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searching for Reaction intermediate 43 found (75 total)

1,3-Bisphosphoglyceric acid (996 words) [view diff] exact match in snippet view article find links to article

also a precursor to 2,3-bisphosphoglycerate which in turn is a reaction intermediate in the glycolytic pathway. 1,3-Bisphosphoglycerate is the conjugate

Octamethylenediamine (365 words) [view diff] exact match in snippet view article find links to article

substance group of aliphatic diamines. It is used as a versatile reaction intermediate in the manufacture of pesticides, especially fungicides. The industrial

Steroid Delta-isomerase (3,232 words) [view diff] exact match in snippet view article find links to article

unusually short, strong hydrogen bonds between KSI oxanion hole and the reaction intermediate as a means of catalytic rate enhancement. In their model, high-energy

Borane (1,227 words) [view diff] exact match in snippet view article find links to article

as borane carbonyl, BH3(CO). Molecular BH3 is believed to be a reaction intermediate in the pyrolysis of diborane to produce higher boranes: B2H6 ⇌ 2BH3

Amastatin (388 words) [view diff] no match in snippet view article find links to article

"Modern Aspects of Enzyme Inhibition with Particular Emphasis on Reaction-Intermediate Analogs and Other Potent, Reversible Inhibitors". In Boger P, Sandmann

Protein O-GlcNAcase (2,189 words) [view diff] exact match in snippet view article find links to article

O-GlcNAc hydrolysis via an oxazoline reaction intermediate. Stable compounds which mimic the reaction intermediate can act as selective enzyme inhibitors

George Huntly Lorimer (419 words) [view diff] exact match in snippet view article find links to article

chemical quench and other techniques to trap and identify the 6-carbon reaction intermediate of the carboxylation reaction and defined the complete stereo-chemical

Deoxyribonuclease IV (1,301 words) [view diff] exact match in snippet view article find links to article

nuclei. In human body, DNase IV was required for cleavage of a reaction intermediate generated by template strand displacement during gap-filling. During

PRDX5 (2,406 words) [view diff] exact match in snippet view article find links to article

mammalian peroxiredoxin that forms an intramolecular disulfide as a reaction intermediate". The Journal of Biological Chemistry. 275 (27): 20346–54. doi:10

Riboflavin synthase (1,086 words) [view diff] exact match in snippet view article find links to article

Zheng YJ, Jordan DB, Liao DI (August 2003). "Examination of a reaction intermediate in the active site of riboflavin synthase". Bioorg. Chem. 31 (4):

Amidophosphoribosyltransferase (1,568 words) [view diff] exact match in snippet view article find links to article

aspect of the catalytic site is an oxyanion hole which catalyzes the reaction intermediate, as shown in the mechanism below. The PRTase domain is homologous

Carboxyglutamic acid (646 words) [view diff] exact match in snippet view article find links to article

glutamic acid is abstracted, and CO2 is subsequently added. The reaction intermediate is a γ-glutamyl carbanion. This reaction is catalyzed by a carboxylase

David Chapman (chemist) (522 words) [view diff] exact match in snippet view article

the first to apply this theory to measure the 'mean life' of a reaction intermediate. Other areas of interest were the theory of detonation in gases

Thiolase (2,117 words) [view diff] exact match in snippet view article find links to article

Wierenga RK (October 1999). "A biosynthetic thiolase in complex with a reaction intermediate: the crystal structure provides new insights into the catalytic

Photosensitizer (3,108 words) [view diff] no match in snippet view article find links to article

mechanism was confirmed through various spectroscopic methods including reaction-intermediate studies and luminescence studies. The term photosensitizer does

Glutathione hydrolase (354 words) [view diff] exact match in snippet view article find links to article

Escherichia coli, a key enzyme in glutathione metabolism, and its reaction intermediate". Proceedings of the National Academy of Sciences of the United

Enolase (3,253 words) [view diff] exact match in snippet view article find links to article

S2CID 43249019. Anderson VE, Weiss PM, Cleland WW (June 1984). "Reaction intermediate analogues for enolase". Biochemistry. 23 (12): 2779–2786. doi:10

Carbonyl reduction (2,729 words) [view diff] exact match in snippet view article find links to article

formed alcohol and added hydrogen atom eclipse each other in the reaction intermediate (as shown in the Newman projection for the axial alcohol). Large

Meropenem (3,780 words) [view diff] exact match in snippet view article find links to article

GR, et al. (November 2008). "Trapping and characterization of a reaction intermediate in carbapenem hydrolysis by B. cereus metallo-beta-lactamase". J

Pectin lyase (1,374 words) [view diff] exact match in snippet view article find links to article

glycosidic bonds, guarantee substrate specificity, and stabilize the reaction intermediate. The active site is pivotal to the ability of pectin lyase to efficiently

HaloTag (977 words) [view diff] exact match in snippet view article find links to article

However, in the modified haloalkane dehalogenase (HaloTag), the reaction intermediate cannot proceed through a subsequent reaction because it cannot be

Amino acid (10,035 words) [view diff] exact match in snippet view article find links to article

(November 2008). "Stabilization and characterization of a heme-oxy reaction intermediate in inducible nitric-oxide synthase". The Journal of Biological Chemistry

O-Succinylbenzoate—CoA ligase (839 words) [view diff] exact match in snippet view article find links to article

synthetase: reaction kinetics and a novel inhibitor mimicking its reaction intermediate". Biochemistry. 47 (47): 12434–47. doi:10.1021/bi801311d. PMC 2710618

Organolithium reagent (5,955 words) [view diff] exact match in snippet view article find links to article

to yield a chiral alcohol product. The structure of the active reaction intermediate was determined by NMR spectroscopy studies in the solution state

Carbene radical (983 words) [view diff] exact match in snippet view article find links to article

Example of carbene radical reaction intermediate generated by reaction of cobalt porphyrin and CHCO2Et ligand. σ donation from the ligand to the "dz2"

Carnitine palmitoyltransferase II deficiency (3,167 words) [view diff] no match in snippet view article find links to article

carnitine acyltransferases from peroxisomes and mitochondria by using a reaction-intermediate analogue". Biochem J. 294 (3): 645–51. doi:10.1042/bj2940645. PMC 1134510

Physical organic chemistry (5,561 words) [view diff] exact match in snippet view article find links to article

stabilizing the transition state structure or destabilizing a key reaction intermediate, and as only a small amount of catalyst is required it can provide

Alpha-methylacyl-CoA racemase (2,234 words) [view diff] exact match in snippet view article find links to article

thioester-dependent racemase: the 1.4 Å crystal structure of a reaction intermediate complex characterized by detailed QM/MM calculations". The Journal

Sirtuin 3 (1,662 words) [view diff] exact match in snippet view article find links to article

acetyl lysine of its natural substrate acetyl-CoA synthetase 2, a reaction intermediate structure trapped by a thioacetyl peptide, and a structure with

Pyrobitumen (1,871 words) [view diff] exact match in snippet view article find links to article

Kobylinski, have inappropriately used the term pyrobitumen as the reaction intermediate between kerogen and oil to distinguish it from natural bitumen.

R. Tom Baker (1,179 words) [view diff] exact match in snippet view article find links to article

release step of dehydrogenation by isolation and characterization of reaction intermediate. Baker also works on utilizing copper and vanadium homogeneous catalysts

Phosphopentose epimerase (1,880 words) [view diff] exact match in snippet view article find links to article

Fe2+ is octahedrally coordinated and stabilizes the 2,3-enediolate reaction intermediate observed in the figure. The β6/α6 loop region interacts with the

FPG IleRS zinc finger (738 words) [view diff] exact match in snippet view article find links to article

"Structural analysis of an Escherichia coli endonuclease VIII covalent reaction intermediate". EMBO J. 21 (4): 789–800. doi:10.1093/emboj/21.4.789. PMC 125349

Lewis acid catalysis (5,024 words) [view diff] exact match in snippet view article find links to article

BINAP-palladium-catalyzed asymmetric Diels-Alder reaction. In the model for the reaction intermediate, the binaphthyl rings are omitted for clarity.

Flupyradifurone (1,096 words) [view diff] exact match in snippet view article find links to article

intermediate, 4-[(2-fluoroethyl)amino]furane-2(5H)-one. Heating the reaction intermediate with 2-chloro-5-(chloromethyl)pyridine in THF under reflux yields

Methylglyoxal synthase (2,053 words) [view diff] exact match in snippet view article find links to article

Rose IA (March 1981). "Liberation of the triosephosphate isomerase reaction intermediate and its trapping by isomerase, yeast aldolase, and methylglyoxal

Helium compounds (11,142 words) [view diff] exact match in snippet view article find links to article

compared to HCO+. It can be considered as a deenergized protonation reaction intermediate for the HeH+ + CO → HCO+ + He. HeHCO+ can be produced by a supersonic

Kinetic isotope effects of RuBisCO (2,412 words) [view diff] exact match in snippet view article find links to article

PMID 11848907. Pierce J, Andrews TJ, Lorimer GH (August 1986). "Reaction intermediate partitioning by ribulose-bisphosphate carboxylases with differing

List of Dutch discoveries (10,146 words) [view diff] exact match in snippet view article find links to article

into the ketose isomer or vice versa, with a tautomeric enediol as reaction intermediate. The transformation is relevant for the industrial production of

Polycatenane (3,718 words) [view diff] exact match in snippet view article find links to article

monomeric cage state, and it can be formed passing through a favored reaction intermediate. The synthesis can follow a statistical or a directed routes, forming

Organogermanium compounds in cross-coupling reactions (1,337 words) [view diff] exact match in snippet view article find links to article

between the nucleophilic end of the enophile and the metal in the reaction intermediate which lowers the energy of the transition state. Enokido, Tatsuki;

Indriline (238 words) [view diff] exact match in snippet view article find links to article

inactive isomer. Based on neighboring group participation (NGP), the reaction intermediate is presumably an aziridinium ion According to Molbase the number

John P. Richard (2,238 words) [view diff] exact match in snippet view article find links to article

demonstrated that there is a large stabilization of the UMP carbanion reaction intermediate by interactions with the protein catalyst. This was one key result