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searching for Carbonium ion 19 found (34 total)

2-Norbornyl cation (5,919 words) [view diff] exact match in snippet view article find links to article

; Lee, Y. T. (1989). "Infrared spectroscopy of the pentacoordinated carbonium ion C 2H+ 7". Journal of the American Chemical Society. 111 (15): 5597.

Tiffeneau–Demjanov rearrangement (2,701 words) [view diff] exact match in snippet view article find links to article

1950s, it had been postulated by many that the TDR mechanism involved a carbonium ion. However, a major breakthrough in the development of the TDR mechanism

2-Acetylaminofluorene (465 words) [view diff] exact match in snippet view article find links to article

intermediate can spontaneously rearrange to form the arylamidonium ion and a carbonium ion which can interact directly with DNA to produce DNA adducts. In addition

Semustine (1,933 words) [view diff] exact match in snippet view article find links to article

become very strong electrophiles through the formation of (chloro-) carbonium ion intermediates, which are products of the hydrolysis of the semustine

Methylidynetricobaltnonacarbonyl (2,041 words) [view diff] exact match in snippet view article find links to article

the filled e set on the apex carbon. Seyferth demonstrated that the carbonium ion had the correct symmetry to accept electron density from the apex carbon

Invertase (1,144 words) [view diff] exact match in snippet view article find links to article

atom by an imidazolium cation. From there, an unstable intermediate carbonium ion will be left behind by the leaving of an alcohol group. Finally, the

Isopentenyl-diphosphate delta isomerase (1,421 words) [view diff] exact match in snippet view article find links to article

"Mechanism of action of isopentenyl pyrophosphate isomerase: evidence for a carbonium ion intermediate". Biochemistry. 25 (19): 5609–5616. doi:10.1021/bi00367a040

Arieh Warshel (1,364 words) [view diff] case mismatch in snippet view article find links to article

Reactions: Dielectric Electrostatic and Steric Stabilization of the Carbonium Ion in the Reaction of Lysozyme". J. Mol. Biol. 103 (2): 227–249. doi:10

Reductions with hydrosilanes (1,452 words) [view diff] exact match in snippet view article find links to article

1021/jo00398a039. Carey, Francis A.; Tremper, Henry S. (January 1969). "Carbonium ion-silane hydride transfer reactions. II. 2-Phenyl-2-norbornyl cation"

Lewis acids and bases (2,761 words) [view diff] exact match in snippet view article find links to article

forming AlCl−4 and creating the strongly acidic, that is, electrophilic, carbonium ion. RCl +AlCl3 → R+ + AlCl−4 A Lewis base is an atomic or molecular species

QM/MM (2,321 words) [view diff] exact match in snippet view article find links to article

reactions: dielectric, electrostatic and steric stabilization of the carbonium ion in the reaction of lysozyme". Journal of Molecular Biology. 103 (2):

Palladacycle (1,142 words) [view diff] exact match in snippet view article find links to article

Crystal structure of [PtI[MeC6H3(CH2NMe2)2-o,o']]BF4: a cyclohexadienyl carbonium ion with a .sigma.-bonded metal substituent". Journal of the American Chemical

Michael Levitt (2,515 words) [view diff] exact match in snippet view article find links to article

reactions: Dielectric, electrostatic and steric stabilization of the carbonium ion in the reaction of lysozyme". Journal of Molecular Biology. 103 (2):

2-Aminofluorene (1,125 words) [view diff] exact match in snippet view article find links to article

N-acteyl-N-acetoxyaminofluorene can form the arylamidonium ion and a carbonium ion which can interact directly with DNA. Exposure to these carcinogens

Enzyme catalysis (5,008 words) [view diff] exact match in snippet view article find links to article

reactions: dielectric, electrostatic and steric stabilization of the carbonium ion in the reaction of lysozyme". Journal of Molecular Biology. 103 (2):

Pyramidal carbocation (2,648 words) [view diff] exact match in snippet view article find links to article

(1972). "Nature of the (CH)5+ species. II. Direct observation of the carbonium ion of 3-hydroxyhomotetrahedrane derivatives". J. Am. Chem. Soc. 94 (25):

List of biophysically important macromolecular crystal structures (2,685 words) [view diff] exact match in snippet view article find links to article

reactions: Dielectric, electrostatic, and steric stabilization of the carbonium ion in the reaction of lysozyme". J Mol Biol. 103 (2): 227–49. doi:10

Force field (chemistry) (9,838 words) [view diff] exact match in snippet view article

reactions: dielectric, electrostatic and steric stabilization of the carbonium ion in the reaction of lysozyme". Journal of Molecular Biology. 103 (2):

Coarse-grained modeling (2,377 words) [view diff] exact match in snippet view article find links to article

reactions: dielectric, electrostatic and steric stabilization of the carbonium ion in the reaction of lysozyme". Journal of Molecular Biology. 103 (2):