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Radical polymerization
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In polymer chemistry, free-radical polymerization (FRP) is a method of polymerization by which a polymer forms by the successive addition of free-radical2-Phenylethyl bromide (93 words) [view diff] exact match in snippet view article find links to article
Analogous to the preparation of most 1-bromoalkanes, it is prepared by free-radical addition of hydrogen bromide to styrene. These conditions lead to anti-MarkovnikovFluoroiodomethane (198 words) [view diff] no match in snippet view article find links to article
[dead link] Tedder, J. M.; Sloan, J. P.; Walton, J. C. (1975). "Free Radical Addition to Olefins, Part XVII. Addition of Fluoroiodomethane to Fluoroethylenes"1-Bromobutane (299 words) [view diff] exact match in snippet view article find links to article
several isomers of butyl bromide. Most 1-bromoalkanes are prepared by free-radical addition of hydrogen bromide to the 1-alkene. These conditions lead to theOrganobromine chemistry (1,557 words) [view diff] exact match in snippet view article find links to article
radical conditions, the direction of the addition can be reversed. Free-radical addition is used commercially for the synthesis of 1-bromoalkanes, precursors1-Bromohexane (178 words) [view diff] exact match in snippet view article find links to article
It is a colorless liquid. Most 1-bromoalkanes are prepared by free-radical addition of hydrogen bromide to the 1-alkene. These conditions lead to anti-MarkovnikovBulk polymerization (443 words) [view diff] no match in snippet view article find links to article
heat transfer is compounded by the highly exothermic nature of free radical addition polymerization. The polymerization is obtained with a broad molecularCopper(II) chloride (2,701 words) [view diff] no match in snippet view article
(where TBDPS = tert-butyldiphenylsilyl): CuCl2 also catalyses the free radical addition of sulfonyl chlorides to alkenes; the alpha-chlorosulfone may thenMethanedisulfonic acid (175 words) [view diff] no match in snippet view article find links to article
3-Propanedisulfonic acid Goldwhite, H.; Gibson, M.S.; Harris, C. (January 1965). "Free radical addition reactions—IV". Tetrahedron. 21 (10): 2743–2747. doi:10.1016/S0040-4020(01)98360-7Thiol-yne reaction (1,734 words) [view diff] case mismatch in snippet view article find links to article
Capella, Laura; Montevecchi, Pier Carlo; Spagnolo, Piero (1995). "Free-Radical Addition of Heteroarenethiols and Heteroarylmethanethiols to Hexyne and Phenylacetylene1-Bromododecane (173 words) [view diff] exact match in snippet view article find links to article
for biological applications. Most 1-bromoalkanes are prepared by free-radical addition of hydrogen bromide to the 1-alkene, which is 1-dodecene in theDiamantane (1,032 words) [view diff] exact match in snippet view article find links to article
n-alkanes. The mechanism for this conversion is thought to be a free-radical addition. Although this method does produce diamantane that has been alkylatedPolystyrene (8,618 words) [view diff] exact match in snippet view article find links to article
potentially other additives) are suspended in water, where they undergo free-radical addition polymerization. The polystyrene beads formed by this mechanism may1-Bromopentane (140 words) [view diff] exact match in snippet view article find links to article
product in Fucus vesiculosus. Most 1-bromoalkanes are prepared by free-radical addition of hydrogen bromide to the 1-alkene, which is 1-pentene in the caseList of gases (4,462 words) [view diff] exact match in snippet view article find links to article
(1954). "Addition of free radicals to unsaturated systems. Part VI. Free-radical addition to the nitroso-group". Journal of the Chemical Society (Resumed):