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searching for Matrix isolation 55 found (96 total)

Thallane (282 words) [view diff] exact match in snippet view article find links to article

thallane species has been isolated. Thallanes have been observed only in matrix isolation studies; the infrared spectrum was obtained in the gas phase by laser

Uranium trioxide (2,442 words) [view diff] no match in snippet view article find links to article

Uranium trioxide (UO3), also called uranyl oxide, uranium(VI) oxide, and uranic oxide, is the hexavalent oxide of uranium. The solid may be obtained by

John D. Baldeschwieler (372 words) [view diff] exact match in snippet view article find links to article

Baldeschwieler, John Dickson (1960). Structure of unstable compounds by matrix isolation techniques (Ph.D.). University of California, Berkeley. OCLC 29101714

Iridium compounds (1,803 words) [view diff] exact match in snippet view article find links to article

Sr2MgIrO6 and Sr2CaIrO6. iridium(VIII) oxide (IrO4) was generated under matrix isolation conditions at 6 K in argon. The highest oxidation state (+9), which

Pi-interaction (968 words) [view diff] exact match in snippet view article find links to article

Kulkarni; S.R. Gadre (2002). "H-π Complexes of acetylene-ethylene: A matrix isolation and computational study". J. Phys. Chem. A. 106 (8): 1504. Bibcode:2002JPCA

Mercury(II) hydride (977 words) [view diff] exact match in snippet view article

2 HgH → Hg 2H 2 Hg 2H 2 → 2 Hg + H 2 This is the preferred method for matrix isolation research. Besides mercury(II) hydride, it also produces other mercury

Neodymium compounds (1,264 words) [view diff] exact match in snippet view article find links to article

obtained in the Nd-NdX3 eutectic system. NdF4 is known only under matrix isolation conditions. The related M3[NdF7] (M = K, Rb, Cs) are very unstable

Argon compounds (15,925 words) [view diff] exact match in snippet view article find links to article

atom. However, compounds of argon have been detected in inert gas matrix isolation, cold gases, and plasmas, and molecular ions containing argon have

Alan Brisdon (834 words) [view diff] exact match in snippet view article find links to article

graduation, he continued to read for his Doctor of Philosophy degree on Matrix isolation infra-red and mass spectrometric studies of some arsenic and selenium

Martyn Poliakoff (1,863 words) [view diff] exact match in snippet view article find links to article

(16): 1008. doi:10.1039/C29700001008. Poliakoff, Martyn (1973). The matrix isolation of large molecules. The photochemistry of transition metal carbonyls

Praseodymium(IV) fluoride (300 words) [view diff] no match in snippet view article

(November 6, 2015). "Investigation of Praseodymium Fluorides: A Combined Matrix-Isolation and Quantum-Chemical Study". Inorganic Chemistry. 54 (23): 11114–11120

Adenine (1,024 words) [view diff] exact match in snippet view article find links to article

Lapinski; J. S. Kwiatkowski; J. Leszczynski (1994). "Experimental matrix isolation and theoretical ab initio HF/6-31G(d, p) studies of infrared spectra

Acene (831 words) [view diff] exact match in snippet view article find links to article

Unsubstituted octacene (n=8) and nonacene (n=9) have been detected in matrix isolation. The first reports of stable nonacene derivatives claimed that due

Chlorine tetroxide (315 words) [view diff] case mismatch in snippet view article find links to article

(16 December 2002). "Chlorine Oxide Radicals ClOx (x=1–4) Studied by Matrix Isolation Spectroscopy". Chemistry: A European Journal. 8 (24): 5601–5621. doi:10

Thiirene (170 words) [view diff] case mismatch in snippet view article find links to article

Bertie, J. E.; Gunning, H. E.; Strausz, O. P. (1978). "Low-Temperature Matrix Isolation of Thiirenes". The Journal of Organic Chemistry. 43 (12): 2490–2493

Stephen Liddle (1,304 words) [view diff] exact match in snippet view article find links to article

uranium(VI) nitride akin to examples previously restricted to cryogenic matrix isolation experiments. Also in 2013, his research group disclosed the first f-element

Praseodymium (5,021 words) [view diff] exact match in snippet view article find links to article

generated by oxidation with ozone. Praseodymium(V) has been observed by matrix isolation and in the bulk state. The existence of praseodymium in its +5 oxidation

Nitrogen difluoride (854 words) [view diff] no match in snippet view article find links to article

Dolphus E.; Guillory, William A.; Smith, Jerry J. (August 1974). "Matrix-isolation study of the vacuum-ultraviolet photolysis of NF3". Journal of Molecular

Zinc hydride (912 words) [view diff] exact match in snippet view article find links to article

successfully identified in the gas phase (that is, not limited to matrix isolation). The average Zn–H bond energy was recently calculated to be 51.24

Wolf Prize in Chemistry (284 words) [view diff] exact match in snippet view article find links to article

chemical laser. George C. Pimentel United States for development of matrix isolation spectroscopy and for the discovery of photodissociation lasers and

Gallane (940 words) [view diff] exact match in snippet view article find links to article

Mijoule, C. (1994). "Aluminium, gallium and indium trihydrides. an IR matrix isolation and ab initio study". Chemical Physics. 185 (1): 25–37. Bibcode:1994CP

Diiron nonacarbonyl (883 words) [view diff] case mismatch in snippet view article find links to article

An IR Spectroscopic Study Using 13C Photolysis with Plane-Polarized Light, and Matrix Isolation". Inorg. Chem. 25 (20): 3597. doi:10.1021/ic00240a014.

Dimethyl sulfite (323 words) [view diff] case mismatch in snippet view article find links to article

A.; Gómez-Zavaglia, A.; Simões, P. N. N. L.; Fausto, R. (2005). "Matrix Isolation FTIR Spectroscopic and Theoretical Study of Dimethyl Sulfite" (PDF)

Diazomethane (1,654 words) [view diff] exact match in snippet view article find links to article

(isodiazomethane). In addition, the parent nitrilimine has been observed under matrix isolation conditions. ICSC 1256 – DIAZOMETHANE NIOSH Pocket Guide to Chemical

Thomas Loerting (1,420 words) [view diff] case mismatch in snippet view article find links to article

J.; Huber, R. G.; Liedl, K. R.; Grothe, H.; Loerting, T. (2013). "Matrix Isolation Studies of Carbonic Acid—The Vapor Phase above the β-Polymorph". J

Ab initio quantum chemistry methods (2,538 words) [view diff] exact match in snippet view article find links to article

are present. Experimental work on these molecules is not easy, but matrix isolation spectroscopy of the products of the reaction of hydrogen atoms and

Silicone (5,110 words) [view diff] exact match in snippet view article find links to article

N. Khabashesku; Z. A. Kerzina; K. N. Kudin; O. M. Nefedov (1998). "Matrix isolation infrared and density functional theoretical studies of organic silanones

Lanthanide (10,478 words) [view diff] exact match in snippet view article find links to article

terbium, neodymium and dysprosium, the last two known only under matrix isolation conditions. All of the lanthanides form trihalides with fluorine, chlorine

Aluminium(I) compounds (1,776 words) [view diff] exact match in snippet view article

determined by analysis of the fine structure of the electronic spectra. Matrix isolation spectroscopy prevents disproportionation of aluminium monohalides and

Zakya Kafafi (815 words) [view diff] exact match in snippet view article find links to article

Scientific career Institutions Lehigh University National Science Foundation Thesis Infrared matrix isolation studies of the alkali-metal cyanides (1972)

Hexabromoethane (114 words) [view diff] exact match in snippet view article find links to article

decomposition of hexahaloethanes and their silicon and germanium analogs using matrix isolation, Seriya Khimicheskaya Iyer, RM; Willard, JE, (1967) Production and

Iridium (7,830 words) [view diff] exact match in snippet view article find links to article

Sr2MgIrO6 and Sr2CaIrO6. iridium(VIII) oxide (IrO4) was generated under matrix isolation conditions at 6 K in argon. The highest oxidation state (+9), which

Nanochemistry (4,456 words) [view diff] exact match in snippet view article find links to article

decades of research on this subject. This research includes the study of matrix isolation laser Raman spectroscopy, naked metal clusters chemistry and photochemistry

David Haddleton (925 words) [view diff] exact match in snippet view article find links to article

complexes for the purposes of methane activation using a combination of matrix isolation, flash photolysis and solution photochemistry. Haddleton was an ICI

Copernicium (8,623 words) [view diff] no match in snippet view article find links to article

even +6 oxidation states in CnF4 and CnF6; the latter may require matrix-isolation conditions to be detected, as in the disputed detection of HgF4. CnF4

Jeremy Burdett (1,016 words) [view diff] exact match in snippet view article find links to article

Spectroscopy. 2: 1–52. OCLC 1101442714. Burdett, Jeremy K. (1978-10-01). "Matrix isolation studies on transition metal carbonyls and related species". Coordination

Stannylene (1,329 words) [view diff] case mismatch in snippet view article find links to article

Hartwig; Minkwitz, Rolf; Watta, Barbel; Neumann, Wilhelm P. (1982). "Matrix Isolation and IR Spectroscopy of Stannylenes (CH3)2Sn and (CD3)2Sn". Tetrahedron

Neon compounds (4,155 words) [view diff] exact match in snippet view article find links to article

PMID 18193854. Manceron, L; Alikhani, M.E; Joly, H.A (March 1998). "Infrared matrix isolation and DFT study of NiN2". Chemical Physics. 228 (1–3): 73–80. Bibcode:1998CP

Chlorotrifluorosilane (1,416 words) [view diff] exact match in snippet view article find links to article

doi:10.1063/1.1748418. Ault, Bruce S. (December 1979). "Infrared matrix isolation studies of the M+SiF5- ion pair and its chlorine-fluorine analogs"

Mercury (element) (13,395 words) [view diff] exact match in snippet view article

Bridgeman, A. J.; Young, N. A. (2008). "Mercury-fluorine interactions: a matrix isolation investigation of Hg⋯F2, HgF2 and HgF4 in argon matrices". Phys Chem

Europium compounds (4,464 words) [view diff] case mismatch in snippet view article find links to article

Early Lanthanide Metal Atoms (Nd, Sm, Eu) with Water Molecules. A Matrix Isolation Infrared Spectroscopic and Theoretical Study". The Journal of Physical

Iron (16,921 words) [view diff] exact match in snippet view article find links to article

chloride, Ferrocenium tetrafluoroborate 4 (d4) Fe(diars) 2Cl2+ 2, FeO(BF4)2 5 (d3) FeO3− 4 6 (d2) Potassium ferrate 7 (d1) [FeO4]– (matrix isolation, 4K)

Nickel tetrafluoride (225 words) [view diff] case mismatch in snippet view article find links to article

"Searching for Monomeric Nickel Tetrafluoride: Unravelling Infrared Matrix Isolation Spectra of Higher Nickel Fluorides". Angewandte Chemie. 133 (12): 6461–6464

Leo Brewer (2,306 words) [view diff] exact match in snippet view article find links to article

for determining their ground electronic states. When low temperature matrix isolation was developed by George Pimentel at UC Berkeley, Brewer produced many

Isodiazene (469 words) [view diff] case mismatch in snippet view article find links to article

S2CID 250826036. Hanson, James Edward (21 June 2007). I. Matrix Isolation of 1,1-Diazenes. II. Distance, Temperature, and Dynamic Solvent Effects

Harry Hallam (academic) (637 words) [view diff] exact match in snippet view article

infrared spectroscopy of the hydrogen bond and as one of the founders of matrix isolation spectroscopy. He passed away unexpectedly on 14 May 1977. Vibrational

Iron compounds (2,753 words) [view diff] exact match in snippet view article find links to article

ferrocenium tetrafluoroborate 4 (d4) Fe(diars) 2Cl2+ 2, iron tetrafluoride 5 (d3) FeO3− 4 6 (d2) Potassium ferrate 7 (d1) [FeO4]– (matrix isolation, 4K)

Iron tetrafluoride (188 words) [view diff] no match in snippet view article find links to article

Tobias; Vent-Schmidt, Thomas; Riedel, Sebastian (26 November 2012). "A Matrix-Isolation and Quantum-Chemical Investigation of FeF 4". Angewandte Chemie International

Nickel compounds (6,313 words) [view diff] case mismatch in snippet view article find links to article

"Searching for Monomeric Nickel Tetrafluoride: Unravelling Infrared Matrix Isolation Spectra of Higher Nickel Fluorides". Angewandte Chemie International

Germylene (3,032 words) [view diff] exact match in snippet view article find links to article

(1984). "Dimethyl germylene insertion into a strained C-Ge bond and matrix isolation of tetramethyl digermene Me2Ge=GeMe2". Tetrahedron Letters. 25 (23):

Solid nitrogen (5,941 words) [view diff] case mismatch in snippet view article find links to article

George C. (1956). "Spectroscopic Studies of Reactive Molecules by the Matrix Isolation Method". The Journal of Chemical Physics. 25 (2): 224. Bibcode:1956JChPh

Main-group element-mediated activation of dinitrogen (1,355 words) [view diff] no match in snippet view article find links to article

Dailey, William P. (May 1992). "Direct observation, reactions under matrix-isolation conditions, and ab initio calculations for halo(trifluoromethyl)carbenes

Properties of metals, metalloids and nonmetals (9,191 words) [view diff] exact match in snippet view article find links to article

hydrogen peroxide; this was prepared and characterised in 1974, using a matrix isolation technique.[citation needed] Alkali metal ozonide salts of the unknown

Helium compounds (11,142 words) [view diff] case mismatch in snippet view article find links to article

S2CID 122589619. Khmelenko, V. V.; Lee, D. M.; Vasiliev, S. (3 December 2010). "Matrix Isolation of H Atoms at Low Temperatures". Journal of Low Temperature Physics

Lanthanide compounds (3,232 words) [view diff] no match in snippet view article find links to article

(2016). "Extending the Row of Lanthanide Tetrafluorides: A Combined Matrix-Isolation and Quantum-Chemical Study". Chemistry: A European Journal. 22 (7):