaction (446 words) [view diff] exact match in snippet view article find links to article

The fragmentation is induced by action of molten alkali. Below, the reaction mechanism is shown for the degradation of (E)-4-hexenoic acid. First, the carboxylic

Epoxide (2,319 words) [view diff] exact match in snippet view article find links to article

epoxidation of ethylene involves its reaction with oxygen. According to a reaction mechanism suggested in 1974 at least one ethylene molecule is totally oxidized

Dioxygenase (2,879 words) [view diff] exact match in snippet view article find links to article

either ferrous iron or ferric iron, respectively. While the exact reaction mechanism for the heme-dependent dioxygenases is still under debate, it is postulated

Ternary complex (354 words) [view diff] case mismatch in snippet view article find links to article

John; Shaw, William V. (2003-03-01). "Random-Order Ternary Complex Reaction Mechanism of Serine Acetyltransferase from Escherichia coli". Biochemistry.

Hydrohalogenation (788 words) [view diff] exact match in snippet view article find links to article

anti-Markovnikov addition fashion. Regiochemistry follows from the reaction mechanism, which exhibits halogen attack on the least-hindered unsaturated carbon

Oxazoline (1,757 words) [view diff] exact match in snippet view article find links to article

in refluxing chlorobenzene under anhydrous conditions. A precise reaction mechanism has never been proposed, although it is likely similar to the Pinner

SNI (159 words) [view diff] exact match in snippet view article find links to article

SNI may refer to: Substitution nucleophilic internal, a chemistry reaction mechanism Swedish Standard Industrial Classification, a Swedish economic classification

Corey–Link reaction (389 words) [view diff] exact match in snippet view article find links to article

Jocic–Reeve reaction using azide as the nucleophile. The multistep reaction mechanism begins with deprotonation of the alcohol, followed by the oxygen-anion

Beta-propeller phytase (2,119 words) [view diff] exact match in snippet view article find links to article

hexakisphosphate hydrolysis by Bacillus phytase: indication of a novel reaction mechanism". The Biochemical Journal. 352 Pt 3 (Pt 3): 623–8. doi:10.1042/bj3520623

Potassium nitrite (1,090 words) [view diff] exact match in snippet view article find links to article

induce vasorelaxation in isolated blood vessel studies, and the same reaction mechanism has been proposed to explain the biological action of nitrite. Potassium

Alwyn Davies (357 words) [view diff] case mismatch in snippet view article find links to article

Children 2 Awards RSC Ingold Lecturer 1992-3, RSC Medal for Organic Reaction Mechanism, 1989; Humboldt Prize, Freiburg University, 1994. Scientific career

Protease (2,799 words) [view diff] exact match in snippet view article find links to article

catalysis. Other enzyme residues (not shown) donate and accept hydrogens and electrostatically stabilise charge build-up along the reaction mechanism.

Carbon pentoxide (583 words) [view diff] exact match in snippet view article find links to article

irradiating cryogenically frozen carbon dioxide with 5 keV electrons. The reaction mechanism is by carbon tetroxide reacting with an oxygen atom. This reaction

Alkene carboamination (883 words) [view diff] exact match in snippet view article find links to article

carboamination reactions, including palladium, copper, and rhodium etc. The reaction mechanism varies with different transition metals. For palladium-catalyzed carboamination

Corey–Itsuno reduction (1,910 words) [view diff] exact match in snippet view article find links to article

published. Corey and coworkers originally proposed the following reaction mechanism to explain the selectivity obtained in the catalytic reduction. The

DeMayo reaction (156 words) [view diff] exact match in snippet view article find links to article

An animation of the reaction mechanism

Hydrostannylation (170 words) [view diff] exact match in snippet view article find links to article

substrates are alkynes. The typical stannane is tributyltin hydride. The reaction mechanism is assumed to operate via oxidative addition of the stannane to give

Randles–Sevcik equation (696 words) [view diff] exact match in snippet view article find links to article

x is close to 0.5 a reaction mechanism according to Randles Sevcik can be assigned. An example for this kind of reaction mechanism is the redox reaction

Alanine racemase (1,382 words) [view diff] case mismatch in snippet view article find links to article

Yoshimura, T., Mikami, B., Hayashi, H., Kagamiyama, H., Esaki, N. (2002) Reaction Mechanism of Alanine Racemase from Bacillus stearothermophilus: X-ray crystallographic

Guanidinium thiocyanate (476 words) [view diff] exact match in snippet view article find links to article

O; Masugi, T; Johnson, FH; Haneda, Y (March 1978). "Properties and reaction mechanism of the bioluminescence system of the deep-sea shrimp Oplophorus gracilorostris"

Guanidinium thiocyanate (476 words) [view diff] exact match in snippet view article find links to article

O; Masugi, T; Johnson, FH; Haneda, Y (March 1978). "Properties and reaction mechanism of the bioluminescence system of the deep-sea shrimp Oplophorus gracilorostris"

Dehydrogenase (2,153 words) [view diff] case mismatch in snippet view article find links to article

ISBN 9781118918401. Yoshikawa, Shinya; Shimada, Atsuhiro (2015-01-20). "Reaction Mechanism of Cytochrome c Oxidase". Chemical Reviews. 115 (4): 1936–1989. doi:10

Carbodiimide (1,599 words) [view diff] exact match in snippet view article find links to article

The reaction mechanism of amide formation using a carbodiimide

DeMayo reaction (156 words) [view diff] exact match in snippet view article find links to article

An animation of the reaction mechanism

Tropospheric ozone depletion events (997 words) [view diff] exact match in snippet view article find links to article

react with and destroy ozone. Due to the autocatalytic nature of the reaction mechanism, it has been called bromine explosion. It is still not fully understood

Gabaculine (725 words) [view diff] case mismatch in snippet view article find links to article

Perry; Ables, Robert; Hegeman, Adrian (Dec 29, 2006). Enzymatic Reaction Mechanism. New York: Oxford University Press Inc. pp. 262–263. ISBN 0195122585

Phosphoenolpyruvate carboxylase (1,883 words) [view diff] exact match in snippet view article find links to article

PMID 23443546. Fujita N, Izui K, Nishino T, Katsuki H (April 1984). "Reaction mechanism of phosphoenolpyruvate carboxylase. Bicarbonate-dependent dephosphorylation

4-Hydroxyphenylpyruvate dioxygenase (1,615 words) [view diff] case mismatch in snippet view article find links to article

Proposed Reaction Mechanism of HPPD

Malate dehydrogenase (2,401 words) [view diff] exact match in snippet view article find links to article

"Malate dehydrogenase of the cytosol. A kinetic investigation of the reaction mechanism and a comparison with lactate dehydrogenase". The Biochemical Journal

Hesperidin (1,228 words) [view diff] exact match in snippet view article find links to article

1.39. PMC 157303. PMID 12228452. Jez JM, Noel JP (January 2002). "Reaction mechanism of chalcone isomerase. pH dependence, diffusion control, and product

Serine protease (2,331 words) [view diff] exact match in snippet view article find links to article

serine protease reaction mechanism

NAS Award in Chemical Sciences (1,259 words) [view diff] exact match in snippet view article find links to article

(1992) For elucidation of fundamental questions of stereochemistry and reaction mechanism and for pioneering work on the synthesis and properties of designed

Transaldolase (831 words) [view diff] exact match in snippet view article find links to article

deprotonation by another active site residue, glutamate-106. The reaction mechanism is similar to the reverse reaction catalyzed by aldolase: The bond

Click chemistry (5,477 words) [view diff] exact match in snippet view article find links to article

catalyze the same reaction in 15 minutes with 91% yield. The first reaction mechanism proposed included one catalytic copper atom; but isotope, kinetic

Menthone (720 words) [view diff] exact match in snippet view article find links to article

example of the inference of an (almost) undetectable intermediate in a reaction mechanism accounting for the outcome of the reaction. Hirsch, Alan R. (2015-03-18)

Aspartoacylase (1,649 words) [view diff] exact match in snippet view article find links to article

Zhang C, Liu X, Xue Y (January 2012). "A general acid–general base reaction mechanism for human brain aspartoacylase: A QM/MM study". Computational and

Wulff–Dötz reaction (1,502 words) [view diff] exact match in snippet view article find links to article

The loss of CO is rate limiting making the investigation of this reaction mechanism difficult, since all subsequent steps occur rapidly. The alkyne then

Cystathionine gamma-lyase (1,225 words) [view diff] exact match in snippet view article find links to article

S2CID 6865017. Brzovic P, Litzenberger Holbrook E (January 1990). "Reaction mechanism of Escherichia coli cystathionine .gamma.-synthase: direct evidence

Adenine phosphoribosyltransferase (2,410 words) [view diff] exact match in snippet view article find links to article

adenine phosphoribosyltransferase from Giardia lamblia has a unique reaction mechanism and unusual substrate binding properties". The Journal of Biological

Aspartate transaminase (2,115 words) [view diff] exact match in snippet view article find links to article

Reaction mechanism for aspartate aminotransferase

Tertiary carbon (630 words) [view diff] case mismatch in snippet view article find links to article

Chemistry LibreTexts. 2016-11-30. Retrieved 2022-11-17. "7.4: SN1 Reaction Mechanism, Energy Diagram and Stereochemistry". Chemistry LibreTexts. 2021-12-15

Soda lime (1,310 words) [view diff] exact match in snippet view article find links to article

considered as a strong-base-catalysed, water-facilitated reaction. The reaction mechanism of carbon dioxide with soda lime can be decomposed in three elementary

D-octopine dehydrogenase (955 words) [view diff] exact match in snippet view article find links to article

OcDH and its substrates have led to the identification of the enzyme reaction mechanism. First, the Rossmann fold in Domain I of OcDH binds NADH. Binding

Mukaiyama aldol addition (958 words) [view diff] exact match in snippet view article find links to article

The reaction is also optimized for asymmetric synthesis. Below, the reaction mechanism is shown with R2 = H: In the cited example the Lewis acid TiCl4 is

Coenzyme A (2,526 words) [view diff] exact match in snippet view article find links to article

Coenzyme A is one of five crucial coenzymes that are necessary in the reaction mechanism of the citric acid cycle. Its acetyl-coenzyme A form is the primary

Propylene (1,930 words) [view diff] exact match in snippet view article find links to article

dehydrogenation of propane. This poses several advantages, as this reaction mechanism can occur at lower temperatures than conventional dehydrogenation

Dithioerythritol (296 words) [view diff] exact match in snippet view article find links to article

Hollocher, Thomas C. (November 1980). "Reduction of flavins by thiols. 1. Reaction mechanism from the kinetics of the attack and breakdown steps". Journal of the

Branched-chain alpha-keto acid dehydrogenase complex (1,781 words) [view diff] exact match in snippet view article find links to article

this side reaction has very little physiological significance. The reaction mechanism is as follows. Please note that any of several branched-chain α-ketoacids

Isoflavonoid synthase (197 words) [view diff] exact match in snippet view article find links to article

Hashim MF, Hakamatsuka T, Ebizuka Y, Sankawa U (October 1990). "Reaction mechanism of oxidative rearrangement of flavanone in isoflavone biosynthesis"

Ethylene oxide (11,529 words) [view diff] exact match in snippet view article find links to article

of acid catalysts, ethylene oxide dimerizes to afford dioxane: The reaction mechanism is as follows: The dimerization reaction is unselective. By-products

2,4 Dienoyl-CoA reductase (1,747 words) [view diff] exact match in snippet view article find links to article

X, Schulz H, Kim JJ (September 2003). "The crystal structure and reaction mechanism of Escherichia coli 2,4-dienoyl-CoA reductase". The Journal of Biological

Kumada coupling (2,238 words) [view diff] exact match in snippet view article find links to article

mechanism for the nickel-catalyzed coupling is limited. Indeed, the reaction mechanism is believed to proceed differently under different reaction conditions

Acetylcholinesterase inhibitor (2,384 words) [view diff] exact match in snippet view article find links to article

cholinesterase-TEPP complex (E–PX) and I is the TEPP concentration. The reaction mechanism and the formula above are both also compatible for other organophosphates

ACSM2B (434 words) [view diff] exact match in snippet view article find links to article

S2CID 8154380. Vessey DA, Kelley M (2001). "Characterization of the reaction mechanism for the XL-I form of bovine liver xenobiotic/medium-chain fatty acid:CoA

Dilute Russell's viper venom time (1,443 words) [view diff] case mismatch in snippet view article find links to article

Mukherjee AK, Ramos MJ, Fernandes PA (2023-07-10). "Unraveling the Reaction Mechanism of Russell's Viper Venom Factor X Activator: A Paradigm for the Reactivity

Oxidative coupling of methane (982 words) [view diff] exact match in snippet view article find links to article

This high reaction temperature establishes a secondary gas-phase reaction mechanism pathway, whereby the desired reaction of methyl radical coupling to

Alkyl cycloalkane (283 words) [view diff] exact match in snippet view article find links to article

electrophilic addition), but with the SN2 (cf. nucleophilic substitution) reaction mechanism. These reactions are both ring opening reactions and cleavage reactions

Proton (disambiguation) (302 words) [view diff] exact match in snippet view article

conductor, an electrolyte Proton-coupled electron transfer, a chemical reaction mechanism Proton spectrum, the nuclear magnetic resonance spectrum of the 1H

Pudovik reaction (356 words) [view diff] no match in snippet view article find links to article

Keglevich, György; Bálint, Erika (2012). "The Kabachnik-Fields reaction: Mechanism and synthetic use". Molecules. 17 (11): 12821–12835. doi:10.3390/molecules171112821

Pyridoxal phosphate (2,933 words) [view diff] case mismatch in snippet view article find links to article

the Dunathan and Quinonoid Intermediates provide Insights into the Reaction Mechanism of Group II Decarboxylases". Journal of Molecular Biology. 432 (24):

Van Slyke determination (491 words) [view diff] exact match in snippet view article find links to article

2024-05-15. {{cite web}}: Missing or empty |title= (help) Van Slyke reaction mechanism scheme Modified Van Slyke Method for Determination of Aliphatic Amino

Drug metabolism (3,259 words) [view diff] exact match in snippet view article find links to article

of hydroxyl groups or N-, O- and S-dealkylation of substrates. The reaction mechanism of the P-450 oxidases proceeds through the reduction of cytochrome-bound

Chichibabin reaction (1,039 words) [view diff] exact match in snippet view article find links to article

nitrogen in amination. It is widely accepted that the Chichibabin reaction mechanism is an addition-elimination reaction that proceeds through an σ-adduct

Henry reaction (1,931 words) [view diff] exact match in snippet view article find links to article

Henry reaction mechanism

Aldolase A (2,034 words) [view diff] exact match in snippet view article find links to article

The reaction mechanism of aldolase. The enzyme's reactive site amino acid's side-chains are shown in blue. Abbreviations: DHAP - dihydroxyacetone phosphate;

Emma Raven (1,075 words) [view diff] case mismatch in snippet view article find links to article

Stephen K.; Raven, Emma Lloyd (April 2009). "Reassessment of the Reaction Mechanism in the Heme Dioxygenases". Journal of the American Chemical Society

Paraben (3,973 words) [view diff] exact match in snippet view article find links to article

however, is observed for chlorinated parabens (59.2–82.8%). A proposed reaction mechanism for the removal of parabens by ozonation is detailed mechanistically

Phenolphthalein (1,809 words) [view diff] exact match in snippet view article find links to article

An animation of the pH-dependent reaction mechanism: H3In+ → H2In → In2− → In(OH)3−

Linoleate 10R-lipoxygenase (170 words) [view diff] exact match in snippet view article find links to article

Jernerén F, Garscha U, Hoffmann I, Hamberg M, Oliw EH (April 2010). "Reaction mechanism of 5,8-linoleate diol synthase, 10R-dioxygenase, and 8,11-hydroperoxide

2,6-Dichloroquinone-4-chloroimide (130 words) [view diff] case mismatch in snippet view article find links to article

(1977). "Colour Reaction of Phenols with the Gibbs Reagent. The Reaction Mechanism and Decomposition and Stabilisation of the Reagent". Microchim. Acta

Adenylyl-sulfate reductase (1,533 words) [view diff] exact match in snippet view article find links to article

PMID 21585336. Schiffer A, Fritz G, Kroneck PM, Ermler U (March 2006). "Reaction mechanism of the iron-sulfur flavoenzyme adenosine-5'-phosphosulfate reductase

Chrome plating (3,230 words) [view diff] exact match in snippet view article find links to article

microcracks that are confined to inner depth of the deposit. This HER side-reaction mechanism seems more acceptable by the electrochemistry community at present

Isocitrate lyase (2,447 words) [view diff] exact match in snippet view article find links to article

cleavage results in the release of succinate and glyoxylate. This reaction mechanism functions much like that of aldolase in glycolysis, where a carbon-carbon

Inositol oxygenase (1,818 words) [view diff] exact match in snippet view article find links to article

2009). "Insights into the (superoxo)Fe(III)Fe(III) intermediate and reaction mechanism of myo-inositol oxygenase: DFT and ONIOM(DFT:MM) study". Journal of

Vinyl acetate (1,201 words) [view diff] case mismatch in snippet view article find links to article

Alan, W.; Neurock, M.; Tysoe Wilfred, T. (2005). "Elucidation of the Reaction Mechanism for the Palladium-Catalyzed Synthesis of Vinyl Acetate". Angewandte

Dihydrolipoamide dehydrogenase (2,338 words) [view diff] exact match in snippet view article find links to article

Chen LY, Liu TC (March 2007). "The role of N286 and D320 in the reaction mechanism of human dihydrolipoamide dehydrogenase (E3) center domain". Journal

Stieglitz rearrangement (2,201 words) [view diff] exact match in snippet view article find links to article

other activated amine derivatives. The Stieglitz rearrangement's reaction mechanism and the products and starting materials involved make it closely related

Hydroquinone (2,394 words) [view diff] exact match in snippet view article find links to article

ways. The most widely used route is similar to the cumene process in reaction mechanism and involves the dialkylation of benzene with propene to give 1,4-diisopropylbenzene

Decamethyldizincocene (1,323 words) [view diff] exact match in snippet view article find links to article

complex is believed to occur via hydrocarbyl-bridged intermediates. The reaction mechanism is, however, uncertain. Previously it was hypothesized that the creation

Methyltransferase (2,911 words) [view diff] exact match in snippet view article find links to article

proline-cysteine pair which forms a thiolate anion important for the reaction mechanism, and the cytosine substrate binding pocket. Many features of DNA methyltransferases

Terephthalic acid (1,843 words) [view diff] case mismatch in snippet view article find links to article

Youwei; Wang, Lijun; Li, Xi (2007). "Semicontinuous Studies on the Reaction Mechanism and Kinetics for the Liquid-Phase Oxidation of p-Xylene to Terephthalic

Laccase (2,036 words) [view diff] exact match in snippet view article find links to article

ISBN 9780521085731. Jones SM, Solomon EI (March 2015). "Electron transfer and reaction mechanism of laccases". Cellular and Molecular Life Sciences. 72 (5): 869–883

Dispersity (1,728 words) [view diff] exact match in snippet view article find links to article

fractional conversion must exceed 0.99, and the dispersity of this reaction mechanism in a batch or PFR is 2.0. Running a step-growth polymerization in

Delta-aminolevulinic acid dehydratase (1,918 words) [view diff] exact match in snippet view article find links to article

Jaffe EK (October 2004). "The porphobilinogen synthase catalyzed reaction mechanism". Bioorganic Chemistry. 32 (5): 316–25. doi:10.1016/j.bioorg.2004

Pair-instability supernova (2,084 words) [view diff] exact match in snippet view article find links to article

radioactive decay, release most of the visible light. A different reaction mechanism, photodisintegration, follows the initial pair-instability collapse

Α,α-Trehalase (221 words) [view diff] exact match in snippet view article find links to article

Ohguchi M, Kim D, Kimura A, Chiba S (November 2009). "Catalytic reaction mechanism based on α-secondary deuterium isotope effects in hydrolysis of trehalose

Richard M. Noyes (352 words) [view diff] exact match in snippet view article find links to article

Belousov–Zhabotinsky reaction. In 1976, he was able to identify the reaction mechanism of the Bray–Liebhafsky reaction. Noyes has received numerous honors

C5-convertase (1,661 words) [view diff] case mismatch in snippet view article find links to article

attack. ==References== Cooper NR, Müller-Eberhard HJ (1970). "The Reaction Mechanism of Human C5 in Immune Hemolysis". J Exp Med. 132 (4): R775–793. doi:10

Oxidative decarboxylation (1,564 words) [view diff] exact match in snippet view article find links to article

succinyl CoA is the product thioester. Dejun, Zhou (2012). Organic reaction mechanism. Chemical Industry Press. Yixian, Lv. Organic Chemistry 7th Edition

Aryl-sulfate sulfotransferase (170 words) [view diff] exact match in snippet view article find links to article

Konishi L, Kobashi K (1986). "Purification, characterization and reaction mechanism of novel arylsulfotransferase obtained from an anaerobic bacterium

Beryllium-8 (1,792 words) [view diff] exact match in snippet view article find links to article

of the bottleneck created by 8Be would result in a very different reaction mechanism in Big Bang nucleosynthesis and the triple-alpha process, as well

Anammox (5,170 words) [view diff] exact match in snippet view article find links to article

without the need for nitrite supply. Another, still unexplored, reaction mechanism involves anaerobic ammonium oxidation on anodes of bio-electrical

Molecular layer deposition (8,513 words) [view diff] exact match in snippet view article find links to article

temperature-dependent factors, such as film diffusion, number of reactive sites or reaction mechanism. When carrying out an MLD process, the ideal case of one monolayer

Glutamine synthetase (3,063 words) [view diff] exact match in snippet view article find links to article

PMID 10708854. Liaw SH, Eisenberg D (Jan 1994). "Structural model for the reaction mechanism of glutamine synthetase, based on five crystal structures of enzyme-substrate

GMP reductase (1,388 words) [view diff] exact match in snippet view article find links to article

PMID 19067971. S2CID 24698373. Spector T, Jones TE, Miller RL (April 1979). "Reaction mechanism and specificity of human GMP reductase. Substrates, inhibitors, activators

Enolase (3,252 words) [view diff] exact match in snippet view article find links to article

S2CID 9976031. Dinovo EC, Boyer PD (1971). "Isotopic probes of the enolase reaction mechanism". J Biol Chem. 240 (14): 4586–93. doi:10.1016/S0021-9258(18)62051-4

Terpentetriene synthase (213 words) [view diff] exact match in snippet view article find links to article

switching, deuterium hyperlabeling, and 1H NMR spectroscopy. The reaction mechanism of a novel streptomyces diterpene cyclase". The Journal of Organic

Propionyl-CoA carboxylase (1,718 words) [view diff] exact match in snippet view article find links to article

biotin bound. With biotin, optimum pH is 8.0-8.5. The normal catalytic reaction mechanism involves a carbanion intermediate and does not proceed through a concerted