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searching for Rate-determining step 53 found (132 total)

Committed step (675 words) [view diff] exact match in snippet view article find links to article

coefficient. It is rare that the first committed step is in fact the rate-determining step. Metabolic pathways require tight regulation, so that the proper

Charge transfer coefficient (550 words) [view diff] exact match in snippet view article find links to article

According to an IUPAC definition, for a reaction with a single rate-determining step, the charge transfer coefficient for a cathodic reaction (the cathodic

PYGB (850 words) [view diff] exact match in snippet view article find links to article

by ATP, ADP, and glucose-6-phosphate. This enzyme catalyzes the rate-determining step in glycogen degradation. [provided by RefSeq, Jul 2008] The PYGB

Phosphofructokinase 2 (4,253 words) [view diff] exact match in snippet view article find links to article

from substrate fructose-6-phosphate. Fru-2,6-P2 contributes to the rate-determining step of glycolysis as it activates enzyme phosphofructokinase 1 in the

Athel Cornish-Bowden (1,872 words) [view diff] exact match in snippet view article find links to article

Cornish-Bowden, AJ; Greenwell, P; Knowles, JR (June 1969). "The rate-determining step in pepsin-catalysed reactions, and evidence against an acyl-enzyme

Chichibabin reaction (1,062 words) [view diff] no match in snippet view article find links to article

cases, the anionic σ-adduct is unstable making its formation the rate determining step. Hydride ion elimination In addition to the mechanism shown above

Tryptophan-rich sensory protein (949 words) [view diff] exact match in snippet view article find links to article

transport from the outer to the inner mitochondrial membrane, the rate-determining step in steroid biosynthesis, has been studied in detail. PBR is required

Baylis–Hillman reaction (2,829 words) [view diff] exact match in snippet view article find links to article

all solvents), which would imply that proton abstraction is the rate-determining step. To account for this reanalysis, McQuade proposed modifying Hoffman's

Reaction rate (3,936 words) [view diff] exact match in snippet view article find links to article

very rapid compared to the second, so the slow reaction 2 is the rate-determining step. This is a bimolecular elementary reaction whose rate is given by

Swain–Lupton equation (1,276 words) [view diff] no match in snippet view article find links to article

will too fail when special circumstances arise, i.e. change in the rate determining step of a mechanism or solvation structure. Hammett equation Taft equation

Borane (1,227 words) [view diff] no match in snippet view article find links to article

diborane to produce higher boranes: B2H6 ⇌ 2BH3 BH3 +B2H6 → B3H7 +H2 (rate determining step) BH3 + B3H7 ⇌ B4H10 B2H6 + B3H7 → BH3 + B4H10 ⇌ B5H11 + H2 Further

Ring-opening metathesis polymerization (780 words) [view diff] no match in snippet view article find links to article

cycloaddition. When using a G3 catalyst, 2+2 cycloaddition is the rate determining step. Frontal ring-opening metathesis polymerization (FROMP) is a variation

Crystallite (1,638 words) [view diff] no match in snippet view article find links to article

the material could fracture. During grain boundary migration, the rate determining step depends on the angle between two adjacent grains. In a small angle

Reactivity (chemistry) (1,206 words) [view diff] exact match in snippet view article

rate is the change in the molar concentration in one second in the rate-determining step of the reaction (the slowest step), [A] is the product of the molar

Tertiary carbon (630 words) [view diff] no match in snippet view article find links to article

reaction by producing a stable carbocation. This happens because the rate determining step of a SN1 reaction is the formation of the carbocation. The rate

Metal-induced embrittlement (638 words) [view diff] no match in snippet view article find links to article

ductile materials. Crack extension, as opposed to crack onset, is the rate determining step for solid induced-metal embrittlement. The main mechanism leading

Chymotrypsin (1,063 words) [view diff] exact match in snippet view article find links to article

Caswell, M.; Caplow, M. (1973). "Concerning a reported change in rate-determining step in chymotrypsin catalysis". J. Am. Chem. Soc. 95 (8): 2734–5. Bibcode:1973JAChS

Primase (2,371 words) [view diff] no match in snippet view article find links to article

strand by halting the progression of the replication fork. The rate determining step in primase is when the first phosphodiester bond is formed between

Tipson–Cohen reaction (727 words) [view diff] no match in snippet view article find links to article

(Ts). Scheme 3: The scheme illustrates the first displacement, the rate determining step and slowest step, where the starting material is converted to the

Shvo catalyst (738 words) [view diff] exact match in snippet view article find links to article

descriptions of the double bond's interaction with the complex at the rate-determining step. The proposed alternatives are an inner-sphere mechanism, where

Malate dehydrogenase (2,401 words) [view diff] no match in snippet view article find links to article

the movement of the loop has been shown to correlate with the rate determining step of the enzyme. Malate dehydrogenases catalyzes the interconversion

Lead chamber process (956 words) [view diff] no match in snippet view article find links to article

reoxidized by molecular oxygen to nitrogen dioxide. This is the overall rate determining step in the process: 2 NO + O2 → 2 NO2 Nitrogen oxides are absorbed and

Chelating resin (949 words) [view diff] no match in snippet view article find links to article

used to determine general properties of chelating resins such as rate determining step and pH dependence, etc. Dowex A-1 is produced from chloromethylated

Methane monooxygenase (1,946 words) [view diff] no match in snippet view article find links to article

abstraction of the hydrogen atom from the substrate to form QH (the rate determining step), hydroxyl bridged compound Q and the free alkyl radical. The nonradical

Conrad–Limpach synthesis (1,046 words) [view diff] exact match in snippet view article find links to article

Conrad–Limpach synthesis.[1] Perhaps the most important step (and the rate-determining step) in the reaction mechanism is the annulation of the molecule via

Insulin-degrading enzyme (2,076 words) [view diff] exact match in snippet view article find links to article

is broken. A look at the whole reaction path indicates that the rate-determining step in this process is the nucleophilic addition. After this point,

RRNA endonuclease (922 words) [view diff] no match in snippet view article find links to article

molecules, also has no effect on the rate. It is suggested that the rate determining step for SRL cleaves occurs within the chemical cleavage of the phosphodiester

Phase-transfer catalyst (1,713 words) [view diff] no match in snippet view article find links to article

stirring is not required because the mass transfer is not the rate determining step in this catalytic system. It is already demonstrated that this system

Cytochalasin B (3,972 words) [view diff] exact match in snippet view article find links to article

is essential for filament build-up. The oligomerization is the rate-determining step, considering actin filament formation as a whole. The so-called

Marcetta Y. Darensbourg (3,522 words) [view diff] exact match in snippet view article find links to article

compounds. During the course of these studies, the kinetics of the rate-determining step of tert-butyllithium dissociation from tetramer to a dimer were

Polymer devolatilization (1,102 words) [view diff] exact match in snippet view article find links to article

diffusion coefficients of volatiles in polymers, this can be the rate-determining step.: 35–65 This effect can be enhanced by higher temperatures or by

Organocopper chemistry (2,449 words) [view diff] exact match in snippet view article find links to article

followed by reductive elimination (RE). The nucleophilic attack is the rate-determining step. In the substitution of iodide, a single-electron transfer mechanism

Leaving group (2,527 words) [view diff] no match in snippet view article find links to article

complexation) and the departure of the leaving group occurs in the rate determining step. In the situation where other variables are held constant (nature

Methedrone (2,512 words) [view diff] no match in snippet view article find links to article

is negative charge built up in the transition state during the rate determining step. This reasoning is based on the good linear correlation (r=0.9805)

Maltose-binding protein (2,397 words) [view diff] exact match in snippet view article find links to article

"Folding of maltose-binding protein. Evidence for the identity of the rate-determining step in vivo and in vitro". The Journal of Biological Chemistry. 268

Inner sphere complex (1,360 words) [view diff] no match in snippet view article find links to article

unstable and possesses a high activation energy. As a result, the rate determining step relies on the breakage of a critical oxo bond that may increase

Enzyme catalysis (5,079 words) [view diff] exact match in snippet view article find links to article

Caswell M, Caplow M (April 1973). "Concerning a reported change in rate-determining step in chymotrypsin catalysis". Journal of the American Chemical Society

Fission barrier (1,601 words) [view diff] exact match in snippet view article find links to article

formation and eventual decay of this transition state nucleus is the rate-determining step in the fission process and corresponds to the passage over an activation

Catalytic triad (5,858 words) [view diff] exact match in snippet view article find links to article

Caswell, M; Caplow, M (1973). "Concerning a reported change in rate-determining step in chymotrypsin catalysis". J. Am. Chem. Soc. 95 (8): 2734–5. Bibcode:1973JAChS

Nuclear chemistry (5,193 words) [view diff] exact match in snippet view article find links to article

energy. This can lead to a decrease in the reaction rate if the rate-determining step involves breaking a bond between hydrogen and another atom. Thus

Omecamtiv mecarbil (1,539 words) [view diff] exact match in snippet view article find links to article

pre-powerstroke and the phosphate release states, thereby accelerating the rate-determining step of the cross-bridge cycle, which is the transition of the actin-myosin

Cyclic voltammetry (3,491 words) [view diff] no match in snippet view article find links to article

fulfilled. This leads to the so called Randles–Sevcik equation and the rate determining step of this electrochemical redox reaction can be assigned to diffusion

Adenylyl-sulfate reductase (1,533 words) [view diff] no match in snippet view article find links to article

reversible transformation of APS to sulfite and AMP, which is the rate determining step of the overall reaction. The reaction catalyzed by APS reductase

Hypervalent molecule (4,517 words) [view diff] no match in snippet view article find links to article

followed by a nucleophilic attack of the intermediate by water in a rate determining step leading to hexacoordinated species that quickly decomposes giving

Dihydrofolate reductase (4,582 words) [view diff] no match in snippet view article find links to article

product (THF) dissociation step from E:NADPH:THF to E:NADPH is the rate determining step during steady-state turnover. Conformational changes are critical

Caricain (2,014 words) [view diff] no match in snippet view article find links to article

substrate complex which is then slowly converted to the product in the rate determining step which regenerates the enzyme. Where the concentration of the enzyme

Hoffman nucleation theory (1,998 words) [view diff] exact match in snippet view article find links to article

the growth rate on the front laterally, referred to as g, is the rate-determining step (RDS) and exceeds the secondary nucleation rate, i. In this instance

Aza-Cope rearrangement (5,704 words) [view diff] case mismatch in snippet view article find links to article

; Overman, L. E. (1987). "Medium Effects and the Nature of the Rate-Determining Step in Mannich-Type Cyclizations". J. Am. Chem. Soc. 109 (20): 6107–6114

Operando spectroscopy (3,438 words) [view diff] no match in snippet view article find links to article

followed by the reduction of molecular oxygen to water, and that the rate determining step is the detachment of the product. Understanding organometallic catalytic

Germanium(II) hydrides (2,198 words) [view diff] exact match in snippet view article

difficult for the oxygen nucleophile to approach the Ge metal in the rate-determining step, as well as by the decreased Lewis basicity of the oxygen the aryl

Industrial catalysts (3,064 words) [view diff] no match in snippet view article find links to article

HOCO as intermediate) followed by the redox mechanism with the rate determining step being the water dissociation. For both HTS catalyst and LTS catalyst

Vinyl cation (4,374 words) [view diff] exact match in snippet view article find links to article

and the proton and with the protonation of the acetylene as the rate-determining step. Monosubstituted aryl/alkoxyacetylenes exhibit faster kinetics in

Organobismuth radical (3,502 words) [view diff] case mismatch in snippet view article find links to article

Unstable Bi(II) Radical from Bi−O Bond Homolysis. Implications in the Rate-Determining Step of the SOHIO Process". Inorganic Chemistry. 41 (14): 3590–3592.