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searching for Oxophilicity 6 found (16 total)

alternate case: oxophilicity

Organotitanium chemistry (1,866 words) [view diff] exact match in snippet view article find links to article

which recommends the use of air-free techniques. On the other hand, high oxophilicity means that titanium alkyls are effective for abstracting or exchanging
Titanium tetrachloride (1,732 words) [view diff] exact match in snippet view article find links to article
occasional use in organic synthesis, capitalizing on its Lewis acidity, its oxophilicity, and the electron-transfer properties of its reduced titanium halides
Post-metallocene catalyst (958 words) [view diff] exact match in snippet view article find links to article
copolymerization of ethylene with polar monomers has been heavily studied. The high oxophilicity of the early metals precluded their use in this application. Late metal
Organogold chemistry (3,036 words) [view diff] exact match in snippet view article find links to article
potential of Au(I)), 2) tolerance towards adventitious moisture (due its low oxophilicity), and 3) relatively low toxicity compared to other pi-acids (e.g., Pt(II)
Alkenylaluminium compounds (1,660 words) [view diff] exact match in snippet view article find links to article
exception being when carbonyl and enone acceptors are used, due to the high oxophilicity of aluminium). In most cases, nucleophilic activation of organoalanes
Chain walking (1,433 words) [view diff] exact match in snippet view article find links to article
is based on late-transition metal complexes, having generally lower oxophilicity, these complexes were demonstrated also to provide copolymerisation of