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Longer titles found: Oxidative decarboxylation (view), Pyruvate decarboxylation (view), Krapcho decarboxylation (view), Ketonic decarboxylation (view), Barton decarboxylation (view), Adams decarboxylation (view)

searching for Decarboxylation 252 found (597 total)

alternate case: decarboxylation

Pyruvate decarboxylase (1,153 words) [view diff] exact match in snippet view article find links to article

Pyruvate decarboxylase is an enzyme (EC 4.1.1.1) that catalyses the decarboxylation of pyruvic acid to acetaldehyde. It is also called 2-oxo-acid carboxylase

Malate dehydrogenase (decarboxylating) (226 words) [view diff] exact match in snippet view article

pyruvate metabolism and carbon fixation. NAD-malic enzyme is one of three decarboxylation enzymes used in the inorganic carbon concentrating mechanisms of C4

Arginine decarboxylase (1,322 words) [view diff] exact match in snippet view article find links to article

agmatine and carbon dioxide. The process consumes a proton in the decarboxylation and employs a pyridoxal-5'-phosphate (PLP) cofactor, similar to other

Bredt's rule (703 words) [view diff] exact match in snippet view article find links to article

doing so. Bicyclo[5.3.1]undecane-11-one-1-carboxylic acid undergoes decarboxylation on heating to 132 °C, but the similar compound bicyclo[2.2

List of EC numbers (EC 7) (1,042 words) [view diff] no match in snippet view article

This list contains a list of sub-classes for the seventh group of Enzyme Commission numbers, EC 7, translocases, placed in numerical order as determined

N-Bromosuccinimide (1,242 words) [view diff] exact match in snippet view article find links to article

by decarboxylation and release of an imine. Further hydrolysis will yield an aldehyde and ammonia. (cf. non-oxidative PLP dependent decarboxylation) Although

IDH3A (1,667 words) [view diff] exact match in snippet view article find links to article

IDH3A gene. Isocitrate dehydrogenases (IDHs) catalyze the oxidative decarboxylation of isocitrate to 2-oxoglutarate. These enzymes belong to two distinct

Malate dehydrogenase (oxaloacetate-decarboxylating) (NADP+) (1,888 words) [view diff] exact match in snippet view article

metabolism and carbon fixation. NADP-malic enzyme is one of three decarboxylation enzymes used in the inorganic carbon concentrating mechanisms of C4

IDH3G (1,615 words) [view diff] exact match in snippet view article find links to article

IDH3G gene. Isocitrate dehydrogenases (IDHs) catalyze the oxidative decarboxylation of isocitrate to 2-oxoglutarate. These enzymes belong to two distinct

Quisqualamine (298 words) [view diff] exact match in snippet view article find links to article

the neurotransmitters glutamate and γ-aminobutyric acid (GABA). α-Decarboxylation of excitatory amino acids can produce derivatives with inhibitory effects

IDH3B (1,737 words) [view diff] exact match in snippet view article find links to article

IDH3B gene. Isocitrate dehydrogenases (IDHs) catalyze the oxidative decarboxylation of isocitrate to 2-oxoglutarate. These enzymes belong to two distinct

Aromatic L-amino acid decarboxylase inhibitor (395 words) [view diff] exact match in snippet view article find links to article

decarboxylase (AADC, AAAD, or DOPA decarboxylase). It is used to inhibit the decarboxylation of L-DOPA to dopamine outside the brain, i.e. in the blood. This is

Gallic acid (1,602 words) [view diff] no match in snippet view article find links to article

Gallic acid (also known as 3,4,5-trihydroxybenzoic acid) is a trihydroxybenzoic acid with the formula C6H2(OH)3CO2H. It is classified as a phenolic acid

Pyruvate dehydrogenase lipoamide kinase isozyme 1 (1,617 words) [view diff] exact match in snippet view article find links to article

of a mitochondrial multienzyme complex that catalyzes the oxidative decarboxylation of pyruvate and is one of the major enzymes responsible for the regulation

Benzisoxazole (342 words) [view diff] exact match in snippet view article find links to article

Origins and catalytic nature of the solvent rate acceleration for the decarboxylation of 3-carboxybenzisoxazoles". Journal of the American Chemical Society

Isocitrate lyase (2,447 words) [view diff] exact match in snippet view article find links to article

and glyoxylate. Together with malate synthase, it bypasses the two decarboxylation steps of the tricarboxylic acid cycle (TCA cycle) and is used by bacteria

Glycin (195 words) [view diff] exact match in snippet view article find links to article

acids. Glycin is structurally related to 4-aminophenol and metol. Decarboxylation of glycin gives metol. Glycin has a milder reduction potential than

Glyoxylate cycle (2,510 words) [view diff] exact match in snippet view article find links to article

carbon acetate units. The glyoxylate cycle bypasses the two oxidative decarboxylation reactions of the TCA cycle and directly converts isocitrate through

2,2,2-Trichloroethoxycarbonyl chloride (141 words) [view diff] exact match in snippet view article find links to article

insertion in the presence of acetic acid, resulting in elimination and decarboxylation. 2,2,2-Trichloroethoxycarbonyl (Troc) group is largely used as a protecting

Higenamine (1,595 words) [view diff] exact match in snippet view article find links to article

synthesized through Shikimate pathway, during which the last step involves decarboxylation and dehydrogenation of arogenate to give L-tyrosine. To generate dopamine

Aldehyde dehydrogenase 6 family, member A1 (1,250 words) [view diff] exact match in snippet view article find links to article

methylmalonate semialdehyde dehydrogenase, catalyzes the irreversible oxidative decarboxylation of malonate and methylmalonate semialdehydes to acetyl- and propionyl-CoA

6-Methylsalicylic acid (114 words) [view diff] exact match in snippet view article find links to article

occurs naturally, being a biosynthetic precursor to m-cresol. Its decarboxylation is catalyzed by 6-methylsalicylate decarboxylase: 6-methylsalicylate

Uridine monophosphate (487 words) [view diff] exact match in snippet view article find links to article

(orotidylic acid) in a decarboxylation reaction catalyzed by the enzyme orotidylate decarboxylase. Uncatalyzed, the decarboxylation reaction is extremely

Daniel S. Kemp (281 words) [view diff] exact match in snippet view article find links to article

triacid [pl] and the Kemp elimination [de] reaction (and the Kemp decarboxylation [de] variant) are among his developments. He was the author of an organic

Transporter Classification Database (5,159 words) [view diff] no match in snippet view article find links to article

The Transporter Classification Database (or TCDB) is an International Union of Biochemistry and Molecular Biology (IUBMB)-approved classification system

5-Fluoroorotic acid (169 words) [view diff] exact match in snippet view article find links to article

for the absence of the URA3 gene, which encodes the enzyme for the decarboxylation of 5-fluoroorotic acid to 5-fluorouracil, a toxic metabolite. It has

Uroporphyrinogen III decarboxylase (1,236 words) [view diff] exact match in snippet view article find links to article

resolutions. UroD is regarded as an unusual decarboxylase, since it performs decarboxylations without the intervention of any cofactors, unlike the vast majority

CBD cigarette (297 words) [view diff] exact match in snippet view article find links to article

hemp products containing less than 0.3% THC on a dry weight, post-decarboxylation basis. Many vendors are positioning CBD cigarettes as an alternative

Aminomethyltransferase (1,436 words) [view diff] exact match in snippet view article find links to article

tetrahydrofolate moiety. The aminomethyl intermediate is the product of the decarboxylation of glycine catalyzed by P-protein. In the reverse reaction, T-protein

4-Hydroxy-2-oxopentanoic acid (102 words) [view diff] exact match in snippet view article find links to article

acid, also known as 4-hydroxy-2-oxovalerate, is formed by the decarboxylation of 4-oxalocrotonate by 4-oxalocrotonate decarboxylase, is degraded

Pyrrole-2-carboxylate decarboxylase (183 words) [view diff] exact match in snippet view article find links to article

} pyrrole + HCO3− The enzyme catalyses both the carboxylation and decarboxylation reactions. Wieser M, Fujii N, Yoshida T, Nagasawa T (October 1998)

1,2-Cyclopentanedione (204 words) [view diff] exact match in snippet view article find links to article

followed by hydrolysis of the resulting diketodiester followed by decarboxylation. The enol is predicted to be about 1-3 kcal/mol more stable than the

Mycofactocin (993 words) [view diff] exact match in snippet view article find links to article

biosynthesis of mycofactocin from its precursor peptide MftA begins with decarboxylation of the C-terminal tyrosine residue by the radical SAM enzyme MftC,

Phosphoenolpyruvate mutase (1,230 words) [view diff] exact match in snippet view article find links to article

to this problem: it catalyzes the very thermodynamically favorable decarboxylation of PPR, and the resulting 2-phosphonoacetaldehyde is then converted

David Sidney Feingold (1,058 words) [view diff] exact match in snippet view article find links to article

The 4-epimerization and decarboxylation of DUP-d-glucuronic acid by extracts of Phaseolus aureus seedings. Decarboxylation of uridine diphosphate-d-glucuronic

IDH1 (3,017 words) [view diff] exact match in snippet view article find links to article

on chromosome 2. Isocitrate dehydrogenases catalyze the oxidative decarboxylation of isocitrate to 2-oxoglutarate. These enzymes belong to two distinct

Pyrogallol (807 words) [view diff] exact match in snippet view article find links to article

manner first reported by Scheele in 1786: heating gallic acid to induce decarboxylation. Gallic acid is also obtained from tannin. Many alternative routes

3-Iodophenol (208 words) [view diff] exact match in snippet view article find links to article

and amine nucleophiles. 3-Iodophenol can be prepared by oxidative decarboxylation of 3-iodobenzoic acid: IC6H4CO2H + "O" → IC6H4OH + CO2 Haynes, p. 5

Diethylsuccinoylsuccinate (238 words) [view diff] exact match in snippet view article find links to article

converts to 1,4-cyclohexanedione via hydrolysis of the esters followed by decarboxylation. Mez, Hans-Christian; Rihs, Gret (1973). "Chemistry of Succinylsuccinic

Oxamate (350 words) [view diff] exact match in snippet view article find links to article

transferase domain active site, and reverses the reaction of oxalaoacetate decarboxylation by pyruvate carboxylase. Watts H (1866). A Dictionary of Chemistry

Tetrahydrofolic acid (447 words) [view diff] exact match in snippet view article find links to article

glutamic acid; this may reduce the amount of histidine available for decarboxylation and protein synthesis, and hence the urinary histamine and formiminoglutamic

Cannabinol (2,138 words) [view diff] exact match in snippet view article find links to article

phytocannabinoids are generated via enzymatic conversion. From there, decarboxylation (i.e., catalyzed by combustion or heat) yields the most well-known

Formate (514 words) [view diff] exact match in snippet view article find links to article

Formate salts have the formula M(O2CH)(H2O)x. Such salts are prone to decarboxylation. For example, hydrated nickel formate decarboxylates at about 200 °C

IDH1 (3,017 words) [view diff] exact match in snippet view article find links to article

on chromosome 2. Isocitrate dehydrogenases catalyze the oxidative decarboxylation of isocitrate to 2-oxoglutarate. These enzymes belong to two distinct

Fatty acid photodecarboxylase (386 words) [view diff] exact match in snippet view article find links to article

being the co-product). FAP uses continuous blue light to catalyze decarboxylation, making it a photoenzyme (the third well described). The photoenzyme

Cannabinol (2,138 words) [view diff] exact match in snippet view article find links to article

phytocannabinoids are generated via enzymatic conversion. From there, decarboxylation (i.e., catalyzed by combustion or heat) yields the most well-known

Formate (514 words) [view diff] exact match in snippet view article find links to article

Formate salts have the formula M(O2CH)(H2O)x. Such salts are prone to decarboxylation. For example, hydrated nickel formate decarboxylates at about 200 °C

Umpolung (1,774 words) [view diff] exact match in snippet view article find links to article

catalyze umpolung reactivity, such as the decarboxylation of pyruvate. In the absence of TPP, the decarboxylation of pyruvate would result in the placement

Hofmann rearrangement (770 words) [view diff] exact match in snippet view article find links to article

to form stable carbamates or other products rather than undergoing decarboxylation. In the following example, the intermediate isocyanate is trapped by

Ronald Breslow (2,040 words) [view diff] exact match in snippet view article find links to article

site of reactivity of thiamin diphosphate in enzymes that promote the decarboxylation of pyruvate – based on his pioneering use of proton NMR with small

Flavodoxin (874 words) [view diff] exact match in snippet view article find links to article

essential POR (pyruvate oxidoreductase enzyme complex) used in pyruvate decarboxylation. Most flavodoxins have a large hydrophobic residue such as tryptophan

Curacin A (794 words) [view diff] exact match in snippet view article find links to article

the hydroxyl group of carbon 15, which activates the molecule for decarboxylation and terminal alkene formation. The CurB (ACP), CurC (ketosynthase)

Lysyl hydroxylase (346 words) [view diff] exact match in snippet view article find links to article

1016/0005-2795(67)90566-1. PMID 6033801. Rhoads RE, Udenfriend S (Aug 1968). "Decarboxylation of alpha-ketoglutarate coupled to collagen proline hydroxylase". Proceedings

Reductions with diimide (966 words) [view diff] exact match in snippet view article find links to article

typically generated either through the oxidation of hydrazine or the decarboxylation of potassium azodicarboxylate. Kinetic experiments suggest that regardless

2-Dehydro-3-deoxy-phosphogluconate aldolase (1,629 words) [view diff] exact match in snippet view article find links to article

formation between a lysine E-amino acid group and carbonyl compounds, decarboxylation of oxaloacetate, and exchange of solvent protons with the methyl hydrogen

Jasmolone (409 words) [view diff] exact match in snippet view article find links to article

The chain shortening could be produced by a beta-oxidation then a decarboxylation. 12-Oxophytodienoic acid is also used in the production of jasmonic

Ketoacyl synthase (2,238 words) [view diff] exact match in snippet view article find links to article

Typically, this enzyme is used in condensation reactions, as well as decarboxylation and acyl group transfer. The reaction proceeds as such: acyl-[acyl-carrier

OGDH (1,535 words) [view diff] exact match in snippet view article find links to article

the gene. This gene encodes a subunit that catalyzes the oxidative decarboxylation of alpha-ketoglutarate to Succinyl-CoA at its active site in the fourth

Hydrothermal liquefaction (2,577 words) [view diff] exact match in snippet view article find links to article

CO2 (decarboxylation). These reactions result in the production of high H/C ratio bio-oil. Simplified descriptions of dehydration and decarboxylation reactions

Aucubin (945 words) [view diff] exact match in snippet view article find links to article

5-pyrophosphomevalonate. Phosphosphomevalonate decarboxylase through a concerted decarboxylation reaction affords isopentenyl pyrophosphate (IPP). IPP is the basic

Acetyl-CoA (2,091 words) [view diff] exact match in snippet view article find links to article

transamination and eventually to isovaleryl-CoA through oxidative decarboxylation by an α-ketoacid dehydrogenase complex. Isovaleryl-CoA undergoes dehydrogenation

Agmatine (1,914 words) [view diff] exact match in snippet view article find links to article

synthesis in mammals was discovered. Agmatine biosynthesis by arginine decarboxylation is well-positioned to compete with the principal arginine-dependent

Sparteine (849 words) [view diff] exact match in snippet view article find links to article

L-lysine. The first intermediate in the biosynthesis is cadaverine, the decarboxylation product of lysine catalyzed by the enzyme lysine decarboxylase (LDC)

Methylmalonyl-CoA decarboxylase (287 words) [view diff] exact match in snippet view article find links to article

(1968). "Methylmalonyl coenzyme A decarboxylase. Its role in succinate decarboxylation by Micrococcus lactilyticus". J. Biol. Chem. 243 (6): 1253–61. PMID 5646172

Hydrotreated vegetable oil (1,178 words) [view diff] exact match in snippet view article find links to article

hydrocarbons by hydrodeoxygenation (removing oxygen as water) and/or decarboxylation (removing oxygen as carbon dioxide). A formulaic example of this is

Silver lactate (299 words) [view diff] exact match in snippet view article find links to article

Christopher; Staples, Richard J.; Winpenny, Richard E. P. (1 July 1991). "Decarboxylation of (triphenylphosphine)gold(I) carboxylates". Organometallics. 10 (7):

Perkin reaction (385 words) [view diff] exact match in snippet view article find links to article

not universally accepted, as several other versions exist, including decarboxylation without acetic group transfer. Benzaldehyde reacts with acetic anhydride

Butenoic acid (310 words) [view diff] exact match in snippet view article find links to article

Bigley and Michael J. Clarke (1982): "Studies in decarboxylation. Part 14. The gas-phase decarboxylation of but-3-enoic acid and the intermediacy of isocrotonic

E1cB-elimination reaction (2,146 words) [view diff] exact match in snippet view article find links to article

reported by Lukeman et al. In this report, a photochemically induced decarboxylation reaction generates a carbanion intermediate, which subsequently eliminates

Α-Ketoisovaleric acid (210 words) [view diff] exact match in snippet view article find links to article

hydroxymethyltransferase. Like many α-ketoacids, α-ketoisovaleric acid is prone to decarboxylation to give isobutyraldehyde: (CH3)2CHC(O)CO2H → (CH3)2CHCHO + CO2 Genetic

Benzofuran (395 words) [view diff] exact match in snippet view article find links to article

acid followed by dehydration (cyclication) of the resulting ether and decarboxylation. Perkin rearrangement, where a coumarin is reacted with a hydroxide:

Lysergic acid (628 words) [view diff] exact match in snippet view article find links to article

N-methylated with S-adenosyl-L-methionine. Oxidative ring closure followed by decarboxylation, reduction, cyclization, oxidation, and allylic isomerization yields

Propionigenium modestum (1,047 words) [view diff] exact match in snippet view article find links to article

ISBN 9780387254975. Janssen, Peter H.; Liesack, Werner (1995). "Succinate decarboxylation by Propionigenium maris sp. nov., a new anaerobic bacterium from an

Sinapinic acid (538 words) [view diff] exact match in snippet view article find links to article

is a phenolic compound found in crude canola oil. It is produced by decarboxylation of sinapic acid during canola seed roasting. Phenolic content in wine

Glutaric acid (375 words) [view diff] exact match in snippet view article find links to article

obtained from oxidation of 1,3-cyclohexanedione, which proceeds with decarboxylation. 1,5-Pentanediol, a common plasticizer and precursor to polyesters

Transition metal imido complex (514 words) [view diff] exact match in snippet view article find links to article

2 RNH3Cl Aryl isocyanates react with metal oxides concomitant with decarboxylation: LnMO + O=C=NR → LnMNR + CO2 Some are generated from the reaction of

2,2′-Bipyridine (317 words) [view diff] exact match in snippet view article find links to article

have practical applications. 2,2'-Bipyridine was first prepared by decarboxylation of divalent metal derivatives of pyridine-2-carboxylate: M(O2CC5H4N)2

Viridin (728 words) [view diff] exact match in snippet view article find links to article

undergoes analogous oxidation at C-18 followed by loss of formic acid or decarboxylation to remove the C-13 methyl. Removal of the side chain has been shown

Pyruvate synthase (971 words) [view diff] exact match in snippet view article find links to article

fixation). Its major role is the extraction of reducing equivalents by the decarboxylation. In aerobic organisms, this conversion is catalysed by pyruvate dehydrogenase

Zomepirac (826 words) [view diff] exact match in snippet view article find links to article

give intermediate 1. Saponification, monoesterification, and thermal decarboxylation gives ester 2. This is acylated with N,N-dimethyl-p-chlorobenzamide

Noscapine (2,869 words) [view diff] exact match in snippet view article find links to article

form 4-hydroxyphenylpyruvic acid (4-HPP), followed by a TPP-mediated decarboxylation to form 4-hydroxyphenylacetaldehyde (4-HPAA). Tyrosine can also be

Pyrimidine metabolism (771 words) [view diff] exact match in snippet view article find links to article

phosphoribosyltransferase OMP PRPP donates a Ribose group. 6 OMP decarboxylase UMP Decarboxylation uridine-cytidine kinase 2 UDP Phosphorylation. ATP is used. nucleoside

Cyanidin (817 words) [view diff] exact match in snippet view article find links to article

mutase enzyme to form prephenate. Prephenate undergoes dehydration, decarboxylation, and transamination with Pyridoxal phosphate (PLP) and alpha-Ketoglutaric

Cyanidin (817 words) [view diff] exact match in snippet view article find links to article

mutase enzyme to form prephenate. Prephenate undergoes dehydration, decarboxylation, and transamination with Pyridoxal phosphate (PLP) and alpha-Ketoglutaric

Sulindac (1,004 words) [view diff] exact match in snippet view article find links to article

gives intermediate diester (3), saponification of which and subsequent decarboxylation leads to 4. {Alternatively it can be formed by Perkin reaction between

Carbidopa (1,120 words) [view diff] exact match in snippet view article find links to article

and α-methyldopa. Carbidopa, an inhibitor of aromatic amino acid decarboxylation, is a white, crystalline compound, slightly soluble in water, with

Methylamine (992 words) [view diff] exact match in snippet view article find links to article

hydrochloric acid. Another method of methylamine production is spontaneous decarboxylation of glycine with a strong base in water.[citation needed] Methylamine

C4 carbon fixation (4,484 words) [view diff] exact match in snippet view article find links to article

grouped in three subtypes, differentiated by the main enzyme used for decarboxylation ( NADP-malic enzyme, NADP-ME; NAD-malic enzyme, NAD-ME; and PEP carboxykinase

4-Ethylphenol (391 words) [view diff] exact match in snippet view article find links to article

perfumery. 4-EP is biosynthesized in two steps from p-coumaric acid. Decarboxylation gives 4-vinylphenol as catalyzed by the enzyme cinnamate decarboxylase

Thiamine pyrophosphate (868 words) [view diff] exact match in snippet view article find links to article

alpha-ketoglutarate dehydrogenase, and transketolase, TPP catalyses the reversible decarboxylation reaction (aka cleavage of a substrate compound at a carbon-carbon bond

Ethylvanillin (208 words) [view diff] exact match in snippet view article find links to article

corresponding mandelic acid derivative (2), which by oxidation (3) and decarboxylation, gives ethylvanillin (4). As a flavorant, ethylvanillin is about three

Hentriacontanonaene (547 words) [view diff] exact match in snippet view article find links to article

OleD. The remaining steps include decarboxylation and dehydration, which might be combined as a single decarboxylation elimination step. The exact roles

Piperylene (180 words) [view diff] exact match in snippet view article find links to article

upon treatment with sulfur dioxide. Piperylene is the product of the decarboxylation of sorbic acid, a common anti-mold agent. Piperylene is obtained as

Pyocyanin (1,971 words) [view diff] exact match in snippet view article find links to article

reaction, HHPDC, is unstable and spontaneously undergoes oxidative decarboxylation in an uncatalyzed reaction to form tetrahydrophenazine-1,6-carboxylic

Cycloheptanone (378 words) [view diff] exact match in snippet view article find links to article

+ (CH2)6CO Cycloheptanone is still produced by the cyclization and decarboxylation of suberic acid or suberic acid esters. This reaction is typically

Catecholamine (2,050 words) [view diff] exact match in snippet view article find links to article

AADC.[citation needed] In neurons that use DA as the transmitter, the decarboxylation of L-DOPA to dopamine is the final step in formation of the transmitter;

Barium hydroxide (926 words) [view diff] exact match in snippet view article find links to article

hendecanedioate. Barium hydroxide has also been used, as well, in the decarboxylation of amino acids liberating barium carbonate in the process. It is also

Ibogaine (5,783 words) [view diff] exact match in snippet view article find links to article

spontaneous decarboxylation can convert (-)-voacangine to (-)-ibogaine. The second pathway consists of PNAE1 and the spontaneous decarboxylation occurring

Acetoacetic acid (1,053 words) [view diff] exact match in snippet view article find links to article

That is, it reacts about 55 times more slowly. The corresponding decarboxylation of trifluoroacetoacetate is used to prepare trifluoroacetone: CF3C(O)CH2CO2H

Isobutyraldehyde (362 words) [view diff] exact match in snippet view article find links to article

α-Ketoisovalerate, derived from oxidative deamination of valine, is prone to decarboxylation to give isobutyraldehyde, which is susceptible to reduction to the

Ethanolamine (1,339 words) [view diff] exact match in snippet view article find links to article

molecules exist in interstellar space. Ethanolamine is biosynthesized by decarboxylation of serine: HOCH 2CH(CO 2H)NH 2 → HOCH 2CH 2NH 2 + CO2 Derivatives of

Japp–Klingemann reaction (468 words) [view diff] exact match in snippet view article find links to article

and 3,4-dihydrobenz[cd]indol-5(1H)-one (Uhle's ketone) via a novel decarboxylation of indole-2-carboxylates". J. Org. Chem. 49 (17): 3195–3199. doi:10

Kochi (disambiguation) (422 words) [view diff] exact match in snippet view article

replacements of proprietary fonts Kochi reaction, an organic reaction for the decarboxylation of carboxylic acids to alkyl halides Kochi (kuih), a Malay-style cake

Aminoaldehydes and aminoketones (353 words) [view diff] exact match in snippet view article find links to article

[CH3C(O)CH2NH3]Cl is readily isolable. Aminoacetone is derived from decarboxylation of alanine. Aminoacetaldehyde is produced by the hydroxylation of taurine

Translocase (2,999 words) [view diff] exact match in snippet view article find links to article

triphosphate EC 7.2.4 Translocation of inorganic cations linked to decarboxylation An important translocase contained in this group is Na+/K+ pump, also

Jasmonic acid (1,125 words) [view diff] exact match in snippet view article find links to article

can also be conjugated to amino acids in some biological contexts. Decarboxylation affords the related fragrance jasmone. Demole, E.; Lederer, E.; Mercier

Mucic acid (326 words) [view diff] exact match in snippet view article find links to article

potassium bisulfate mucic acid forms 3-hydroxy-2-pyrone by dehydration and decarboxylation. Mucic acid can be used to replace tartaric acid in self-raising flour

Sodium acetate (1,261 words) [view diff] exact match in snippet view article find links to article

CH3COONa + BrCH2CH3 → CH3COOCH2CH3 + NaBr Sodium acetate undergoes decarboxylation to form methane (CH4) under forcing conditions (pyrolysis in the presence

Catalpol (502 words) [view diff] exact match in snippet view article find links to article

geniposidic acid, is furnished via hydrolysis of C10, and then a decarboxylation to remove the carboxylic acid at C4 provides bartsioside. The very

Korsakoff syndrome (2,186 words) [view diff] exact match in snippet view article find links to article

places, mental excitation, and euphoria. Thiamine is essential for the decarboxylation of pyruvate, and deficiency during this metabolic process is thought

Guaiacol (1,127 words) [view diff] exact match in snippet view article find links to article

is oxidized to produce phenylglyoxylic acid. This acid undergoes a decarboxylation to afford vanillin. The crude vanillin product can then be purified

2,6-Lutidine (610 words) [view diff] exact match in snippet view article find links to article

6-dimethyl-1,4-dihydropyridine, which, after hydrolysis, undergoes decarboxylation. It is produced industrially by the reaction of formaldehyde, acetone

Polyketide (2,213 words) [view diff] exact match in snippet view article find links to article

methylmalonyl-CoA). The condensation reaction is accompanied by the decarboxylation of the extender unit, yielding a beta-keto functional group and releasing

4-Aminobenzoic acid (1,261 words) [view diff] exact match in snippet view article find links to article

pathway in which PABA is oxidized by O2 via hydrogen abstraction and decarboxylation. In the past, PABA was widely used in sunscreens as a UV filter. It

Anisomycin (573 words) [view diff] exact match in snippet view article find links to article

because tracking of radioactivity indicated that tyrosine undergoes decarboxylation during fermentation. Anisomycin is used as a component of Martin Lewis

Reporter gene (1,980 words) [view diff] exact match in snippet view article find links to article

"Phototransformation of green fluorescent protein with UV and visible light leads to decarboxylation of glutamate 222". Nature Structural Biology. 9 (1): 37–41. doi:10

Glycerol-3-phosphate dehydrogenase (2,206 words) [view diff] exact match in snippet view article find links to article

NADH and 2 ATP via a series of 5 enzymes. (F) Alcoholic fermentation; decarboxylation of pyruvate by pyruvate decarboxylase, followed by reduction of acetaldehyde

Yoshito Kaziro (3,150 words) [view diff] exact match in snippet view article find links to article

Kaziro and his team found that the mechanism for the carboxylation and decarboxylation of the propionyl carboxylase enzyme takes place over two reactions

Isopentenyl-diphosphate delta isomerase (1,421 words) [view diff] exact match in snippet view article find links to article

"Studies on the biosynthesis of cholesterol. XX. Steric course of decarboxylation of 5-pyrophosphomevalonate and of the carbon to carbon bond formation

N,N'-Dicyclohexylcarbodiimide (993 words) [view diff] exact match in snippet view article find links to article

a peak at about 139 ppm downfield from TMS. DCC is produced by the decarboxylation of cyclohexylisocyanate using phosphine oxides as a catalyst: 2 C6H11NCO

Malonyl-CoA decarboxylase (1,922 words) [view diff] exact match in snippet view article find links to article

9 - malonyl-CoA decarboxylase". Hayaishi O (Jul 1955). "Enzymatic decarboxylation of malonic acid". The Journal of Biological Chemistry. 215 (1): 125–36

Tyrosine decarboxylase (128 words) [view diff] exact match in snippet view article find links to article

cofactor, pyridoxal phosphate. McGilvery RW, Cohen PP (July 1948). "The decarboxylation of L-phenylalanine by Streptococcus faecalis R". The Journal of Biological

Fatty acid metabolism (5,569 words) [view diff] exact match in snippet view article find links to article

turn of the cycle, two carbon atoms leave the cycle as CO2 in the decarboxylation reactions catalyzed by isocitrate dehydrogenase and alpha-ketoglutarate

Nucleotide (3,299 words) [view diff] exact match in snippet view article find links to article

monophosphate (UMP). PRPP transferase catalyzes both the ribosylation and decarboxylation reactions, forming UMP from orotic acid in the presence of PRPP. It

O-Cresol (488 words) [view diff] exact match in snippet view article find links to article

Many other production methods have been examined, including oxidative decarboxylation of salicylic acid, oxygenation of toluene, and hydrolysis of 2-chlorotoluene

Novobiocin (2,266 words) [view diff] exact match in snippet view article find links to article

shikimic acid biosynthetic pathway. The enzyme NovF catalyzes the decarboxylation of prephenate while simultaneously reducing nicotinamide adenine dinucleotide

Malate synthase (2,446 words) [view diff] exact match in snippet view article find links to article

In this cycle, isocitrate lyase and malate synthase skip over the decarboxylation steps of the citric acid cycle. In other words, malate synthase works

Mesaconic acid (301 words) [view diff] exact match in snippet view article find links to article

which is first converted to itaconic anhydride by dehydration and decarboxylation. Itaconic acid anhydride is isomerized to citraconic anhydride, which

BCKDHA (2,087 words) [view diff] exact match in snippet view article find links to article

chromosomes was defecting the urine. He found the gene on the level of the decarboxylation of the branched-chain amino acids. The cytogenetic location of BCKDHA

Indole-3-carboxylate decarboxylase (94 words) [view diff] exact match in snippet view article find links to article

reversible indole-3-carboxylate decarboxylase catalyzing nonoxidative decarboxylation". Bioscience, Biotechnology, and Biochemistry. 66 (11): 2388–94. doi:10

Nucleotide (3,299 words) [view diff] exact match in snippet view article find links to article

monophosphate (UMP). PRPP transferase catalyzes both the ribosylation and decarboxylation reactions, forming UMP from orotic acid in the presence of PRPP. It

Methionine (2,980 words) [view diff] exact match in snippet view article find links to article

chloroethylmethylsulfide (ClCH2CH2SCH3) followed by hydrolysis and decarboxylation. Also see Methanol. Methionine supplementation benefit those suffering

Hydroxypyruvate decarboxylase (99 words) [view diff] case mismatch in snippet view article find links to article

dicarboxylate metabolism. HEDRICK JL, SALLACH HJ (1964). "THE NONOXIDATIVE DECARBOXYLATION OF HYDROXYPYRUVATE IN MAMMALIAN SYSTEMS". Arch. Biochem. Biophys. 105

Protocatechuate decarboxylase (114 words) [view diff] exact match in snippet view article find links to article

degradation via hydroxylation. Grant DJ, Patel JC (1969). "The non-oxidative decarboxylation of p-hydroxybenzoic acid, gentisic acid, protocatechuic acid and gallic

IGHG1 (870 words) [view diff] exact match in snippet view article find links to article

S2CID 4306592. Hotta K, Lange H, Tantillo DJ, et al. (2000). "Catalysis of decarboxylation by a preorganized heterogeneous microenvironment: crystal structures

Aldehyde dehydrogenase 5 family, member A1 (868 words) [view diff] exact match in snippet view article find links to article

respiratory electron transport chain protein homotetramerization acetate metabolic process glutamate decarboxylation to succinate Sources:Amigo / QuickGO

BCKDHA (2,087 words) [view diff] exact match in snippet view article find links to article

chromosomes was defecting the urine. He found the gene on the level of the decarboxylation of the branched-chain amino acids. The cytogenetic location of BCKDHA

Polyketide synthase (2,158 words) [view diff] exact match in snippet view article find links to article

Reaction mechanisms of type I, II and III PKSs. Decarboxylation of malonyl unit followed by thio-Claisen condensation. a) (cis-AT) type I PKS with acyl

Gallate decarboxylase (115 words) [view diff] exact match in snippet view article find links to article

degradation via CoA ligation. Grant DJ, Patel JC (1969). "The non-oxidative decarboxylation of p-hydroxybenzoic acid, gentisic acid, protocatechuic acid and gallic

Alanine (2,180 words) [view diff] exact match in snippet view article find links to article

and the citric acid cycle. L-Alanine is produced industrially by decarboxylation of L-aspartate by the action of aspartate 4-decarboxylase. Fermentation

Lipogenesis (2,179 words) [view diff] exact match in snippet view article find links to article

Aerobic respiration Glycolysis → Pyruvate decarboxylation → Citric acid cycle → Oxidative phosphorylation (electron transport chain + ATP synthase) Anaerobic

Metol (489 words) [view diff] exact match in snippet view article find links to article

methods exist for the preparation of N-methylaminophenol. It arises by decarboxylation of N-4-hydroxyphenylglycine (Glycin). It can be obtained by reaction

Asparagusic acid (1,272 words) [view diff] exact match in snippet view article find links to article

treated with hydroiodic acid to yield β,β'-diiodoisobutyric acid after decarboxylation and ester hydrolysis (with removal of volatile ethanol and carbon dioxide)

Ribonucleotide (2,627 words) [view diff] exact match in snippet view article find links to article

yielding orotidine monophosphate (OMP). OMP follows with the decarboxylation by orotidylate decarboxylase to form the Uridylate (UMP) ribonucleotide

GAD2 (290 words) [view diff] exact match in snippet view article find links to article

metabolic process neurotransmitter biosynthetic process glutamate decarboxylation to succinate chemical synaptic transmission neurotransmitter secretion

Gentisate decarboxylase (112 words) [view diff] exact match in snippet view article find links to article

tyrosine metabolism. Grant DJ, Patel JC (1969). "The non-oxidative decarboxylation of p-hydroxybenzoic acid, gentisic acid, protocatechuic acid and gallic

Phloroglucinol (1,959 words) [view diff] exact match in snippet view article find links to article

synthesis begins with the condensation of three malonyl-CoAs. Then decarboxylation followed by the cyclization of the activated 3,5-diketoheptanedioate

Weed: The User's Guide (328 words) [view diff] exact match in snippet view article find links to article

"smartly written pot primer", but misses some information like quick decarboxylation of cannabis in a home oven. One critic said the book was "testament

Enzyme inhibitor (11,575 words) [view diff] exact match in snippet view article find links to article

can catalyse the decarboxylation of DFMO instead of ornithine (see the "DFMO inhibitor mechanism" diagram). However, this decarboxylation reaction is followed

Phenyl salicylate (1,801 words) [view diff] exact match in snippet view article find links to article

→ C6H5O2C6H4OH + CO2 + H2O The conversion entails dehydration and decarboxylation. Heating phenyl salicylate in turn gives xanthone. 2 C6H5O2C6H4OH →

Transition metal oxo complex (1,843 words) [view diff] exact match in snippet view article find links to article

Alpha-ketoglutarate-dependent hydroxylases activate O2 by oxidative decarboxylation of ketoglutarate, generating Fe(IV)=O centers, i.e. ferryl, that hydroxylate

Anacardic acids (1,002 words) [view diff] exact match in snippet view article find links to article

alcohols (cardanols) with reduced activity compared to the acids. Decarboxylation, such as through heating done in most commercial oil processing, results

Aminobenzoate decarboxylase (107 words) [view diff] exact match in snippet view article find links to article

phosphate. McCullough WG, Piligian JT, Daniel IJ (1957). "Enzymatic decarboxylation of three aminobenzoates". J. Am. Chem. Soc. 79 (3): 628–630. doi:10

Rosavin (638 words) [view diff] exact match in snippet view article find links to article

(1,3-sigmatropic rearrangement). Phenolpyruvate is generated by the decarboxylation of prephenate, and the loss of a water molecule. Phenylalanine ammonia

Ketogenesis (2,337 words) [view diff] exact match in snippet view article find links to article

off and used for metabolism. Acetone, which is generated through the decarboxylation of acetoacetate, either spontaneously or through the enzyme acetoacetate

Cell biology (5,258 words) [view diff] exact match in snippet view article find links to article

within the cytosol of the cell to produce pyruvate. Pyruvate undergoes decarboxylation using the multi-enzyme complex to form acetyl coA which can readily

IGKC (852 words) [view diff] exact match in snippet view article find links to article

PMID 10354514. Hotta K, Lange H, Tantillo DJ, et al. (2000). "Catalysis of decarboxylation by a preorganized heterogeneous microenvironment: crystal structures

4-hydroxybenzoate decarboxylase (154 words) [view diff] exact match in snippet view article find links to article

degradation via CoA ligation. Grant DJ, Patel JC (1969). "The non-oxidative decarboxylation of p-hydroxybenzoic acid, gentisic acid, protocatechuic acid and gallic

Camptothecin (2,512 words) [view diff] exact match in snippet view article find links to article

tryptophan. In the next step, tryptamine is produced as the result of decarboxylation by tryptophan decarboxylase (TDC). Secologanin synthesis begins with

Phenol (4,791 words) [view diff] exact match in snippet view article find links to article

Kaeding, Warren W. (1 September 1964). "Oxidation of Aromatic Acids. IV. Decarboxylation of Salicylic Acids". The Journal of Organic Chemistry. 29 (9): 2556–2559

Cell biology (5,258 words) [view diff] exact match in snippet view article find links to article

within the cytosol of the cell to produce pyruvate. Pyruvate undergoes decarboxylation using the multi-enzyme complex to form acetyl coA which can readily

4-hydroxybenzoate decarboxylase (154 words) [view diff] exact match in snippet view article find links to article

degradation via CoA ligation. Grant DJ, Patel JC (1969). "The non-oxidative decarboxylation of p-hydroxybenzoic acid, gentisic acid, protocatechuic acid and gallic

Transition metal NHC complex (532 words) [view diff] exact match in snippet view article find links to article

silver(I) oxide with the imidazolium salt. A third method involves decarboxylation of NHC-carboxylates. In this approach, N-methylimidazoles react with

Enzyme inhibitor (11,575 words) [view diff] exact match in snippet view article find links to article

can catalyse the decarboxylation of DFMO instead of ornithine (see the "DFMO inhibitor mechanism" diagram). However, this decarboxylation reaction is followed

Oxalate decarboxylase (214 words) [view diff] exact match in snippet view article find links to article

2UYA, and 2UYB. HAYAISHI O, JAKOBY WB, OHMURA E (1956). "Enzymatic decarboxylation of oxalic acid". J. Biol. Chem. 222 (1): 435–46. PMID 13367015. Tanner

Profadol (221 words) [view diff] exact match in snippet view article find links to article

Hydrolysis of both nitrile groups, saponification of the ester and decarboxylation gives the diacid, CID:164137621 (3). Imide formation occurs upon treatment

Biotin-independent malonate decarboxylase (417 words) [view diff] exact match in snippet view article find links to article

(December 1999). "Functional evaluation of the genes involved in malonate decarboxylation by Acinetobacter calcoaceticus". European Journal of Biochemistry.

Alpha-Phenylcinnamic acid (278 words) [view diff] exact match in snippet view article find links to article

ultraviolet light into a mixture containing nearly 50% of the Z isomer. Decarboxylation of α-phenylcinnamic acid yields stilbene, with the (E) isomer producing

Sodium trichloroacetate (331 words) [view diff] exact match in snippet view article find links to article

useful for introducing the trichloromethyl group into other molecules. Decarboxylation produces the trichloromethyl anion, which is a sufficiently strong

Biotin-dependent malonate decarboxylase (354 words) [view diff] exact match in snippet view article find links to article

"Stereochemical course of malonate decarboxylase in Malonomonas rubra has biotin decarboxylation with retention". J. Am. Chem. Soc. 117 (3): 1153–1154. doi:10.1021/ja00108a042

Enterochromaffin cell (1,931 words) [view diff] exact match in snippet view article find links to article

non-rate limiting L-amino acid decarboxylase converts 5-HTP to 5-HT by decarboxylation. Following synthesis, 5-HT is then stored in vesicles by vesicular

Nitrile anion (999 words) [view diff] exact match in snippet view article find links to article

solutions to this problem exist. Alkylation of cyanoacetates followed by decarboxylation provides one solution. Polyanions of nitriles can also be generated

Salicylic acid (3,439 words) [view diff] exact match in snippet view article find links to article

Kaeding WW (1 September 1964). "Oxidation of Aromatic Acids. IV. Decarboxylation of Salicylic Acids". The Journal of Organic Chemistry. 29 (9): 2556–2559

Malonyl-S-ACP decarboxylase (272 words) [view diff] exact match in snippet view article find links to article

(December 1999). "Functional evaluation of the genes involved in malonate decarboxylation by Acinetobacter calcoaceticus". European Journal of Biochemistry.

Macrophomic acid (540 words) [view diff] exact match in snippet view article find links to article

bicyclic intermediate (5). Finally, this bicyclic compound undergoes a decarboxylation to form intermediate 6 and dehydration to form macrophomic acid (7)

Cardiac fibrosis (2,834 words) [view diff] exact match in snippet view article find links to article

generally administered along with carbidopa, which prevents the peripheral decarboxylation of 5-HTP to serotonin and so ensures that only brain serotonin levels

Clavaminate synthase (292 words) [view diff] exact match in snippet view article find links to article

iron enzyme clavaminate synthase 2: Coupling mechanism of oxidative decarboxylation and hydroxylation". J. Am. Chem. Soc. 120: 13539–13540. doi:10.1021/ja983534x

Robert Walker Hay (224 words) [view diff] exact match in snippet view article find links to article

Wellington, University of Sterling, St Andrews University Thesis The catalysed decarboxylation of oxaloacetic acid. (1960) Doctoral students Kevin Tate

Vanillin (3,762 words) [view diff] exact match in snippet view article find links to article

4-Hydroxy-3-methoxyphenylglyoxylic acid (3) to vanillin (4) by oxidative decarboxylation. 15% of the world's production of vanillin is produced from lignosulfonates

GAD1 (1,125 words) [view diff] exact match in snippet view article find links to article

biosynthetic process protein-pyridoxal-5-phosphate linkage glutamate decarboxylation to succinate chemical synaptic transmission social behavior locomotory

Communesin B (411 words) [view diff] exact match in snippet view article find links to article

molecules processed by different pathways. The first pathway involves a decarboxylation step catalyzed by CnsB to produce tryptamine. The second pathway starts

2-hydroxy-3-oxoadipate synthase (202 words) [view diff] exact match in snippet view article find links to article

1021/bi00841a042. PMID 4320439. Stewart PR, Quayle JR (1967). "The synergistic decarboxylation of glyoxalate and 2-oxoglutarate by an enzyme system from pig-liver

Malonate CoA-transferase (143 words) [view diff] exact match in snippet view article find links to article

metabolism and propanoate metabolism. Hayaishi O (July 1955). "Enzymatic decarboxylation of malonic acid". The Journal of Biological Chemistry. 215 (1): 125–36

UDP-arabinose 4-epimerase (152 words) [view diff] exact match in snippet view article find links to article

FEINGOLD DS, NEUFELD EF, HASSID WZ (1960). "The 4-epimerization and decarboxylation of uridine diphosphate D-glucuronic acid by extracts from Phaseolus

Azaspiracid (2,766 words) [view diff] exact match in snippet view article find links to article

Philipp (2009). "Formation of Azaspiracids-3, -4, -6, and -9 via Decarboxylation of Carboxyazaspiracid Metabolites from Shellfish". Journal of Agricultural

Leaving group (2,532 words) [view diff] exact match in snippet view article find links to article

expulsion of an extremely poor leaving group, R2N−. Even more dramatic, decarboxylation of benzoate anions can occur by heating with copper or Cu2O, involving

Maple syrup urine disease (3,409 words) [view diff] exact match in snippet view article find links to article

into acetoacetate, acetyl-CoA, and succinyl-CoA through oxidative decarboxylation of α-ketoacids. The BCKAD complex consists of four subunits designated

Malonyl-S-ACP:biotin-protein carboxyltransferase (218 words) [view diff] exact match in snippet view article find links to article

"Stereochemical course of malonate decarboxylase in Malonomonas rubra has biotin decarboxylation with retention". J. Am. Chem. Soc. 117: 1153–1154. doi:10.1021/ja00108a042

Pyruvate carboxylase (2,678 words) [view diff] exact match in snippet view article find links to article

Aerobic respiration Glycolysis → Pyruvate decarboxylation → Citric acid cycle → Oxidative phosphorylation (electron transport chain + ATP synthase) Anaerobic

Prodigiosin (1,405 words) [view diff] exact match in snippet view article find links to article

masked carbanion formed from the pyridoxal phosphate (PLP) mediated decarboxylation of L-serine, which cyclizes in a dehydration reaction to yield the

Uridine monophosphate synthase (3,560 words) [view diff] exact match in snippet view article find links to article

some evidence against this theory. OMP protonation on O4 or O2 before decarboxylation, which entails and ylide formation on N1, has also been considered

Mescaline (4,905 words) [view diff] exact match in snippet view article find links to article

towards the synthesis of mescaline. Tyrosine can either undergo a decarboxylation via tyrosine decarboxylase to generate tyramine and subsequently undergo

UDP-glucuronate 4-epimerase (160 words) [view diff] exact match in snippet view article find links to article

FEINGOLD DS, NEUFELD EF, HASSID WZ (1960). "The 4-epimerization and decarboxylation of uridine diphosphate D-glucuronic acid by extracts from Phaseolus

Isocyanate (3,846 words) [view diff] exact match in snippet view article find links to article

polymer chains known as polyureas. Carbodiimides are produced by the decarboxylation of alkyl and aryl isocyanate using phosphine oxides as a catalyst:

Ene reaction (3,349 words) [view diff] exact match in snippet view article find links to article

therein Dewar, Michael J. S.; Ford, George P. (1977-12-01). "Thermal decarboxylation of but-3-enoic acid. MINDO/3 calculations of activation parameters

Lactate 2-monooxygenase (235 words) [view diff] exact match in snippet view article find links to article

"Enzymatic oxygen fixation into acetate concomitant with the enzymatic decarboxylation of L-lactate". J. Am. Chem. Soc. 79 (17): 4809–4810. doi:10.1021/ja01574a060

Malonyl-S-ACP:biotin-protein carboxyltransferase (218 words) [view diff] exact match in snippet view article find links to article

"Stereochemical course of malonate decarboxylase in Malonomonas rubra has biotin decarboxylation with retention". J. Am. Chem. Soc. 117: 1153–1154. doi:10.1021/ja00108a042

PDPR (559 words) [view diff] exact match in snippet view article find links to article

mitochondrial pyruvate dehydrogenase complex (PDC) catalyzes the oxidative decarboxylation of pyruvate, linking glycolysis to the tricarboxylic acid cycle and

Glycine dehydrogenase (decarboxylating) (1,239 words) [view diff] exact match in snippet view article

cellular amino acid metabolic process glycine metabolic process glycine decarboxylation via glycine cleavage system glycine catabolic process response to methylamine

Penelope Brothers (464 words) [view diff] exact match in snippet view article find links to article

Baker, Penelope J. Brothers, George R. Clark, and David C. Ware. "Decarboxylation of an α-amino acid coordinated to cobalt (III): kinetic stabilisation

Fatty-acyl-CoA synthase (1,667 words) [view diff] exact match in snippet view article find links to article

ACP with Maloyl-CoA by MPT, Claisen condensation at the KS by (5) decarboxylation and (6) nucleophilic attack of the enolate at the carbonyl carbon of

Jasmonate (2,887 words) [view diff] exact match in snippet view article find links to article

et al 2011 for Solanum nigrum's herbivore resistance. JA undergoes decarboxylation to give cis-jasmone. Although jasmonate (JA) regulates many different

Camalexin (558 words) [view diff] exact match in snippet view article find links to article

subsequent unknown enzyme is needed to form dihydrocamalexic acid. A final decarboxylation step by cytochrome P450 CYP71B15, also called phytoalexin deficient4

Marinobacter hydrocarbonoclasticus (1,037 words) [view diff] exact match in snippet view article find links to article

α-hydroxy acid siderophore that readily undergoes a light-mediated decarboxylation reaction when bound to Fe(III).” Marinobacter hydrocarbonoclastus degrade

Aspartate 4-decarboxylase (321 words) [view diff] exact match in snippet view article find links to article

"Inhibition of aspartate beta-decarboxylase by aminomalonate Stereospecific decarboxylation of aminomalonate to glycine". Biochemistry. 9 (11): 2310–5. doi:10

Burkholderia gladioli (1,741 words) [view diff] exact match in snippet view article find links to article

negative B. gladioli is indole negative, nitrate negative, and lysine decarboxylation negative. On the molecular level, PCR can be used to distinguish between

Malonomonas (203 words) [view diff] exact match in snippet view article find links to article

nov. sp. nov., a microaerotolerant anaerobic bacterium growing by decarboxylation of malonate". Archives of Microbiology. 151 (5): 427–433. doi:10.1007/BF00416602

2,4,6-Trinitrobenzoic acid (169 words) [view diff] exact match in snippet view article find links to article

with dichromate. Upon heating, 2,4,6-trinitrobenzoic acid undergoes decarboxylation to give 1,3,5-trinitrobenzene. Reduction with tin gives 2,4,6-triaminobenzenoic

5-Ethyl-2-methylpyridine (209 words) [view diff] exact match in snippet view article find links to article

5-ethyl-2-methylpyridine with nitric acid gives nicotinic acid via the decarboxylation of 2,5-pyridinedicarboxylic acid. Like most alkylpyridines, the LD50

Quinine (6,724 words) [view diff] exact match in snippet view article find links to article

modification of strictosidine leads to an aldehyde. Hydrolysis and decarboxylation would initially remove one carbon from the iridoid portion and produce

2-Furoic acid (1,165 words) [view diff] exact match in snippet view article find links to article

PMID 17408308. S2CID 42398133. Hucker, B.; Varelis, P. (2011). "Thermal decarboxylation of 2-furoic acid and its implication for the formation of furan in

Cholesterol (8,518 words) [view diff] exact match in snippet view article find links to article

isopentenyl pyrophosphate (IPP) through two phosphorylation steps and one decarboxylation step that requires ATP. Three molecules of isopentenyl pyrophosphate

Branched-chain amino acid aminotransferase (3,560 words) [view diff] exact match in snippet view article find links to article

metabolism, a reversible transamination followed by the oxidative decarboxylation of the transamination products α-ketoisocaproate, α-keto-β-methylvalerate

4-hydroxybenzoate 1-hydroxylase (205 words) [view diff] exact match in snippet view article find links to article

4-hydroxybenzoate in Candida parapsilosis proceeds through initial oxidative decarboxylation by a FAD-dependent 4-hydroxybenzoate 1-hydroxylase". FEMS Microbiol

Harpagoside (468 words) [view diff] exact match in snippet view article find links to article

Carboxylation followed by glycosylation leads to the glycoside. Subsequent decarboxylation and three p450-type oxidations leads to harpagide. Cinnamoyl esterification

Algae fuel (11,959 words) [view diff] exact match in snippet view article find links to article

currently the most common pathway to produce fuel-like hydrocarbons via decarboxylation/decarbonylation, there is an alternative process offering a number

Ergine (2,202 words) [view diff] exact match in snippet view article find links to article

of 4-DMA-L-abrine to chanoclavine-I is thought to occur through a decarboxylation and two oxidation steps, catalyzed by the FAD dependent oxidoreductase

Prunasin (1,332 words) [view diff] exact match in snippet view article find links to article

L-phenylalanine is first hydroxylated by CYP79D16, followed by a decarboxylation and dehydration, forming the E-oxime phenylacetaldoxime. Next, CYP71AN24

(E)-Stilbene (1,849 words) [view diff] exact match in snippet view article

trans-C6H5–CH=CH–C6H5 Both isomers of stilbene can be produced by decarboxylation of α-phenylcinnamic acid, trans-stilbene being produced from the (Z)-isomer

Salvinorin A (3,838 words) [view diff] exact match in snippet view article find links to article

glycolysis, are converted into 1-deoxy-D-xylulose 5-phosphate via decarboxylation. Subsequent reduction with NADPH generates 2C-methyl-D-erythritol 2

A3 coupling reaction (848 words) [view diff] exact match in snippet view article find links to article

792-795 doi:10.1002/anie.200805122;Aldehyde- and Ketone-Induced Tandem Decarboxylation-Coupling (Csp3−Csp) of Natural α-Amino Acids and Alkynes Hai-Peng Bi

(E)-Stilbene (1,849 words) [view diff] exact match in snippet view article

trans-C6H5–CH=CH–C6H5 Both isomers of stilbene can be produced by decarboxylation of α-phenylcinnamic acid, trans-stilbene being produced from the (Z)-isomer

Harpagoside (468 words) [view diff] exact match in snippet view article find links to article

Carboxylation followed by glycosylation leads to the glycoside. Subsequent decarboxylation and three p450-type oxidations leads to harpagide. Cinnamoyl esterification

Spirotryprostatin B (871 words) [view diff] exact match in snippet view article find links to article

stereochemistry at the spirocyclic ring juncture is established by a decarboxylation-prenylation sequence, reminiscent of the Carroll reaction. Here, a

Carl Neuberg (1,158 words) [view diff] exact match in snippet view article find links to article

decarboxylase (EC 4.1.1.1, then called just "carboxylase") which catalyzes the decarboxylation of pyruvate to produce acetate. He also introduced methods for trapping

Texaphyrin (1,508 words) [view diff] exact match in snippet view article find links to article

diacid (III) which is subsequently converted to the aldehyde via a decarboxylation-formylation sequence similar to a Clezy formylation. The dialdehyde

2-Succinyl-5-enolpyruvyl-6-hydroxy-3-cyclohexene-1-carboxylic-acid synthase (370 words) [view diff] exact match in snippet view article find links to article

All of the organisms share something in common, being that catalyze decarboxylation reactions. "Enzyme entry EC: 2.2.1.9". ExPASy. "The Enzyme List Class

Pyruvate dehydrogenase (lipoamide) beta (2,629 words) [view diff] exact match in snippet view article

The pyruvate dehydrogenase complex is responsible for the oxidative decarboxylation of pyruvate, with the final product being Acetyl CoA. Overall the complex

Rosefuran (753 words) [view diff] exact match in snippet view article find links to article

methyl ester of 4-bromo-5-methyl-2-furancarboxylic acid followed by decarboxylation. Alternatively, rosefuran has been prepared from other furan derivatives

Pyruvate dehydrogenase (lipoamide) alpha 1 (2,885 words) [view diff] exact match in snippet view article

The pyruvate dehydrogenase complex is responsible for the oxidative decarboxylation of pyruvate, with the final product being Acetyl CoA. Overall the complex

N-Methyltyramine (2,028 words) [view diff] exact match in snippet view article find links to article

for making NMT was given by Corti, who prepared it by the thermal decarboxylation of N-methyltyrosine (ratanhin), by heating the amino-acid in fluorene

Flavin prenyltransferase (UbiX) (765 words) [view diff] exact match in snippet view article

D, et al. (June 2015). "New cofactor supports α,β-unsaturated acid decarboxylation via 1,3-dipolar cycloaddition". Nature. 522 (7557): 497–501. Bibcode:2015Natur

GCSH (1,457 words) [view diff] exact match in snippet view article find links to article

glycine cleavage complex mitochondrion Biological process glycine decarboxylation via glycine cleavage system glycine catabolic process methylation protein

EC 4.1.1.102 (184 words) [view diff] exact match in snippet view article find links to article

Kawamukai M, Iefuji H (2010). "PAD1 and FDC1 are essential for the decarboxylation of phenylacrylic acids in Saccharomyces cerevisiae". J. Biosci. Bioeng

PET bottle recycling (5,849 words) [view diff] exact match in snippet view article find links to article

groups, e.g. formation of vinyl ester end groups through dehydration or decarboxylation of terephthalate acid, reaction of the OH- or COOH- end groups with

Phytane (2,160 words) [view diff] exact match in snippet view article find links to article

conditions by phytol oxidation to phytenic acid, which may then undergo decarboxylation to pristene, before finally being reduced to pristane. In contrast

Stygiella (1,276 words) [view diff] exact match in snippet view article find links to article

transfer chain but contain proteins for eubacterium-like pyruvate decarboxylation, such as pyruvate:ferredoxin oxidoreductase and [FeFe]-hydrogenase

Agmatidine (1,086 words) [view diff] exact match in snippet view article find links to article

agmatine to the C2-oxo group of cytidine by TiaS. Agmatine in turn is a decarboxylation product of arginine (an aminoacid present in all cells). Agmatidine

Pulvinone (1,581 words) [view diff] exact match in snippet view article find links to article

formed by a sequence of dimerisation, oxidative ring-cleavage and decarboxylation.[page range too broad] Jacob Volhard was the first to synthesise vulpinic

Coniine (3,314 words) [view diff] exact match in snippet view article find links to article

into trimethyl indolizine-tricarboxylate. This, on hydrolysis and decarboxylation, furnishes indolizine, the octahydro-derivate of which, also known

Lester O. Krampitz (988 words) [view diff] exact match in snippet view article find links to article

Krampitz, Lester Orville; Werkman, Chester Hamlin (1941). "The enzymic decarboxylation of oxaloacetate". Biochemical Journal. 35 (5–6): 595–602. doi:10.1042/bj0350595

Undecaprenyl-phosphate 4-deoxy-4-formamido-L-arabinose transferase (247 words) [view diff] exact match in snippet view article find links to article

Breazeale SD, Ribeiro AA, Raetz CR (January 2002). "Oxidative decarboxylation of UDP-glucuronic acid in extracts of polymyxin-resistant Escherichia

Ethylene oxide (11,529 words) [view diff] exact match in snippet view article find links to article

(750 psi)) yielding ethylene carbonate and its subsequent hydrolysis with decarboxylation: ( CH 2 CH 2 ) O + CO 2 ⟶ ( O − CH 2 CH 2 − O ) C = O ethylene carbonate

GalP (protein) (1,807 words) [view diff] exact match in snippet view article

is an important substrate to have for metabolic processes such as decarboxylation of oxaloacetate (6). A H+/amino acid symporter BrnQ can be found in

Jirō Tsuji (1,032 words) [view diff] exact match in snippet view article find links to article

Shimizu, Isao; Tsuji, Jiro (October 1982). "Palladium-catalyzed decarboxylation-dehydrogenation of allyl .beta.-oxo carboxylates and allyl enol carbonates

Hans Baruch (1,871 words) [view diff] exact match in snippet view article find links to article

incubation flask described by Baruch and Chaikoff (1) for tissue slices and decarboxylation studies has gained widespread popularity." In other publications the

Jacob Hooker (2,574 words) [view diff] exact match in snippet view article find links to article

first example of radiofluorination with fluoride-18 using C-H and decarboxylation with manganese catalysts. A new application for radiolabeled glucose:

4-Ipomeanol (3,270 words) [view diff] exact match in snippet view article find links to article

4-(ethoxycarbonyl)furan-3-carboxylic acid (II) occurs. This is followed by decarboxylation by heating with a copper powder yielded ethyl 3-furoate (III). The

Mitochondria associated membranes (1,419 words) [view diff] exact match in snippet view article find links to article

Transport of phosphatidylserine into mitochondria from the ER for decarboxylation to phosphatidylethanolamine through the ER-mitochondria lipid which

Neuroendocrine tumor (8,013 words) [view diff] exact match in snippet view article find links to article

often show amine precursor (L-DOPA and 5-hydroxytryptophan) uptake and decarboxylation to produce biogenic amines such as catecholamines and serotonin. Although

Chloroplast (18,774 words) [view diff] exact match in snippet view article find links to article

to form the majority of the lipid is from acetyl-CoA, which is the decarboxylation product of pyruvate. Pyruvate may enter the plastid from the cytosol

Energy development (12,804 words) [view diff] exact match in snippet view article find links to article

Europe. However, research is underway on producing renewable fuels from decarboxylation In 2010, worldwide biofuel production reached 105 billion liters (28