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Longer titles found: Trifluoromethoxy group (view)

searching for Methoxy group 68 found (99 total)

Cephamycin (230 words) [view diff] exact match in snippet view article find links to article

have been produced as well.[citation needed] Cephamycins possess a methoxy group at the 7-alpha position. In addition, cephamycins have been shown to

Brodimoprim (65 words) [view diff] exact match in snippet view article find links to article

Brodimoprim is a structural derivative of trimethoprim. In brodimoprim, the 4-methoxy group of trimethoprim is replaced with a bromine atom. As trimethoprim, brodimoprim

Idarubicin (290 words) [view diff] exact match in snippet view article find links to article

topoisomerase II. It is an analog of daunorubicin, but the absence of a methoxy group increases its fat solubility and cellular uptake. Similar to other anthracyclines

14-Methoxymetopon (302 words) [view diff] exact match in snippet view article find links to article

Innsbruck in the mid-1990s. It is a derivative of metopon in which a methoxy group has been inserted at the 14-position. It is a highly potent analgesic

JWH-164 (237 words) [view diff] exact match in snippet view article find links to article

is a positional isomer of the related compound JWH-081, but with a methoxy group at the 7-position of the naphthyl ring, rather than the 4-position as

Dillapiole (270 words) [view diff] exact match in snippet view article find links to article

as fennel root. This compound is closely related to apiole, having a methoxy group positioned differently on the benzene ring. Dillapiole works synergically

Anisole (736 words) [view diff] exact match in snippet view article find links to article

benzene reflects the influence of the methoxy group, which renders the ring more electron-rich. The methoxy group strongly affects the pi cloud of the

4-Anisaldehyde (317 words) [view diff] exact match in snippet view article find links to article

CH3OC6H4CHO. The molecule consists of a benzene ring with a formyl and a methoxy group. It is a colorless liquid with a strong aroma. It provides sweet, floral

Melatonin receptor agonist (2,894 words) [view diff] exact match in snippet view article find links to article

general structure of melatonin is the indole ring with methoxy group in position 5 (5-methoxy group) and acylaminoethyl side-chain in position 3. The two

Wulff–Dötz reaction (1,502 words) [view diff] exact match in snippet view article find links to article

the phenol and the smallest alkyne substituent (RS) neighboring the methoxy group. Hence, this reaction is more useful for terminal alkynes than internal

Anisoyl chloride (84 words) [view diff] exact match in snippet view article find links to article

structures differ in the arene substitution pattern—the location of the methoxy group on the ring as compared to the acyl halide. National Institute of Standards

Danishefsky's diene (963 words) [view diff] exact match in snippet view article find links to article

reacts rapidly with electrophilic alkenes, such as maleic anhydride. The methoxy group promotes highly regioselective additions. The diene is known to react

Isorhapontigenin (380 words) [view diff] exact match in snippet view article find links to article

Isorhapontigenin is a tetrahydroxylated stilbenoid with a methoxy group. It is an isomer of rhapontigenin and an analog of resveratrol. It is found in

Hypromellose (1,205 words) [view diff] exact match in snippet view article find links to article

concentration of the methoxy group within the HPMC molecule (which in turn depends on both the degree of substitution of the methoxy group and the molar substitution)

Trifluoromescaline (193 words) [view diff] exact match in snippet view article find links to article

mescaline, which has a trifluoromethoxy group replacing the central methoxy group of mescaline. Synthesis of this compound was first reported by Daniel

Directed ortho metalation (1,041 words) [view diff] exact match in snippet view article find links to article

interacts with lithium through a hetero atom. Examples of DMG's are the methoxy group, a tertiary amine group and an amide group.The compound can be produced

2'-O-methylation (703 words) [view diff] exact match in snippet view article find links to article

2' hydroxyl of the ribose moiety of any nucleotide (Nm) producing a methoxy group. The modification of one Nm creates more stabilization in the structure

Vanillin (3,752 words) [view diff] exact match in snippet view article find links to article

differs from vanillin by having an ethoxy group (−O−CH2CH3) instead of a methoxy group (−O−CH3). Natural vanilla extract is a mixture of several hundred different

Naphthol Red (246 words) [view diff] exact match in snippet view article find links to article

Research shows that by replacing the ethoxy group in this compound by a methoxy group the crystal structure is less stable and in the final application and

2CD-5EtO (328 words) [view diff] exact match in snippet view article find links to article

is a homologue of the psychedelic phenethylamine 2C-D, where the 5-methoxy group of 2C-D has been lengthened to an ethoxy group. 2CD-5EtO is a representative

6-Methylenedihydrodesoxymorphine (319 words) [view diff] exact match in snippet view article find links to article

reagent in diethyl ether to form 6-Methylenedihydrodesoxycodeine. The 3-methoxy group is then cleaved to hydroxy, by reaction with pyridine. The second step

Deoxymethoxetamine (142 words) [view diff] exact match in snippet view article find links to article

dissociative effects. It is an analogue of methoxetamine where the 3-methoxy group has been replaced by methyl. It has been sold online since around October

5-Methoxymethylone (190 words) [view diff] exact match in snippet view article find links to article

comparison with methylone, the two compounds differ by the addition of a methoxy group at the 5th carbon atom of the aromatic ring. The toxicity of this compound

Poly(4-vinylphenol) (363 words) [view diff] exact match in snippet view article

oxidation at room temperature. If poly(4-methoxystyrene) is produced, the methoxy group can be cleaved by treating it with trimethylsilyliodide. There are several

Stereoisomerism (1,653 words) [view diff] exact match in snippet view article find links to article

the ring for example, a hydroxyl group, a methyl hydroxyl group, a methoxy group or another pyranose or furanose group which are typical single bond

Gingerol (2,832 words) [view diff] exact match in snippet view article find links to article

final synthesis of 6-Gingerol (10). Because it is unclear whether the methoxy group addition is performed before or after the condensation step of the polyketide

Sodium bis(trimethylsilyl)amide (450 words) [view diff] exact match in snippet view article

via the reagent CH3OCH2N(Si(CH3)3)2, which contains a displaceable methoxy group CH3O–. Metal bis(trimethylsilyl)amides Watson, B. T.; Lebel, H. "Sodium

Furoquinoline alkaloid (792 words) [view diff] exact match in snippet view article find links to article

response in 6.90-7.10 ppm region. Aromatic methoxy group give responses in 4.0-4.2 ppm region but 4-methoxy group give responses in ~4.40 ppm region. Cordell

Delphinine (750 words) [view diff] exact match in snippet view article find links to article

time, Wiesner's research group corrected the stereochemistry of the methoxy group at C-1 from the β- to the α- configuration. Thus, any drawing of the

Mitotic inhibitor (6,908 words) [view diff] exact match in snippet view article find links to article

in conjunction with the ring C. The 3-methoxy group increased the binding ability whereas the 1-methoxy group helped in attaining the correct conformation

Weinreb ketone synthesis (1,295 words) [view diff] exact match in snippet view article find links to article

addition by the organometallic reagent is stabilized by chelation from the methoxy group as shown. This intermediate is stable only at low temperatures, requiring

4'-Methoxy-α-pyrrolidinopropiophenone (473 words) [view diff] exact match in snippet view article find links to article

related to α-PPP in the same way that PMA is related to amphetamine: a methoxy group has been added to the 4-position on the phenyl ring. Comparison of similar

Oleandomycin (990 words) [view diff] exact match in snippet view article find links to article

effective synthetic derivatives, it lacks a 12-hydroxyl group and a 3-methoxy group. This change in structure may adversely affect its interactions with

Strobilurin (854 words) [view diff] exact match in snippet view article find links to article

natural product with a phenolic hydroxy group in place of the aromatic methoxy group of strobilurin H is called strobilurin F1 and is found in C. anomala

Organic photochemistry (1,838 words) [view diff] exact match in snippet view article find links to article

beta carbon). When one of the aryl groups has a para-cyano or para-methoxy group, that substituted aryl group migrates in preference. Inspection of the

Cereblon E3 ligase modulator (5,487 words) [view diff] exact match in snippet view article find links to article

PDE4 inhibitors such as rolipram. Optimal activity is achieved with a methoxy group at the 4-position (X2) and a bigger group, such as cyclopentoxy at the

Methedrone (2,476 words) [view diff] exact match in snippet view article find links to article

effects.[citation needed] Some amphetamine analogs containing a para-methoxy group are known to cause severe hyperthermia and even death due to concurrent

Camptothecin (2,512 words) [view diff] exact match in snippet view article find links to article

insoluble in aqueous solutions, which causes difficulty in administrations. Methoxy group at both position 10 and 11 simultaneously leads to inactivity. Hexacyclic

2CE-5iPrO (114 words) [view diff] exact match in snippet view article find links to article

substituted phenethylamine derivative related to 2C-E, but with the 5-methoxy group extended to isopropoxy. Similar to related "tweetio" compounds such

Cerivastatin (1,690 words) [view diff] exact match in snippet view article find links to article

fluorophenyl linked to a pyridine. The pyridine has two isopropyl groups, one methoxy group and a dihydroxyheptanoic acid side chain. The dihydroxyheptanoic acid

MTOR inhibitors (6,225 words) [view diff] exact match in snippet view article find links to article

immunophilin FK506 binding protein, tacrolimus or FKBP-12, through its methoxy group. The rapamycin-FKBP12 complex interferes with FRB domain of mTOR. Molecular

2C-B-FLY (1,475 words) [view diff] exact match in snippet view article find links to article

the fully unsaturated derivative of Bromo-DragonFLY. When only one methoxy group of a 2Cx drug is cyclized into a dihydro-furan ring, the resulting compound

Tolcapone (2,140 words) [view diff] exact match in snippet view article find links to article

cleavage of the benzyl ether. The synthesis ends with cleavage of the methoxy group using aluminum chloride to yield the product alcohol. Tolcapone was

Vidarabine (1,952 words) [view diff] exact match in snippet view article find links to article

effective at blocking deamination, such as replacement of the amine with a methoxy group (ara-M). This results in about a 10-fold greater selectivity against

Methyllycaconitine (3,540 words) [view diff] exact match in snippet view article find links to article

Edwards and Przybylska independently corrected the stereochemistry of the methoxy group at C-1 from the β- to α- configuration. Thus any drawing of MLA appearing

Inverse electron-demand Diels–Alder reaction (2,643 words) [view diff] exact match in snippet view article find links to article

In the endo transition state, the methoxy group is "inside" the boat; where in the exo transition state, it is "outside".

Aconitine (3,598 words) [view diff] exact match in snippet view article find links to article

The acetoxyl group at the c8 position can readily be replaced by a methoxy group, by heating aconitine in methanol, to produce a 8-deacetyl-8-O-methyl

Structural scheduling of synthetic cannabinoids (2,865 words) [view diff] exact match in snippet view article find links to article

alkyl substitution on the nitrogen atom of the indole ring as well as a methoxy group attached to the phenyl ring. Benzoylindoles: Any compound containing

PiHKAL (676 words) [view diff] exact match in snippet view article find links to article

desoxy methyl, referring to the removal of the Oxygen atom from the Methoxy group on the "4" carbon. Mescaline (3,4,5-trimethoxyphenethylamine) All six

Curtin–Hammett principle (3,700 words) [view diff] exact match in snippet view article find links to article

activation barriers for the step following ylide formation. If the ortho-methoxy group undergoes oxonium ylide formation, a 1,4-methyl shift can then generate

Colchicine (5,669 words) [view diff] exact match in snippet view article find links to article

derivatives is that they keep the tropolone ring (the ring with the methoxy group and the carbonyl) intact to retain the mechanistic properties of the

Renin inhibitor (4,784 words) [view diff] exact match in snippet view article find links to article

carboxylic acid group of Gly217 and the oxygen atom of the Asp32. The methoxy group on the aromatic ring fills the S3 pocket and may possibly form a hydrogen

Meta-selective C–H functionalization (1,947 words) [view diff] exact match in snippet view article find links to article

However, the meta-selectivity is lost when highly ortho/para-directing methoxy group substitutes one of the meta-hydrogen of the anilide, which marks the

Aristolochia californica (952 words) [view diff] no match in snippet view article find links to article

phenanthrene-1-carboxylic acid, with a methylenedioxy- group at the 3rd and 4th positions, a methoxy- group at the 8th position, and a nitro group at the 10th position.

Quinine total synthesis (2,207 words) [view diff] exact match in snippet view article find links to article

from the biomolecule cinchonine (related to quinidine but without the methoxy group): The key step in the assembly of quinotoxine is a Claisen condensation:

Discovery and development of integrase inhibitors (4,154 words) [view diff] exact match in snippet view article find links to article

metal-chelating capability (compared to structure J in fig. 4) while a methoxy group (I) is much less potent due to steric clash by the additional methyl

Amphetamine type stimulant (2,404 words) [view diff] exact match in snippet view article find links to article

5-dimethoxyamphetamine and 2,5-dimethoxy-4-methylamphetamine. When the methoxy group is substituted in the para position of the ATS molecule, the hallucinogenic

Hsp90 inhibitor (2,756 words) [view diff] exact match in snippet view article find links to article

N terminal domain via the following key interactions. At the top 2 methoxy group of phenyl ring attaches itself to lys 112 of N terminal domain The 9

Discovery and development of proton pump inhibitors (4,718 words) [view diff] exact match in snippet view article find links to article

but substituted with two methoxy and two methyl groups. One of the methoxy group is at position 6 of the bensoimidazole and the other at position 4 of

Kalkitoxin (2,902 words) [view diff] exact match in snippet view article find links to article

the corresponding aldehyde, Wittig reaction using an ylide carrying a methoxy group to produce an enol ether, hydrolysis to the aldehyde and finally oxidation

Pillararene (2,360 words) [view diff] exact match in snippet view article find links to article

connected phenylene carbon as 2, and the carbon atom connected to the methoxy group as 3. When viewed from the side of the pilot atom, if the three atoms

Carpanone (1,206 words) [view diff] exact match in snippet view article find links to article

gives the required desmethylcarpacin (carpacin with the methyl of its methoxy group removed). Though oxidative dimerizations of phenols normally used a

Discovery and development of direct Xa inhibitors (4,916 words) [view diff] exact match in snippet view article find links to article

forms a tight inhibitor-enzyme complex when connected to FXa. The p-methoxy group of apixaban connects to S1 pocket of FXa but does not appear to have

Pyramidal carbocation (2,648 words) [view diff] exact match in snippet view article find links to article

its hard base in oxygen, will react at the center of positivity. The methoxy group appears at carbon 1, forcing bridges to form between carbon 2 and 4

Kedarcidin (2,705 words) [view diff] exact match in snippet view article find links to article

substituent, Shen et al. invoke double C-methylation of the corresponding methoxy group by the radical SAM methyltransferase KedN5. Owing to its non-specific

Selective norepinephrine reuptake inhibitor (3,816 words) [view diff] exact match in snippet view article find links to article

methyl group in position 2’ provides more affinity towards NET than a methoxy group in the same position. The amine group of atomoxetine binds to the amino

Enders SAMP/RAMP hydrazone-alkylation reaction (2,515 words) [view diff] exact match in snippet view article find links to article

sterically more accessible face. The chelation of lithium cation with the methoxy group is one of the most important features of the transition state for Enders'

9-Borafluorene (2,648 words) [view diff] exact match in snippet view article find links to article

thermochromism based on intermolecular coordination of the oxygen atom in the methoxy group of one molecule to a boron center in another molecule. It was observed