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searching for Trimethylsilyl chloride 8 found (80 total)

Hexamethyldisilane (181 words) [view diff] exact match in snippet view article find links to article

Hexamethyldisilane can be produced by Wurtz-like coupling of trimethylsilyl chloride in the presence of a reducing agent such as potassium graphite:

Ferrole (367 words) [view diff] exact match in snippet view article find links to article

route to ferroles involves treatment of Collman's reagent with trimethylsilyl chloride (tms = (CH3)3Si): 2 Na2Fe(CO)4 + 4 tmsCl → Fe2(CO)6C4(Otms)4 +

Tris(trimethylsilyl)phosphine (339 words) [view diff] exact match in snippet view article

readily. Tris(trimethylsilyl)phosphine is prepared by treating trimethylsilyl chloride, white phosphorus, and sodium-potassium alloy: 1/4 P4 + 3 Me3SiCl

Carbonyldiimidazole (1,043 words) [view diff] exact match in snippet view article find links to article

more preparative effort with the advantage that the coproduct trimethylsilyl chloride is volatile. CDI hydrolyzes readily to give back imidazole: (C3H3N2)2CO

Protecting group (6,755 words) [view diff] exact match in snippet view article find links to article

methyl iodide in N,N‑dimethylformamide, or methanol and catalytic trimethylsilyl chloride Benzyl esters — Also removed by hydrogenolysis. Benzhydryl esters —

Rubottom oxidation (3,396 words) [view diff] exact match in snippet view article find links to article

the anionic oxy-Cope, the enolate intermediate was trapped with trimethylsilyl chloride (TMSCl). The silyl enol ether intermediate could then be treated

Tris(trimethylsilyl)amine (1,628 words) [view diff] exact match in snippet view article

Shiina observed that lithium (as an electron donor) forms with trimethylsilyl chloride under darkening tris(trimethylsilyl)amine in the presence of chromium(III)

Organolithium reagent (5,971 words) [view diff] exact match in snippet view article find links to article

controlling the amount of organolithium reagent addition, or using trimethylsilyl chloride to quench excess lithium reagent. A more common way to synthesize