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Oxophilicity
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shown that oxophilicity depends more on the electronegativity and effective nuclear charge of the element than on its hardness. This explains why the earlyRydberg formula (1,901 words) [view diff] exact match in snippet view article find links to article
elements, i.e. atoms with only one electron being affected by an effective nuclear charge (which is easily estimated). Examples would include He+, Li2+,Gallium(III) bromide (869 words) [view diff] exact match in snippet view article
structure with the Br in an equatorial position due to their large effective nuclear charge. Additionally, GaBr3 can be used as a catalyst in certain oxidativeYtterbium(III) chloride (data page) (30 words) [view diff] exact match in snippet view article
Crystallographic constants a = 6.73 b = 11.65 c = 6.38 β = 110.4° Effective nuclear charge 3.290 Bond strength 1194±7 kJ/mol Bond length 2.434 (Yb-Cl) BondMössbauer spectroscopy (3,664 words) [view diff] exact match in snippet view article find links to article
a nuclear constant, the difference between Re2 and Rg2 is the effective nuclear charge radius difference between excited state and the ground state, andYtterbium(III) chloride (971 words) [view diff] exact match in snippet view article
than Yb+3 because lanthanides become much smaller with increasing effective nuclear charge as a consequence of the f electrons not being as well shieldedZeta (2,016 words) [view diff] exact match in snippet view article find links to article
physics The rotational quantity of angular jerk in physics The effective nuclear charge on an electron in quantum chemistry The electrokinetic potentialNearly free electron model (1,346 words) [view diff] exact match in snippet view article find links to article
magnitude "seen" by the conduction electrons. The result is an effective nuclear charge experienced by the conduction electrons which is significantlyVariational method (quantum mechanics) (2,033 words) [view diff] no match in snippet view article
other electron, so we can use a trial wavefunction equal with an "effective" nuclear charge Z < 2: The expectation value of H in this state is: ⟨ H ⟩ = [Slater-type orbital (2,484 words) [view diff] exact match in snippet view article find links to article
nuclear charge being partly shielded by electrons. Historically, the effective nuclear charge was estimated by Slater's rules. The normalization constant isHypervalent molecule (4,486 words) [view diff] exact match in snippet view article find links to article
change for silicon species over phosphorus species is the increased effective nuclear charge at phosphorus. Therefore, silicon is concluded to be more looselySharp series (1,395 words) [view diff] case mismatch in snippet view article find links to article
Araki; L. K. Noda (September 1999). "A Procedure to Obtain the Effective Nuclear Charge from the Atomic Spectrum of Sodium" (PDF). Journal of ChemicalTotal position spread (2,031 words) [view diff] exact match in snippet view article find links to article
nuclei being near to each other's causing and enhancement of the effective nuclear charge that makes electrons to be more localized. When stretching theHelium atom (6,000 words) [view diff] exact match in snippet view article find links to article
shields the nucleus so that the other electron actually sees an effective nuclear charge Z that is less than 2. A wave function of this type is given by:Diffuse series (1,820 words) [view diff] case mismatch in snippet view article find links to article
K.; Noda, L. K. (September 1999). "A Procedure to Obtain the Effective Nuclear Charge from the Atomic Spectrum of Sodium" (PDF). Journal of ChemicalInverted ligand field theory (2,935 words) [view diff] exact match in snippet view article find links to article
transition metals. Energy shifts in XAS are higher due to the higher effective nuclear charge of atoms in higher oxidations, presumably due to the higher binding