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searching for Transmetalation 23 found (69 total)

Corey–House synthesis (1,516 words) [view diff] exact match in snippet view article find links to article

from the alkyllithium by treatment with copper(I) iodide (CuI) in a transmetalation reaction: 2 RLi + CuI → Li+[R–Cu–R]– + LiI If the use of alkyllithium

Organostannane addition (979 words) [view diff] exact match in snippet view article find links to article

addition, Lewis-acid-promoted addition, and addition involving prior transmetalation. Each of these modes invokes a unique model for stereocontrol, but

Kumada coupling (2,269 words) [view diff] exact match in snippet view article find links to article

oxidative addition forms an organo-Pd(II)-complex (2). Subsequent transmetalation with the Grignard reagent forms a hetero-organometallic complex (3)

W. Clark Still (2,040 words) [view diff] exact match in snippet view article find links to article

lithium diisopropylamide formed the kinetic enolate which then underwent transmetalation upon the addition of magnesium bromide. Subsequent addition of the

Reactions of organocopper reagents (1,732 words) [view diff] exact match in snippet view article find links to article

a catalytic amount of copper halide. Transmetalation to copper and carbocupration are followed by transmetalation of the product alkene back to magnesium

Triethylgallium (340 words) [view diff] exact match in snippet view article find links to article

The ether is not easily removed. Thus an alternative route involves transmetalation with triethylaluminium according to this simplified equation: GaCl3

Organosodium chemistry (1,261 words) [view diff] exact match in snippet view article find links to article

Schlenk's Organoalkali-Metal Chemistry. The Metal Displacement and the Transmetalation Reactions. Metalation of Weakly Acidic Hydrocarbons. Superbases" Organometallics

Scott E. Denmark (1,093 words) [view diff] exact match in snippet view article find links to article

the Denmark group is the observation and characterization of the pre-transmetalation species of the boron-palladium adduct in Suzuki reactions using rapid-injection

Chloro(triphenylphosphine)gold(I) (581 words) [view diff] exact match in snippet view article

complex Ph3PAuMe is prepared from triphenylphosphinegold(I) chloride by transmetalation with a Grignard reagent. Further treatment of Ph3PAuMe with methyllithium

Kulinkovich reaction (1,716 words) [view diff] exact match in snippet view article find links to article

titanium salt of the cyclopropanol (4). (This species then undergoes transmetalation with Grignard reagent to regenerate 1 and close the catalytic cycle

Norio Miyaura (1,071 words) [view diff] exact match in snippet view article find links to article

base. In 1997, Miyaura created a new catalytic cycle starting from transmetalation which resulted in an aryl- or 1-alkenylrhodium(I) intermediate for

John R. Falck (1,568 words) [view diff] exact match in snippet view article find links to article

Falck, J. R.; Bhatt, Rama K.; Ye, Jianhua (June 1995). "Tin-Copper Transmetalation: Cross-Coupling of .alpha.-Heteroatom-Substituted Alkyltributylstannanes

Catalyst transfer polymerization (1,017 words) [view diff] exact match in snippet view article find links to article

propagation reaction. The propagation steps of CTP occurs through a cycle of transmetalation, reductive elimination, ring walking, and oxidative addition. The existence

Peter Wipf (950 words) [view diff] exact match in snippet view article find links to article

PMID 11671655. Wipf, Peter; Ribe, Seth (1 September 1998). "Zirconocene−Zinc Transmetalation and in Situ Catalytic Asymmetric Addition to Aldehydes". The Journal

Catalyst transfer polymerization (1,017 words) [view diff] exact match in snippet view article find links to article

propagation reaction. The propagation steps of CTP occurs through a cycle of transmetalation, reductive elimination, ring walking, and oxidative addition. The existence

Alkenylaluminium compounds (1,660 words) [view diff] exact match in snippet view article find links to article

metal-free diene product. (13) Alkenyl- and alkynylalanes undergo transmetalation to a variety of metals, including boron, zirconium, and mercury. (14)

Suzanne Blum (658 words) [view diff] exact match in snippet view article find links to article

(2011). "Organogold Reactivity with Palladium, Nickel, and Rhodium: Transmetalation, Cross-Coupling, and Dual Catalysis". Accounts of Chemical Research

Lead (19,075 words) [view diff] exact match in snippet view article find links to article

Retrieved 18 February 2017. Dieter, R. K.; Watson, R. T. (2009). "Transmetalation reactions producing organocopper compounds". In Rappoport, Z.; Marek

Periodic table (27,210 words) [view diff] exact match in snippet view article find links to article

9003A. doi:10.1021/ja00207a003. Dieter, R. K.; Watson, R. T. (2009). "Transmetalation reactions producing organocopper compounds". In Rappoport, Z.; Marek

Georgiy B. Shul'pin (1,912 words) [view diff] exact match in snippet view article find links to article

aryl-platinum dinuclear complexes via ortho C-H bond activation of phenol and transmetalation of arylboronic acid”, Organometallics, 2005, 24, 5528-5536. doi:10

Organomagnesium chemistry (3,348 words) [view diff] exact match in snippet view article find links to article

which can be used to perform nucleophilic addition, substitution, transmetalation, and metal-halogen exchange reactions. The first crystal structure

Cheon Jinwoo (2,832 words) [view diff] exact match in snippet view article find links to article

and "core-shell" type cobalt− platinum magnetic nanoparticles via transmetalation reactions". Journal of the American Chemical Society. 24 (123): 5743–5746

Stibinidene (3,128 words) [view diff] exact match in snippet view article find links to article

N-chelated pnictinidenes with Rh(I) and Ir(I) complexes: Coordination vs. Transmetalation". Journal of Organometallic Chemistry. Organometallic Chemistry of