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Longer titles found: Sulfonium-based oxidation of alcohols to aldehydes (view), Trimethylsulfonium (view)

searching for Sulfonium 33 found (199 total)

alternate case: sulfonium

Ylide (1,164 words) [view diff] exact match in snippet view article find links to article

with metal ions like palladium and platinum. Other common ylides include sulfonium ylides and sulfoxonium ylides; for instance, the Corey-Chaykovsky reagent

Adenosylmethionine hydrolase (140 words) [view diff] exact match in snippet view article find links to article

methylmethionine-sulfonium-salt hydrolase, and adenosylmethionine lyase. Mazelis M, Levin B, Mallinson N (1965). "Decomposition of methyl methionine sulfonium salts

ATC code C02 (416 words) [view diff] no match in snippet view article find links to article

ATC code C02 Antihypertensives is a therapeutic subgroup of the Anatomical Therapeutic Chemical Classification System, a system of alphanumeric codes developed

David J. Procter (976 words) [view diff] exact match in snippet view article find links to article

on organic chemistry and catalysis, specifically on radical cascades, sulfonium cross-coupling and copper catalysis. Procter completed his Bsc in 1992

Feist–Benary synthesis (261 words) [view diff] exact match in snippet view article find links to article

nucleophilic aliphatic substitution. In place of α-haloketones, propargyl sulfonium salts can be used to alkylate the diketone. Another modification is the

2,3-sigmatropic rearrangement (337 words) [view diff] exact match in snippet view article find links to article

OCLC 642506595. Ring expansion by 2,3-sigmatropic shifts of unstabilized sulfonium ylides. Synthesis of eight- to ten-membered thiacycloalk-4-enes V. Cere

Pummerer rearrangement (858 words) [view diff] exact match in snippet view article find links to article

involving a pyridine oxide Stevens rearrangement ― similar reaction involving sulfonium or ammonium salts, more generally de Lucchi, Ottorino; Miotti, Umberto;

Glycosylation (3,475 words) [view diff] exact match in snippet view article find links to article

developed based on solvent participation or the formation of bicyclic sulfonium ions as chiral-auxiliary groups. The non-enzymatic glycosylation is also

Tetrahydrothiophene (618 words) [view diff] exact match in snippet view article find links to article

Elucidation of Absolute Stereochemistry of Salaprinol, another Thiosugar Sulfonium Sulfate from the Ayurvedic Traditional Medicine Salacia prinoides". Tetrahedron

Albright–Goldman oxidation (281 words) [view diff] exact match in snippet view article find links to article

First, dimethyl sulfoxide (1) reacts with acetic anhydride to form a sulfonium ion. It reacts with the primary alcohol in an addition reaction. Furthermore

Diethylaminosulfur trifluoride (631 words) [view diff] exact match in snippet view article find links to article

trifluoride (trade name: Deoxo-Fluor) and difluoro(morpholino)sulfonium tetrafluoroborate (trade name: XtalFluor-M) are reagents related to DAST

Sodium hydride (1,352 words) [view diff] exact match in snippet view article find links to article

condensation. Other carbon acids susceptible to deprotonation by NaH include sulfonium salts and DMSO. NaH is used to make sulfur ylides, which in turn are used

Hiyama coupling (1,984 words) [view diff] exact match in snippet view article find links to article

organic halides mediated by a palladium catalyst and tris(diethylamino)sulfonium difluorotrimethylsilicate". Journal of Organic Chemistry. 53 (4): 918–920

Leaving group (1,857 words) [view diff] exact match in snippet view article find links to article

substrates are more likely to react by competitive addition-elimination, while sulfonium and ammonium salts generally form ylides or undergo E2 elimination. Phenoxides

Dogger Bank itch (708 words) [view diff] exact match in snippet view article find links to article

Christophersen C (1980). "Dogger Bank itch the allergen is 2-hydroxyethyldimethyl sulfonium ion". Journal of the American Chemical Society. 102 (15): 5107–108. doi:10

Trimethylglycine (1,759 words) [view diff] exact match in snippet view article find links to article

PMID 10505788. Rhodes D, Hanson AD (1993). "Quaternary Ammonium and Tertiary Sulfonium Compounds in Higher Plants". Annual Review of Plant Physiology and Plant

Pnictogen bond (904 words) [view diff] exact match in snippet view article find links to article

Gabbaï have demonstrated such a system, in which reduction of an adjacent sulfonium enables the transmembrane transport of anions by an antimony transporter

Gerrit Friedrich Otto Toennies (649 words) [view diff] exact match in snippet view article find links to article

Toennies was the first to point out the probable biological importance of sulfonium compounds – a prediction later borne out by a variety of findings by other

Echinomycin (433 words) [view diff] exact match in snippet view article find links to article

disulfide bond. Secondly deprotonation of the alpha proton to the tertiary sulfonium cation promotes the rearrangement for the formation of the thioacetal

Sulfinyl nitrene (677 words) [view diff] exact match in snippet view article find links to article

Me3SiOtBu NaNSO, KNSO, RbNSO, CsNSO, (Me2N)3S+NSO− and tris(dimethylamino)sulfonium [(Me2N)3S][NSO] salts are known. Davies, Thomas Q.; Tilby, Michael J.;

Marjorie Caserio (1,213 words) [view diff] exact match in snippet view article find links to article

(1966-12-01). "The Nature of Sulfur Bonding in α,β-Unsaturated Sulfides and Sulfonium Salts1,2". Journal of the American Chemical Society. 88 (24): 5747–5753

Trihexyphenidyl (2,085 words) [view diff] exact match in snippet view article find links to article

1957). "Synthesis of Certain 3-Hydroxy-3-phenylpropylsulfonium Salts. Sulfonium Analogs of Artane (Trihexyphenidyl) and Pathilon (Tridihexethyl Iodide)"

Holton Taxol total synthesis (1,478 words) [view diff] exact match in snippet view article find links to article

tetrahydrofuran, tert-butyldimethylsilyl chloride tris(dimethylamino)sulfonium difluorotrimethylsilicate (TASF) After Grob fragmentation (Scheme 1),

Fluorosulfite (627 words) [view diff] exact match in snippet view article find links to article

orthorhombic Pbca a=11.520 b=11.505 c=11.627 Z=8 1541.0 1.355 tris-dimethylamino sulfonium fluorosulfite [((CH3)2N)3S][SO2F] 247.35 orthorhombic Pnma a=14.690 b=11

Kendra Daly (1,190 words) [view diff] exact match in snippet view article find links to article

Southern Ocean", Biological and Environmental Chemistry of DMSP and Related Sulfonium Compounds, Boston, MA: Springer US, pp. 223–238, doi:10.1007/978-1-4613-0377-0_20

Tamejiro Hiyama (1,221 words) [view diff] exact match in snippet view article find links to article

organic halides mediated by a palladium catalyst and tris(diethylamino) sulfonium difluorotrimethylsilicate". J. Org. Chem. 53 (4): 918–920. doi:10.1021/jo00239a056

In situ (8,009 words) [view diff] exact match in snippet view article find links to article

Corey–Chaykovsky reagent, a sulfur ylide, is generated in situ by deprotonating sulfonium halides with a strong base. This approach is used because unstablized

Isaac Bencowitz (1,406 words) [view diff] case mismatch in snippet view article find links to article

ACTIVITY OF CERTAIN -ONIUM COMPOUNDS. THE MOBILITIES OF THE -ONIUM IONS. I. SULFONIUM IONS." J. Am. Chem. Soc., 1925, 47 (7), pp 1904–1916. DOI: 10.1021/ja01684a018

Adhesive bonding of semiconductor wafers (3,822 words) [view diff] exact match in snippet view article find links to article

negative photoresist based on epoxy resin, gamma butyrolactone, and triaryl sulfonium salt. SU-8 polymerizes at approximately 100 °C and is temperature-stable

Living polymerization (4,445 words) [view diff] exact match in snippet view article find links to article

be catalysed by bifluorides and bioxyanions such as tris(dialkylamino)sulfonium bifluoride or tetrabutyl ammonium bibenzoate. The method was discovered

Organic nomenclature in Chinese (1,162 words) [view diff] exact match in snippet view article find links to article

From fusion of the sounds of 氫/氢 qīng 'hydrogen' and 硫 liú 'sulfur' (Sulfonium is 鋶/锍 liǔ, in analogy with ammonium) 醛 aldehyde 荃 quán quán 'change in

Ptaquiloside (3,291 words) [view diff] exact match in snippet view article find links to article

performed to provide compound 4. On treatment with base and a chloroethyl sulfonium salt, a mixture of spirocyclopropanes was obtained. The minor product

Photoredox catalysis (6,259 words) [view diff] exact match in snippet view article find links to article

aminotrifluoromethylation reactions. These reactions use Umemoto's reagent, a sulfonium salt that serves as an electrophilic source of the trifluoromethyl group