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Find link is a tool written by Edward Betts.Longer titles found: Free-radical halogenation (view), Hell–Volhard–Zelinsky halogenation (view), Ketone halogenation (view), Electrophilic halogenation (view), Darzens halogenation (view), Dehalogenation (view), Reductive dehalogenation of halo ketones (view), Hydrohalogenation (view), Transhalogenation (view)
searching for Halogenation 133 found (261 total)
alternate case: halogenation
Friedel–Crafts reaction
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The Friedel–Crafts reactions are a set of reactions developed by Charles Friedel and James Crafts in 1877 to attach substituents to an aromatic ring. Friedel–CraftsMabuterol (404 words) [view diff] exact match in snippet view article find links to article
Mabuterol is a selective β2 adrenoreceptor agonist. The halogenation of 2-(Trifluoromethyl)aniline [88-17-5] (1) with iodine and sodium bicarbonate resultedEther (1,835 words) [view diff] no match in snippet view article find links to article
In organic chemistry, ethers are a class of compounds that contain an ether group—an oxygen atom bonded to two organyl groups (e.g., alkyl or aryl). TheyHydantoin (773 words) [view diff] no match in snippet view article find links to article
Hydantoin, or glycolylurea, is a heterocyclic organic compound with the formula CH2C(O)NHC(O)NH. It is a colorless solid that arises from the reactionOrganoboron chemistry (2,451 words) [view diff] exact match in snippet view article find links to article
the boron atom may convert to halide, but disiamylborane permits only halogenation of the hydroborated olefin: Treatment of an alkenylborane with iodineHalonium ion (1,070 words) [view diff] exact match in snippet view article find links to article
3-membered cyclic variety commonly proposed as intermediates in electrophilic halogenation may be called haliranium ions, using the Hantzsch-Widman nomenclatureSulfonic acid (1,833 words) [view diff] no match in snippet view article find links to article
In organic chemistry, sulfonic acid (or sulphonic acid) refers to a member of the class of organosulfur compounds with the general formula R−S(=O)2−OHSilyl enol ether (1,369 words) [view diff] exact match in snippet view article find links to article
stable carbocations in the presence of Lewis acids like TiCl4 or SnCl4. Halogenation of silyl enol ethers gives haloketones. Acyloins form upon organic oxidationAllyl bromide (430 words) [view diff] no match in snippet view article find links to article
Allyl bromide (3-bromopropene) is an organic halide. It is an alkylating agent used in synthesis of polymers, pharmaceuticals, perfumes and other organicClocortolone (1,151 words) [view diff] exact match in snippet view article find links to article
esterification at C-21, and halogenation at C-6 and C-9. It is common in the medical community to associate halogenation of topical corticosteroids withDiphenyl disulfide (472 words) [view diff] no match in snippet view article find links to article
Diphenyl disulfide is the chemical compound with the formula (C6H5S)2. This colorless crystalline material is often abbreviated Ph2S2. It is one of theFullerene chemistry (4,408 words) [view diff] no match in snippet view article find links to article
Fullerene chemistry is a field of organic chemistry devoted to the chemical properties of fullerenes. Research in this field is driven by the need to functionalizeTriphosgene (645 words) [view diff] exact match in snippet view article find links to article
Triphosgene is stable up to 200 °C. Triphosgene is used in a variety of halogenation reactions. This compound is commercially available. It is prepared byChloride peroxidase (440 words) [view diff] exact match in snippet view article find links to article
catalase and cytochrome P450-like activities in addition to catalyzing halogenation reactions. Despite functional similarities with other heme enzymes, theAlfuzosin (710 words) [view diff] exact match in snippet view article find links to article
6-Nitroveratraldehyde [20357-25-9] (2). Oxidation of the aldehyde to the acid, halogenation with thionyl chloride and amide formation with ammonia gives 4Carbon nanotube chemistry (3,689 words) [view diff] no match in snippet view article find links to article
Carbon nanotube chemistry involves chemical reactions, which are used to modify the properties of carbon nanotubes (CNTs). CNTs can be functionalized toTryptophan 7-halogenase (2,306 words) [view diff] exact match in snippet view article find links to article
the end of the tunnel where the chlorinating agent exits. Multiple halogenations are prevented as the addition of a halogen atom to the substrate greatlySulfolene (1,863 words) [view diff] no match in snippet view article find links to article
Sulfolene, or butadiene sulfone is a cyclic organic chemical with a sulfone functional group. It is a white, odorless, crystalline, indefinitely storableReactivity–selectivity principle (561 words) [view diff] exact match in snippet view article find links to article
found in older organic chemistry textbooks concerns the free radical halogenation of simple alkanes. Whereas the relatively unreactive bromine reacts withGraham reaction (204 words) [view diff] exact match in snippet view article find links to article
displaced by a various nucleophiles. Graham, W. H. (1965-10-01). "The Halogenation of Amidines. I. Synthesis of 3-Halo- and Other Negatively SubstitutedAryl halide (1,804 words) [view diff] exact match in snippet view article find links to article
concerns. Chlorobenzenes are used mainly as solvents. Friedel-Crafts halogenation or "direct chlorination" is the main synthesis route. Lewis acids, eClocinizine (155 words) [view diff] exact match in snippet view article find links to article
4-Chlorobenzophenone [134-85-0] (1) with NBH gives 4-Chlorobenzhydrol [119-56-2] (2). Halogenation of the alcohol in muriatic acid afforded 4-Chlorobenzhydryl chlorideBenzyl bromide (308 words) [view diff] exact match in snippet view article find links to article
bromination of toluene under conditions suitable for a free radical halogenation: The structure has been examined by electron diffraction. Benzyl bromideOxohalide (1,852 words) [view diff] exact match in snippet view article find links to article
state increases by two and the electrical charge is unchanged. Partial halogenation of an oxide: 2 V2O5 + 6 Cl2 + 3 C → 4 VOCl3 + 3 CO2 Oxide replacement:Setoperone (335 words) [view diff] exact match in snippet view article find links to article
3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-5-one, CID:15586462 (1). Halogenation of this with hydrobromic acid in acetic acid gives CID:15586463 (2).Pyrimidine (2,105 words) [view diff] exact match in snippet view article find links to article
substitution is relatively facile at the 5-position, including nitration and halogenation.: 4–8 Reduction in resonance stabilization of pyrimidines may lead to1-Iodomorphine (377 words) [view diff] exact match in snippet view article find links to article
1-Iodomorphine is a semi-synthetic narcotic analgesic formed by halogenation of the 1 position on the morphine carbon skeleton. Halogenated morphine derivativesCyclooctane (476 words) [view diff] exact match in snippet view article find links to article
typical of other saturated hydrocarbons, combustion and free radical halogenation. Work in 2009 on alkane functionalisation, using peroxides such as dicumylTeicoplanin (2,154 words) [view diff] exact match in snippet view article find links to article
and 6 (3-Cl-β-Hty). The halogenase Tei8* has been acts to catalyze the halogenation of both tyrosine residues. Chlorination occurs at the amino acyl-PCPChlorotonil A (553 words) [view diff] exact match in snippet view article find links to article
is a unique functionality in polyketides. In addition to its unique halogenation, the structure of chlorotonil A has also garnered interest due to itsSulfur (10,951 words) [view diff] no match in snippet view article find links to article
Sulfur (also spelled sulphur in British English) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallicDibenzofuran (348 words) [view diff] exact match in snippet view article find links to article
a heat transfer agent. It undergoes electrophilic reactions, such as halogenation and Friedel-Crafts reactions. Reaction of DBF with butyl lithium resultsChloroacetone (380 words) [view diff] exact match in snippet view article find links to article
American Chemical Society. 68 (1): 38–40. doi:10.1021/ja01205a012. ISSN 0002-7863. Phys. Chem. Chem. Phys., 2000,2, 237-245 The Halogenation of CarbonylsOrganogermanium compounds in cross-coupling reactions (1,337 words) [view diff] exact match in snippet view article find links to article
electrophilic halogen sources without transition-metal catalysts to give ipso halogenation product under mild conditions. For the bromination (with NBS) and iodinationHeidelberg University Faculty of Chemistry and Earth Sciences (574 words) [view diff] exact match in snippet view article find links to article
and rates of humification of natural organic matter natural halogenation and de-halogenation of organic molecules development of hyphenated instrumentalMephentermine (605 words) [view diff] exact match in snippet view article find links to article
CID:12640087 (5). Alkylation with iodomethane led to CID:10058106 (6). Halogenation with thionyl chloride gave CID:129921490 (7). Lastly, a Rosenmund reductionPirlindole (398 words) [view diff] exact match in snippet view article find links to article
Imine formation with ethanolamine [141-43-5] (4) gives CID:2838578 (5). Halogenation with phosphorus oxychloride gives (6). Intramolcular alkylation withBambuterol (464 words) [view diff] exact match in snippet view article find links to article
gives 5-Acetyl-1,3-phenylene bis(dimethylcarbamate) [81732-48-1] (3). Halogenation with bromine led to 5-(Bromoacetyl)-1,3-phenylene bis(dimethylcarbamate)Piperoxan (397 words) [view diff] exact match in snippet view article find links to article
anion then leads to 2-hydroxymethyl-1,4-benzodioxane [3663-82-9] (3). Halogenation with thionyl chloride gives 2-chloromethyl-1,4-benzodioxane [2164-33-2]O-Xylene (352 words) [view diff] exact match in snippet view article find links to article
Related to their easy oxidation, the methyl groups are susceptible to halogenation. When treated with elemental bromine, these groups are brominated, yieldingSuproclone (272 words) [view diff] exact match in snippet view article find links to article
7-Chloro-1,8-naphthyridin-2-amine [15944-33-9] (2) gives PC23343647 (3). Halogenation with phosphoryl chloride leads to PC23343652 (4). Reductino with potassiumBromazine (418 words) [view diff] exact match in snippet view article find links to article
para-bromobenzaldehyde [1122-91-4] (1) gives p-bromobenzhydrol [29334-16-5] (2). Halogenation with acetyl bromide in benzene solvent gives p-bromo-benzhydrylbromidePhosphorus tribromide (882 words) [view diff] exact match in snippet view article find links to article
acyl chlorides, they are used as intermediates in Hell-Volhard-Zelinsky halogenation. Initially PBr3 reacts with the carboxylic acid to form the acyl bromideOsmocene (432 words) [view diff] exact match in snippet view article find links to article
Arnold L.; Winter, Charles H. (1995). "Synthesis, Characterization, and Halogenation of Decakis( acetoxymercurio)osmoene. Crystal and Molecular StructurePerchloryl fluoride (781 words) [view diff] exact match in snippet view article find links to article
ISBN 3-527-30691-9. Peter Bernard David De la Mare (1976). Electrophilic halogenation: reaction pathways involving attack by electrophilic halogens on unsaturatedPyrrole (3,142 words) [view diff] exact match in snippet view article find links to article
and halogenating (e.g. NCS, NBS, Br2, SO2Cl2, and KI/H2O2) agents. Halogenation generally provides polyhalogenated pyrroles, but monohalogenation canManifaxine (327 words) [view diff] exact match in snippet view article find links to article
ethylmagnesium bromide gives 3,5-difluoropropiophenone [135306-45-5] (2). Halogenation with molecular bromine occurs at the alpha-keto position providing 2-bromo-3'Salinosporamide A (1,032 words) [view diff] exact match in snippet view article find links to article
their structural similarities.[citation needed] It was thought that the halogenation of the unactivated methyl group was catalyzed by a non-heme iron halogenaseOrganochlorine chemistry (1,909 words) [view diff] exact match in snippet view article find links to article
difficult to control. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst. The haloform reaction, usingOxybuprocaine (514 words) [view diff] exact match in snippet view article find links to article
CID:13346201 (4). The product is crystallized from hydrochloric acid, and then halogenation with thionyl chloride gives 3-butoxy-4-nitrobenzoyl chloride [23442-21-9]Bromfenac (1,002 words) [view diff] exact match in snippet view article find links to article
excreted via the urine, and 13% via the faeces. Compared to amfenac, the halogenation of bromfenac's chemical structure (the bromine atom at C4) increasesRadical substitution (351 words) [view diff] exact match in snippet view article find links to article
created, able to participate in secondary reactions. In free radical halogenation reactions, radical substitution takes place with halogen reagents andOtto Ruff (442 words) [view diff] exact match in snippet view article find links to article
supervision of Carl Magnus von Hell (known from the Hell-Volhard-Zelinsky halogenation) at the University of Stuttgart he joined the group of Hermann Emil FischerCeric ammonium nitrate (817 words) [view diff] exact match in snippet view article find links to article
complicating side reactions usually encountered using other reagents. Oxidative halogenation can be promoted by CAN as an in situ oxidant for benzylic brominationBenzyl group (1,604 words) [view diff] exact match in snippet view article find links to article
substituents exhibit enhanced reactivity, as in oxidation, free radical halogenation, or hydrogenolysis. As a practical example, in the presence of suitableRadicicol (269 words) [view diff] exact match in snippet view article find links to article
monocillin II. This intermediate is transformed to radicicol through halogenation and epoxide formation performed by RadH and RadP respectively. ThesePhendimetrazine (682 words) [view diff] exact match in snippet view article find links to article
synthesis of phendimetrazine (5). {The starting material is prepared by the halogenation of Propiophenone [93-55-0] with bromine.} Alkylation of ephedrine (1)Haloperoxidase (498 words) [view diff] exact match in snippet view article find links to article
halides and hydrogen peroxide are widely available in the environment. Halogenations of organic compounds by free halogens (F2, Cl2, Br2, and sometimes I2)Sematilide (180 words) [view diff] exact match in snippet view article find links to article
mixture gives 4-[(Methylsulfonyl)amino]benzoic acid sodium salt (2). Halogenation with thionyl chloride gives 4-[(Methylsulfonyl)Amino]Benzoyl ChlorideOrganobromine chemistry (1,557 words) [view diff] exact match in snippet view article find links to article
identified in human white blood cells as products of myeloperoxidase-induced halogenation on invading pathogens. In addition to conventional brominated naturalOxazoline (1,757 words) [view diff] exact match in snippet view article find links to article
unsuitable as they preferentially undergo rapid electrophilic aromatic halogenation with the oxidising agent. The use of catalytic amounts of ZnCl2 to generateTropospheric ozone depletion events (997 words) [view diff] exact match in snippet view article find links to article
consumption of ozone and the enhancement of halogens. Arctic haze Free radical halogenation Tropospheric ozone Frost flower (sea ice) Cao, Le; Platt, Ulrich; GutheilPyrene (1,114 words) [view diff] exact match in snippet view article find links to article
undergoes a series of hydrogenation reactions and is susceptible to halogenation, Diels-Alder additions, and nitration, all with varying degrees of selectivityCloperastine (644 words) [view diff] exact match in snippet view article find links to article
in or responsible for the antitussive efficacy of cloperastine. The halogenation of 4-Chlorobenzhydrol [119-56-2] (1) with phosphorus tribromide in tetrachloromethaneCarbonyl bromide (304 words) [view diff] exact match in snippet view article find links to article
contrast to phosgene, carbonyl bromide cannot be produced efficiently by halogenation of carbon monoxide. The bromination of carbon monoxide follows this equation:Alkane (5,928 words) [view diff] exact match in snippet view article find links to article
electrons, play a large role in most reactions of alkanes. Free radical halogenation reactions occur with halogens, leading to the production of haloalkanesPoint of use water filter (1,070 words) [view diff] exact match in snippet view article find links to article
concentrations of halogenated organic species that can be created through the halogenation of organic rich waters as part of the disinfection process at the municipalColumbia-Southern Chemical Corporation (415 words) [view diff] exact match in snippet view article find links to article
Beauharnois, Quebec in Canada. Collected Reprints of McBee's Annual Reviews of Halogenation, 1948–1958: Reprinted from Industrial and Engineering Chemistry for Columbia-SouthernPorphyrin (2,307 words) [view diff] exact match in snippet view article find links to article
6,13,16-Tetrapropylporphycene: Rational Synthesis, Complexation, and Halogenation". The Journal of Organic Chemistry. 87 (5): 2721–2729. doi:10.1021/acsActivated carbon (7,964 words) [view diff] exact match in snippet view article find links to article
EN, Lacroix R, Donnet JB, Nansé GR, Fioux P (1995). "XPS study of the halogenation of carbon black—Part 2. Chlorination". Carbon. 33 (1): 63–72. Bibcode:1995CarboOrganomolybdenum chemistry (1,939 words) [view diff] exact match in snippet view article find links to article
metal vapor synthesis and reductive routes from molybdenum(V) chloride. Halogenation of Mo(CO)6 gives Mo(II) carbonyl halides, which are also versatile precursorsOrganomolybdenum chemistry (1,939 words) [view diff] exact match in snippet view article find links to article
metal vapor synthesis and reductive routes from molybdenum(V) chloride. Halogenation of Mo(CO)6 gives Mo(II) carbonyl halides, which are also versatile precursorsFlumexadol (547 words) [view diff] exact match in snippet view article find links to article
clinically in France as an antidepressant and anxiolytic agent. Ex 1: Halogenation of 2-chloro ethyl vinyl ether [110-75-8] (1) with molecular bromine gives2,6-Dichloroaniline (99 words) [view diff] exact match in snippet view article find links to article
of 2,6-dichloronitrobenzene. In the laboratory, it can be prepared by halogenation of sulfanilamide followed by desulfonation. P. F. Vogt; J. J. GerulisMazindol (1,379 words) [view diff] exact match in snippet view article find links to article
SERT affinity without significant decreases in NET or DAT affinities. Halogenation of 3' and/or 4' position of the phenyl ring of mazindol results in increasedAzaloxan (179 words) [view diff] exact match in snippet view article find links to article
Thymoleptic described as a “psychostimulant” according to patent title. The halogenation of allyl cyanide [109-75-1] (1) with bromine gives 3,4-dibromobutyronitrileBiphenyl (1,358 words) [view diff] exact match in snippet view article find links to article
are useful fungicides. In other substitution reactions, it undergoes halogenation. Polychlorinated biphenyls were once popular pesticides. Lithium biphenylAdenosine A2B receptor (2,090 words) [view diff] exact match in snippet view article find links to article
Maatougui A, Majellaro M, et al. (December 2022). "Exploring the Effect of Halogenation in a Series of Potent and Selective A2B Adenosine Receptor Antagonists"Glaucine (1,401 words) [view diff] exact match in snippet view article find links to article
predicentrine and glaucine derivatives at D1 and D2 dopaminergic receptors: halogenation and D1 receptor selectivity". Bioorganic & Medicinal Chemistry. 13 (11):Ritanserin (1,081 words) [view diff] exact match in snippet view article find links to article
6-(2-hydroxyethyl)-7-methyl-[1,3]thiazolo[3,2-a]pyrimidin-5-one, CID:82612453 (4). Halogenation of the terminal alcohol with phosphorus oxychloride then yields 6-(2-chloroethyl)-Roluperidone (614 words) [view diff] exact match in snippet view article find links to article
4-aminomethylpiperidine-1-carboxylate hydrochloride [359629-16-6] (2). The free-radical halogenation of ethyl o-toluate [87-24-1] (3) led to ethyl 2-(bromomethyl)benzoateCyanogen halide (651 words) [view diff] exact match in snippet view article find links to article
can be obtained by the reaction of halogens with metal cyanides or the halogenation of hydrocyanic acid. M C N + X 2 ⟶ X C N + M X {\displaystyle \mathrmOrtho-Carborane (1,544 words) [view diff] exact match in snippet view article find links to article
catalytic amount of AlCl3 while in refluxing dichloromethane. Exohedral halogenation leads to an increase in the electron withdrawing effect of the carboraneNeophyl chloride (332 words) [view diff] exact match in snippet view article find links to article
H2C=C(CH3)CH2Cl + C6H6 → C6H5C(CH3)2CH2Cl It can also be prepared by free radical halogenation of tert-butylbenzene, using various chlorine donors. Neophyl chlorideRadical (chemistry) (4,457 words) [view diff] exact match in snippet view article
which occurs under light and serves as the driving force for radical halogenation reactions. Another notable reaction is the homolysis of dibenzoyl peroxideSylvie Garneau-Tsodikova (579 words) [view diff] exact match in snippet view article find links to article
Garneau-Tsodikova; Christopher T Walsh (1 August 2006). "Nature's inventory of halogenation catalysts: oxidative strategies predominate". Chemical Reviews. 106 (8):Chloropyridine (139 words) [view diff] exact match in snippet view article find links to article
2-Chloropyridine 3-Chloropyridine 4-Chloropyridine 2,6-Dichloropyridine Direct halogenation of pyridine with chlorine gas above 270 °C gives a mixture of 2-chloropyridineArrow pushing (2,090 words) [view diff] exact match in snippet view article find links to article
single unpaired electron. This is the initiation stage of free radical halogenation. Heterolytic bond cleavage is a process where the electron pair thatOrganoselenium chemistry (2,079 words) [view diff] exact match in snippet view article find links to article
product PhSeMgBr. Selanyl halides (R−Se−Cl, R−Se−Br) are prepared by halogenation of diselenides. Bromination of diphenyldiselenide gives phenylselanylCarborane acid (2,584 words) [view diff] exact match in snippet view article find links to article
boron scientists, Plešek, Štíbr, and Heřmánek improved the process for halogenation of carborane molecules. These findings were instrumental in developingMarinone (448 words) [view diff] exact match in snippet view article find links to article
cyclization to yield the α-chloroepoxide, 6. This is followed by the reductive halogenation of the α-chloroepoxide to yield the hydroxynaphthoquinone, 7. Next, oxidationThomas Lectka (1,390 words) [view diff] exact match in snippet view article find links to article
his term at Johns Hopkins University also focused on enantioselective halogenation, cooperative asymmetric catalysis, the medicinal chemistry of fluorinatedAdenosine receptor antagonist (458 words) [view diff] exact match in snippet view article find links to article
Juan C.; Andújar-Arias, Antonio (2022-12-14). "Exploring the Effect of Halogenation in a Series of Potent and Selective A 2B Adenosine Receptor Antagonists"Mucobromic acid (302 words) [view diff] exact match in snippet view article find links to article
Mucohalic acids have received attention since they are products of the halogenation of biomass. They are genotoxins and potential carcinogens. They haveBromide peroxidase (678 words) [view diff] exact match in snippet view article find links to article
Garneau-Tsodikova, Sylvie; Walsh, Christopher T. (2006). "Nature's Inventory of Halogenation Catalysts: Oxidative Strategies Predominate". Chemical Reviews. 106 (8):Debromomarinone (429 words) [view diff] exact match in snippet view article find links to article
cyclization to yield the α-chloroepoxide, 6. This is followed by the reductive halogenation of the α-chloroepoxide to yield the hydroxynaphthoquinone, 7. Next, oxidationAmpyzine (248 words) [view diff] exact match in snippet view article find links to article
(2); oxidative decarboxylation gives 2-hydroxypyrazine [6270-63-9] (3). Halogenation with PCl5 produces 2-chloropyrazine [14508-49-7] (4). Displacement ofBoronic acid (2,662 words) [view diff] exact match in snippet view article find links to article
hdl:2115/56377. PMID 14680243. S2CID 34802662. Murphy, Jaclyn M. (2007). "Meta Halogenation of 1,3-Disubstituted Arenes via Iridium-Catalyzed Arene Borylation".Acid (5,955 words) [view diff] exact match in snippet view article find links to article
(CH3-CHOH-COOH) Oxalic acid (HOOC-COOH) Tartaric acid (HOOC-CHOH-CHOH-COOH) Halogenation at alpha position increases acid strength, so that the following acidsIUPAC nomenclature of organic chemistry (4,496 words) [view diff] exact match in snippet view article find links to article
then the number is indicated by prefixing with "di-", "tri-" as with halogenation. (CH3)3O+ is trimethyloxonium. CH3F3N+ is trifluoromethylammonium. ChemistryChloroform (5,625 words) [view diff] exact match in snippet view article find links to article
methyl chloride (CH3Cl) or methane (CH4). At 400–500 °C, free radical halogenation occurs, converting these precursors to progressively more chlorinatedBohrium (6,572 words) [view diff] exact match in snippet view article find links to article
acid, HBhO4. Rhenium and technetium form a range of oxyhalides from the halogenation of the oxide. The chlorination of the oxide forms the oxychlorides MO3ClEosinophil peroxidase (2,880 words) [view diff] exact match in snippet view article find links to article
There are three distinct cycles which EPO can undergo. The first is the halogenation cycle: [Fe(III)...Por] + H2O2 → [Fe(IV)=O...Por•+] + H2O where Por denotesLegionella (5,322 words) [view diff] exact match in snippet view article find links to article
differently from chlorine; its action is one of pure oxidation rather than halogenation, so these halogenated byproducts are not formed. Chlorine dioxide doesDioxygenase (2,879 words) [view diff] exact match in snippet view article find links to article
then utilized to carry out various reactions, including hydroxylation, halogenation, and demethylation. In the best characterized case, the hydroxylases3-Bromocytisine (285 words) [view diff] exact match in snippet view article find links to article
Cassels BK, Iturriaga-Vásquez P, Bermudez I, et al. (April 2006). "C3-halogenation of cytisine generates potent and efficacious nicotinic receptor agonists"Chlorine (12,989 words) [view diff] exact match in snippet view article find links to article
easily separated. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst. The haloform reaction, usingImmune checkpoint (3,477 words) [view diff] exact match in snippet view article find links to article
Juan C.; Andújar-Arias, Antonio (2022-12-14). "Exploring the Effect of Halogenation in a Series of Potent and Selective A 2B Adenosine Receptor Antagonists"Marjorie Caserio (1,174 words) [view diff] exact match in snippet view article find links to article
"Stereochemistry of additions of allenes. I. Methoxymercuration and halogenation of 1,3-dimethylallene". Journal of the American Chemical Society. 90Raschig–Hooker process (680 words) [view diff] exact match in snippet view article find links to article
Pale, P; Louis, B (2016). "Eco-compatible zeolite-catalysed continuous halogenation of aromatics". Green Chemistry. 18 (17): 4714–4724. doi:10.1039/C6GC00731GΒk-2C-B (2,916 words) [view diff] exact match in snippet view article find links to article
a ketone. The vicinal primary carbon is easily brominated by ketone halogenation. Then a Delépine reaction is employed to convert the alkyl halide toProtecting group (6,755 words) [view diff] exact match in snippet view article find links to article
hydration. For alkenes two protecting groups are basically known: Temporary halogenation with bromine to a trans‑1,2‑dibromoalkane: the regeneration of the alkeneBoron (12,785 words) [view diff] exact match in snippet view article find links to article
it burns to form boron trioxide: 4 B + 3 O2 → 2 B2O3 Boron undergoes halogenation to give trihalides; for example, 2 B + 3 Br2 → 2 BBr3 The trichlorideProline organocatalysis (1,841 words) [view diff] exact match in snippet view article find links to article
Mannich reaction, Michael reaction, amination, α-oxyamination, and α-halogenation. Modifications on the basic proline structure improved the enantioselectivityΑ-Halo carboxylic acids and esters (483 words) [view diff] exact match in snippet view article find links to article
Cl2 → RCHClCO2R' + HCl A related method is the Hell-Volhard-Zelinsky halogenation. Amino acids are susceptible to diazotization in the presence of chlorideAlison Butler (817 words) [view diff] exact match in snippet view article find links to article
iron, vanadium haloperoxidases in microbial quorum sensing and cryptic halogenation, bio-inspired wet adhesion using catechol compounds, and the oxidativeDiazirine (2,309 words) [view diff] exact match in snippet view article find links to article
ISSN 1066-5285. S2CID 97472127. Graham, W. H. (1965-10-01). "The Halogenation of Amidines. I. Synthesis of 3-Halo- and Other Negatively SubstitutedHectochlorin (1,016 words) [view diff] exact match in snippet view article find links to article
gem-dichloro group in 5,5-dichlorohexanoic acid. For such, hctB has one halogenation domain in the N-terminus, which is 47% similar to a halogenase at MicrocystisDimanganese decacarbonyl (4,524 words) [view diff] exact match in snippet view article find links to article
Steven P.; Trogler, William C.; Basolo, Fred (March 1984). "Mechanism of halogenation of dimanganese, manganese-rhenium, and dirhenium decacarbonyls". JournalVinyl iodide functional group (3,003 words) [view diff] exact match in snippet view article find links to article
vinyl halides via carbozincation of acetylenic sulfones followed by halogenation". Journal of Organometallic Chemistry. 694 (14): 2258–2262. doi:10.1016/jΒ-Hydroxy β-methylbutyric acid (9,982 words) [view diff] exact match in snippet view article find links to article
haloform reaction provides another pathway to HMB involving the exhaustive halogenation of the methyl-ketone region of diacetone alcohol with sodium hypobromiteGraphene (27,661 words) [view diff] exact match in snippet view article find links to article
fluorographene (graphene fluoride), while partial fluorination (generally halogenation) provides fluorinated (halogenated) graphene. Graphene can be a ligandSquire Booker (2,364 words) [view diff] exact match in snippet view article find links to article
J. M. (2009). "Substrate positioning controls the partition between halogenation and hydroxylation in the aliphatic halogenase, SyrB2". Proceedings ofPhotochlorination (2,997 words) [view diff] exact match in snippet view article find links to article
Criteria 181: CHLORINATED PARAFFINS. Earl T. McBee, Ogden R Pierce: Halogenation. In: Industrial & Engineering Chemistry. 46, 1954, p. 1835–1841, doi:10Chloroeremomycin (915 words) [view diff] exact match in snippet view article find links to article
of the tailoring enzymes that will perform the necessary reactions (halogenation, glycosylation, methylation, oxidative cross-linking, and hydroxylations)List of Russian scientists (9,600 words) [view diff] exact match in snippet view article find links to article
in Europe during World War I, co-discoverer of Hell-Volhard-Zelinsky halogenation, a founder of petrochemistry Nikolai Zinin, discovered benzidine, co-discoveredSibur (6,277 words) [view diff] exact match in snippet view article find links to article
become operational in 2020. Now this is the region's first butyl rubber halogenation plant. In addition, Sibur agreed to share proprietary butyl rubber technologySibur (6,277 words) [view diff] exact match in snippet view article find links to article
become operational in 2020. Now this is the region's first butyl rubber halogenation plant. In addition, Sibur agreed to share proprietary butyl rubber technologyJamaicamide A (488 words) [view diff] exact match in snippet view article find links to article
Garneau-Tsodikova, Sylvie; Walsh, Christopher T. (2006). "Nature's Inventory of Halogenation Catalysts: Oxidative Strategies Predominate". Chemical Reviews. 106 (8):Iodotoluene (305 words) [view diff] exact match in snippet view article find links to article
January 19, 2023. Datta, Rasik Lal; Chatterjee, Nihar Ranjan (1917). "Halogenation. Xv. Direct Iodination of Hydrocarbons by Means of Iodine and NitricList of Russian people (22,823 words) [view diff] exact match in snippet view article find links to article
in Europe during World War I, co-discoverer of Hell-Volhard-Zelinsky halogenation, a founder of petrochemistry Nikolai Zinin, discovered benzidine, co-discoveredTotarol (4,785 words) [view diff] exact match in snippet view article find links to article
with p-TsOH in benzene to yield 17. The synthesis was completed by a halogenation-dehydrogenation sequence and subsequent bromination to yield 18 and ringHydrolyzed vegetable protein (2,732 words) [view diff] exact match in snippet view article find links to article
L-tyrosine, and L-leucine. Tyrosine is an amino acid susceptible to halogenation during hydrolysis with HCl. To prevent this, phenol is often added to