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searching for Allyl bromide 14 found (41 total)

Morris S. Kharasch (1,632 words) [view diff] exact match in snippet view article find links to article

Addition of Hydrogen Bromide to Allyl Bromide", proposed that the anti-Markovnikov addition of HBr to allyl bromide to yield 1,3-dibromopropane was due

Barbier reaction (486 words) [view diff] exact match in snippet view article find links to article

intramolecular Barbier reaction with samarium(II) iodide: the reaction of an allyl bromide with formaldehyde in THF with indium powder: The Barbier reaction is

Hydrobromic acid (481 words) [view diff] exact match in snippet view article find links to article

significant organic compounds prepared from hydrobromic acid include allyl bromide, tetrabromobis(phenol), and bromoacetic acid. HBr almost uniquely participates

Organoindium chemistry (1,124 words) [view diff] exact match in snippet view article find links to article

reaction gives mixed organoindium halides. Illustrative is the reaction of allyl bromide with a THF suspension of indium. Both monoallylindium dibromide and

Free-radical addition (893 words) [view diff] case mismatch in snippet view article find links to article

Reagents to Unsaturated Compounds. I. The Addition of Hydrogen Bromide to Allyl Bromide". Journal of the American Chemical Society. 55 (6): 2468–2496. doi:10

Double bond rule (726 words) [view diff] exact match in snippet view article find links to article

double bond. In bromoalkenes, the C–Br bond is very stable, but in an allyl bromide, this bond is very reactive. Likewise, bromobenzenes are generally inert

Diiron nonacarbonyl (753 words) [view diff] exact match in snippet view article find links to article

following reaction: Fe2(CO)9 → Fe(CO)5 + Fe(CO)4(THF) Oxidative addition of allyl bromide to diiron nonacarbonyl gives the allyl iron(II) derivaive: Fe2(CO)9

Transition-metal allyl complex (1,338 words) [view diff] exact match in snippet view article find links to article

Ni2(μ-Cl)2(η3-C3H5)2 + 8 CO A similar oxidative addition involves the reaction of allyl bromide to diiron nonacarbonyl. Oxidative addition route has been used for Mo(II)

Carbonyldiimidazole (1,043 words) [view diff] exact match in snippet view article find links to article

treated with at least 3 equivalents of an activated halide (such as allyl bromide or iodomethane) and CDI yields the corresponding halide with good yield

Corey–House synthesis (1,517 words) [view diff] exact match in snippet view article find links to article

(Kochi–Schlosser coupling). While the coupling of organocopper compounds and allyl bromide was reported as early as 1936 by Henry Gilman (Iowa State University)

Muscarine (1,882 words) [view diff] exact match in snippet view article find links to article

ether gives the aldehyde (4). Treatment of the crude aldehyde with allyl bromide and zinc powder in water with NH4Cl as catalyst resulted in an anti:syn

Proxicromil (1,590 words) [view diff] exact match in snippet view article find links to article

condensation of 6-acetyl-7-hydroxy-1,2,3,4-tetrahydronaphthalene (I) with allyl bromide (A) using of K2CO3 in DMF gives 6-acetyl-7-allyloxy-1,2,3,4-tetrahydronaphthalene

Carpanone (1,206 words) [view diff] exact match in snippet view article find links to article

anion generated after treatment of sesamol with potassium carbonate and allyl bromide, followed by a thermal Claisen rearrangement to move the O-allyl group

Bioorthogonal chemistry (5,098 words) [view diff] exact match in snippet view article find links to article

first step is Fischer indole synthesis. The product is alkylated with allyl bromide as a handle for future probe attachment; TMS is then added. Oxidation