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searching for Silyl enol ether 5 found (27 total)

Self-condensation (488 words) [view diff] exact match in snippet view article find links to article

will occur. One way to get around this is to turn the aldehyde into a silyl enol ether using trimethylsilyl chloride and a base, such as triethylamine, and

Conia-ene reaction (1,805 words) [view diff] exact match in snippet view article find links to article

chiral cyclohexenone 1, a series of enone functionalizations gave silyl enol ether 2 as the Conia-ene precursor. To effect cyclization, 2 was treated

Povarov reaction (695 words) [view diff] exact match in snippet view article find links to article

first step, a dirhodium catalyst effects diazo decomposition from silyl enol ether diazo compound to yield a donor/acceptor cyclopropene. The donor/acceptor

Enamine (1,800 words) [view diff] exact match in snippet view article find links to article

Saegusa, T (1975). "Synthesis of 1,4-diketones by the reaction of silyl enol ether with silver oxide. Regiospecific formation of silver(I) enolate intermediates"

W. Clark Still (2,031 words) [view diff] exact match in snippet view article find links to article

enolate was trapped with chlorotrimethylsilane to form the macrocyclic silyl enol ether as a single diastereomer. This intermediate was then transformed into