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searching for Bond dissociation energy 19 found (80 total)

alternate case: bond dissociation energy

Adenosylcobalamin (337 words) [view diff] exact match in snippet view article find links to article

the carbon-cobalt bond. This bond is exceptionally weak, with a bond dissociation energy of 31 kcal/mol, which is further lowered in the chemical environment

Hexachlorocyclohexane (435 words) [view diff] exact match in snippet view article find links to article

rather than substitution takes place, due to the very high C–H bond dissociation energy (112 kcal/mol) that disfavors abstraction of a hydrogen atom. Addition

Diazald (242 words) [view diff] exact match in snippet view article find links to article

is thermally sensitive, as a result of its weak N–NO bond whose bond dissociation energy was measured to be 33.4 kcal/mol. External MSDS, Sigma Aldrich

Nitroxyl (916 words) [view diff] exact match in snippet view article find links to article

form of nitric oxide (NO) and is isoelectronic with dioxygen. The bond dissociation energy of H−NO is 49.5 kcal/mol (207 kJ/mol), which is unusually weak

Methane functionalization (2,233 words) [view diff] exact match in snippet view article find links to article

Firstly, the C-H bond is extremely inert and non-polar, with a high bond dissociation energy, making methane a relatively unreactive starting material. Secondly

Krypton difluoride (1,534 words) [view diff] exact match in snippet view article find links to article

difluorine to atomic fluorine requires cleaving a F–F bond with a bond dissociation energy of 36 kcal/mol. Consequently, KrF2 is a good source of the extremely

Carbon–hydrogen bond (533 words) [view diff] case mismatch in snippet view article find links to article

Bond Hydrocarbon radical Molar Bond Dissociation Energy (kcal) Molar Bond Dissociation Energy (kJ) CH3−H Methyl 104 440 C2H5−H Ethyl 98 410 (CH3)2HC−H

Organopalladium chemistry (1,189 words) [view diff] exact match in snippet view article find links to article

sigma-bonded complexes. The stability of the bonds in terms of bond dissociation energy follows the trend: Pd-Alkynyl > Pd-Vinyl ≈ Pd-Aryl > Pd-Alkyl and

Disulfur decafluoride (654 words) [view diff] exact match in snippet view article find links to article

switchgear. S2F10 is also made during the production of SF6. The S-S bond dissociation energy is 305 ± 21 kJ/mol, about 80 kJ/mol stronger than the S-S bond

Butylated hydroxytoluene (2,262 words) [view diff] exact match in snippet view article find links to article

the inductive effect and the hyperconjugation effect, reduce the bond dissociation energy of the phenolic hydroxyl group, and enhance its reactivity to lipid

Carbon group (3,844 words) [view diff] exact match in snippet view article find links to article

alkyl derivatives of other groups. In the case of carbon, the high bond dissociation energy of the C–C bond and lack of electronegativity difference between

N-Hydroxyphthalimide (1,927 words) [view diff] exact match in snippet view article find links to article

acronym being PINO. It is a powerful H-atom abstracting agent. The bond dissociation energy of NHPI (i.e., PINO–H) is 88–90 kcal/mol (370–380 kJ/mol), depending

Stille reaction (5,235 words) [view diff] exact match in snippet view article find links to article

in the halogen sequence (its shorter bond length and stronger bond dissociation energy makes it more difficult to break via oxidative addition). Starting

Plumbylene (2,683 words) [view diff] exact match in snippet view article find links to article

driving force being the relief of steric strain and the low Pb-C bond dissociation energy. Plumbylenes can be used as concurrent σ-donor-σ-acceptor ligands

Water (data page) (1,857 words) [view diff] exact match in snippet view article

57.98 at 90 °C 55.33 at 100 °C Bond strength 492.215 kJ/mol O–H bond dissociation energy Bond length 95.87 pm (equilibrium) Bond angle 104.48° (equilibrium)

Coinage metal N-heterocyclic carbene complexes (2,695 words) [view diff] exact match in snippet view article find links to article

that electrostatic contributions are just one part of the overall bond dissociation energy calculations; while the Ag-NHC bonds have the greatest percentage

Phosphasilene (3,350 words) [view diff] exact match in snippet view article find links to article

Si-P-H bond angle are calculated to be 2.084 Å and 90.7o. The Si=P bond dissociation energy is 75.0 kcal mol−1 at the B97-D/6-31G(d) level of theory; while

Dispersion stabilized molecules (2,637 words) [view diff] exact match in snippet view article find links to article

investigations reveal that the silylated dimer has roughly twice the bond dissociation energy of parent diplumbene Pb2H4 despite the parent diplumbene having

Orders of magnitude (energy) (9,881 words) [view diff] exact match in snippet view article

Energy of ultraviolet light photons 10−18 atto- (aJ) 1.78×10−18 J Bond dissociation energy for the carbon monoxide (CO) triple bond, alternatively stated: