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Longer titles found: Michael addition reaction (view), Halogen addition reaction (view)

searching for Addition reaction 85 found (176 total)

alternate case: addition reaction

Quinone (1,741 words) [view diff] exact match in snippet view article find links to article

flow batteries. Quinones undergo addition reaction to form 1,4-addition products. An example of 1,4-addition reaction is the addition of hydrogen chloride
Cativa process (373 words) [view diff] exact match in snippet view article find links to article
species (2), the fac-isomer of [Ir(CO)2(CH3)I3]−. This oxidative addition reaction involves the formal insertion of the iridium(I) centre into the carbon-iodine
Passerini reaction (1,603 words) [view diff] exact match in snippet view article find links to article
(or ketone), and a carboxylic acid to form a α-acyloxy amide. This addition reaction is one of the oldest isocyanide-based multicomponent reactions and
Scandium(III) trifluoromethanesulfonate (181 words) [view diff] exact match in snippet view article
of the scientific use of scandium triflate is the Mukaiyama aldol addition reaction between benzaldehyde and the silyl enol ether of cyclohexanone with
Polyvinyl siloxane (371 words) [view diff] no match in snippet view article find links to article
poly-vinyl siloxane, vinyl polysiloxane (VPS), or vinylpolysiloxane, is an addition-reaction silicone elastomer (an addition silicone). It is a viscous liquid
Polyaspartic esters (781 words) [view diff] exact match in snippet view article find links to article
Miles Corporation in the United States. It utilizes the aza-Michael addition reaction. These products are then used in coatings, adhesives, sealants and
Danishefsky's diene (963 words) [view diff] exact match in snippet view article find links to article
adduct is amenable to further functional group manipulations after the addition reaction. High regioselectivity is obtained with unsymmetrical alkenes with
Endothelial lipase (1,175 words) [view diff] exact match in snippet view article find links to article
dimer prior to secretion which causes dimerization to appear. The addition reaction of the same compound and molecules enhances the resistance to cleavage
Triphenylmethanol (599 words) [view diff] case mismatch in snippet view article find links to article
(2007). "The GC–MS Observation of Intermediates in a Stepwise Grignard Addition Reaction". J. Chem. Educ. 84 (4): 699. Bibcode:2007JChEd..84..699L. doi:10
Asymmetric induction (3,674 words) [view diff] exact match in snippet view article find links to article
structure is shown in Newman projection. In this case the nucleophilic addition reaction happens at the face where the hydrogen (the small group) is, producing
Thermosetting polymer (1,708 words) [view diff] exact match in snippet view article find links to article
short-chain diamine extenders – the amine-isocyanate nucleophilic addition reaction does not require catalysts. Polyureas also form when isocyanate resins
Borazine (1,683 words) [view diff] exact match in snippet view article find links to article
B3N3H9Cl3 Addition reaction of borazine with hydrogen chloride B3N3H9Cl3 + NaBH4 → (BH4N)3 Reduction with sodium borohydride The addition reaction with bromine
Triflate (597 words) [view diff] exact match in snippet view article find links to article
reactions and Diels–Alder reactions. An example is the Mukaiyama aldol addition reaction between benzaldehyde and the silyl enol ether of cyclohexanone with
Pinnick oxidation (1,146 words) [view diff] exact match in snippet view article find links to article
one can take advantage of the propensity of HOCl to undergo this addition reaction by adding a sacrificial alkene-containing chemical to the reaction
Ozonide (642 words) [view diff] exact match in snippet view article find links to article
{\ce {(RO)3PO3 -> (RO)3PO + ^{1}O2}}} Molozonides are formed by the addition reaction between ozone and alkenes. They are rarely isolated during the course
Ullmann condensation (800 words) [view diff] exact match in snippet view article find links to article
In the case of C-N coupling, kinetic studies implicate oxidative addition reaction followed by reductive elimination from Cu(III) intermediates (Ln =
Hydrogen bromide (853 words) [view diff] exact match in snippet view article find links to article
in the production of organobromine compounds. In an electrophilic addition reaction, HBr adds to alkenes: RCH=CH2 + HBr → R−CHBr−CH3 The resulting alkyl
Mesembrine (712 words) [view diff] exact match in snippet view article find links to article
α-allylation for synthesis of the quaternary carbon, and conjugate addition reaction for the final five-membered ring closure. The final product from this
Monosaccharide (2,059 words) [view diff] exact match in snippet view article find links to article
acyclic (open-chain) form to a cyclic form, through a nucleophilic addition reaction between the carbonyl group and one of the hydroxyl groups of the same
Mercury(II) sulfate (841 words) [view diff] exact match in snippet view article
catalysts in oxymercuration-demercuration, a type of electrophilic addition reaction which results in hydration of an unsaturated compound. The hydration
Ketone (2,948 words) [view diff] no match in snippet view article find links to article
lesser number of carbon atoms than the parent ketone. Electrophilic addition, reaction with an electrophile gives a resonance stabilized cation With phosphonium
Maleic acid (787 words) [view diff] exact match in snippet view article find links to article
bromine into a bromine radical, which attacks the alkene in a radical addition reaction to a bromo-alkane radical; and now single bond rotation is possible
Aldol (519 words) [view diff] exact match in snippet view article find links to article
of other compounds. Aldols are usually synthesized from an aldol addition reaction using two aldehydes or an aldehyde and a ketone for a ketol. These
Condenser (heat transfer) (1,433 words) [view diff] exact match in snippet view article
condensation reaction which links two fragments into a single molecule by an addition reaction and an elimination reaction. In laboratory distillation, reflux, and
Proline organocatalysis (1,841 words) [view diff] exact match in snippet view article find links to article
Claudio (15 July 2005). "Current Progress in the asymmetric aldol addition reaction". Chem. Soc. Rev. 33 (2): 65–75. doi:10.1039/b202901d. PMID 14767502
Dysprosium acetylacetonate (425 words) [view diff] exact match in snippet view article find links to article
acetonitrile. Dysprosium acetylacetonate can be used to catalyze the addition reaction of norbornene and carbon tetrachloride. The dihydrate has been characterized
Ylide (1,152 words) [view diff] exact match in snippet view article find links to article
found to react as nucleophiles in SN2' substitution: The initial addition reaction is followed by an elimination reaction. 1,3-dipole Betaine: a neutral
Ethenone (1,486 words) [view diff] exact match in snippet view article find links to article
cumulative double bonds, ethenone is highly reactive and reacts in an addition reaction H-acidic compounds to the corresponding acetic acid derivatives. It
Troparil (1,036 words) [view diff] case mismatch in snippet view article find links to article
Derivatives. Enhanced Stereoselectivity Observed for the Conjugate Addition Reaction of Phenylmagnesium Bromide Derivatives with Anhydro Dichloromethane"
1,1,1,2-Tetrachloroethane (145 words) [view diff] exact match in snippet view article find links to article
2-tetrachloroethane. 1,1,1,2-Tetrachloroethane can be obtained by a two-step addition reaction of acetylene with chlorine (via dichloroethene), but this mainly produces
Hydrogen chloride (2,805 words) [view diff] exact match in snippet view article find links to article
Hydrochloride, organic salts of hydrochloric acid Hydrochlorination, addition reaction with alkenes "hydrogen chloride (CHEBI:17883)". Chemical Entities
2,2,6,6-Tetramethylpiperidine (246 words) [view diff] exact match in snippet view article find links to article
synthesis of TMP have been reported. One method starts with a conjugate addition reaction of ammonia to phorone. The intermediate triacetone amine is then reduced
WIN-35428 (1,004 words) [view diff] exact match in snippet view article find links to article
derivatives. Enhanced stereoselectivity observed for the conjugate addition reaction of phenylmagnesium bromide derivatives with anhydro dichloromethane"
Arthur Michael (658 words) [view diff] case mismatch in snippet view article find links to article
ca. Retrieved 2023-08-06. "Arthur Michael (1853–1942): The Michael Addition Reaction". Thieme. 15 October 2021. Retrieved 5 September 2023. Brief biography
Tetrasulfur tetranitride (1,355 words) [view diff] exact match in snippet view article find links to article
reacts with Vaska's complex ([Ir(Cl)(CO)(PPh3)2] in an oxidative addition reaction to form a six coordinate iridium complex where the S4N4 binds through
Chupícuaro (1,950 words) [view diff] exact match in snippet view article find links to article
family members. Maya blue is a blue/indigo pigment resulting from an addition reaction between indigo and clay, which was widely used in pre-Columbian Mesoamerica
Chupícuaro (1,950 words) [view diff] exact match in snippet view article find links to article
family members. Maya blue is a blue/indigo pigment resulting from an addition reaction between indigo and clay, which was widely used in pre-Columbian Mesoamerica
Albright–Goldman oxidation (281 words) [view diff] exact match in snippet view article find links to article
to form a sulfonium ion. It reacts with the primary alcohol in an addition reaction. Furthermore, acetic acid is cleaved, so that intermediate 2 is formed
Chlorethoxyfos (1,945 words) [view diff] exact match in snippet view article find links to article
pentachloride. Phosphorus chloride is added to the chloral via an addition reaction. The double bond of chloral (with which the oxygen is bound) becomes
Enantioselective synthesis (4,724 words) [view diff] exact match in snippet view article find links to article
An energy profile of an enantioselective addition reaction.
James P. Collman (486 words) [view diff] exact match in snippet view article find links to article
as well as original research, his group popularized the oxidative addition reaction, leading to the discovery of new low-valent complexes including Ru(CO)3(PPh3)2
Diphosphenes (2,521 words) [view diff] exact match in snippet view article find links to article
transition-metal: Similar to the ring-formation behavior in the carbene addition reaction of C=C double bonds, diphosphene can form a P-C-P three-membered ring
Kharasch addition (414 words) [view diff] exact match in snippet view article find links to article
chemical reactions for the Kharasch addition reaction of chloroform to a terminal alkene.
Wacker process (3,872 words) [view diff] exact match in snippet view article find links to article
also yielded products that inferred nucleophilic attack was an anti-addition reaction. Kinetic studies were conducted on isotopically substituted allyl
Glucose (12,979 words) [view diff] exact match in snippet view article find links to article
arises from the open-chain form by an intramolecular nucleophilic addition reaction between the aldehyde group (at C-1) and either the C-4 or C-5 hydroxyl
Sulfur chloride pentafluoride (306 words) [view diff] exact match in snippet view article find links to article
reaction occurs with propene: CH 3CH=CH 2 + SF 5Cl → CH3CHClCH2SF5 The addition reaction is catalyzed by (CH3CH2)3B at around −30 °C. SF5Br is used similarly
RTV silicone (781 words) [view diff] no match in snippet view article find links to article
condensation curing. Two-part silicones can also be platinum catylized in a "addition" reaction. Other reactive species to facilitate cross-linking include acetoxy
Migratory insertion (2,262 words) [view diff] exact match in snippet view article find links to article
above, includes both insertion and de-insertion steps. The oxidative addition reaction of methyl iodide with (1) involves the formal insertion of the iridium(I)
Cyclopentenone prostaglandins (3,059 words) [view diff] exact match in snippet view article find links to article
This results in the addition of the PG to the protein by a Michael addition reaction and important modifications in the activity of target proteins that
Diethyl maleate (551 words) [view diff] exact match in snippet view article find links to article
dialkyl maleate - usually diethyl maleate - utilizing the Michael addition reaction. These products are then used in coatings, adhesives, sealants and
Thomas J. Kealy (490 words) [view diff] exact match in snippet view article find links to article
chemist for DuPont in Delaware. His published research includes the addition reaction of phenols with ethylene, the chemistry of allene (propadiene, H2C=C=CH2)
(+)-CPCA (4,044 words) [view diff] exact match in snippet view article
derivatives. Enhanced stereoselectivity observed for the conjugate addition reaction of phenylmagnesium bromide derivatives with anhydro dichloromethane"
3-Arylpropiolonitriles (559 words) [view diff] exact match in snippet view article find links to article
the payload in the blood circulation due to reversibility of the addition reaction between maleimide moiety and cysteine residue of a protein (retro
Macrophomic acid (540 words) [view diff] exact match in snippet view article find links to article
Michael-aldol sequence. The Michael-aldol sequence involves a Michael addition reaction and an aldol condensation. The actual pathway is not yet understood
Hammett equation (4,056 words) [view diff] exact match in snippet view article find links to article
non-leaving group can in fact accelerate the rate of the nucleophilic addition reaction when X is an EWG. This is attributed to the resonance contribution
Thiol-ene reaction (2,808 words) [view diff] exact match in snippet view article find links to article
Basic schematic of thiol-ene addition reaction
Insertion reaction (1,867 words) [view diff] exact match in snippet view article find links to article
above, includes both insertion and de-insertion steps. The oxidative addition reaction of methyl iodide with (1) involves the formal insertion of the iridium(I)
Organozinc chemistry (3,394 words) [view diff] exact match in snippet view article find links to article
Danishefsky's synthesis of cycloproparadicicol. By using the organozinc addition reaction conditions the other functionality of the dienone and the alkyne are
Captodative effect (1,312 words) [view diff] exact match in snippet view article find links to article
reactions was observed. The process studied was: The rate of the addition reaction was accelerated by the following EDGs in increasing order: H < CH3 < OCH2CH3
Nitroethylene (844 words) [view diff] exact match in snippet view article find links to article
bond, nitroethylene can serve as a Michael acceptor in a Michael addition reaction. A typical Michael donor (i.e. ketone or aldehyde) can be used. Like
Shi epoxidation (1,183 words) [view diff] exact match in snippet view article find links to article
The first step in the catalytic cycle reaction is the nucleophilic addition reaction of the oxone with the ketone group on the catalyst (intermediate 1)
Erysodienone (495 words) [view diff] exact match in snippet view article find links to article
forms the diphenoquinone intermediate E. An intramolecular Michael addition reaction converts E to the final product, erysodienone. A biomimetic synthesis
Asymmetric addition of alkenylmetals to aldehydes (335 words) [view diff] exact match in snippet view article find links to article
synthesis of muscone. (b) Detailed steps for the reaction. Structure of the ligand and the proposed transition state for the key addition reaction are shown.
Thermodynamic versus kinetic reaction control (2,751 words) [view diff] exact match in snippet view article find links to article
largely mirrors the deprotonation equilibrium. The electrophilic addition reaction of hydrogen bromide to 1,3-butadiene above room temperature leads
Dibutyl maleate (276 words) [view diff] exact match in snippet view article find links to article
maleate but also dibutyl maleate may be used- utilizing the Michael addition reaction. The resulting products, polyaspartic esters products are then used
Cyproterone acetate (13,370 words) [view diff] exact match in snippet view article find links to article
[2668-75-9] (3). Reacting this with diazomethane results in a 1,3-dipolar addition reaction at C1–C2 of the double bond of the steroid system, which forms a derivative
Phosphetene (2,187 words) [view diff] exact match in snippet view article find links to article
synthetic intermediate discovered by Schmidpeter et al. in 1996 from the addition reaction of 1,3-diphosphoniopropenide with chlorophosphines. The synthesis
Vinylsulfonic acid (601 words) [view diff] exact match in snippet view article find links to article
bond of vinylsulfonic acid reacts readily with nucleophiles in an addition reaction. 2-Aminoethanesulfonic acid is formed with ammonia and 2-methylaminoethanesulfonic
Michael Peak (513 words) [view diff] case mismatch in snippet view article find links to article
ca. Retrieved 2021-05-20. "Arthur Michael (1853–1942): The Michael Addition Reaction" (PDF). Retrieved 2021-05-20. Gadd, Ben (2008), Geology of the Rocky
Trisilaallene (1,551 words) [view diff] exact match in snippet view article find links to article
to generate dialkoxytrisilane. The regioselectivity of the alcohol addition reaction depends on the type of substituents. In 2007, Kira et al. reported
Kalkitoxin (2,902 words) [view diff] exact match in snippet view article find links to article
carrying the 4-phenyl-2-oxazolidinone, an organocopper conjugate addition reaction was used instead. This was done specifically by connecting the organocopper
Liu Ruozhuang (658 words) [view diff] case mismatch in snippet view article find links to article
Jin; R. Z. Liu (1984). "Quantum Chemical Study of the Electrophilic Addition Reaction of Iodine to Ethylene". Int. J. Quantum Chem. 25 (4): 699–705. doi:10
Lewis acid catalysis (5,017 words) [view diff] exact match in snippet view article find links to article
supported by a chiral phosphoramidite ligand for a conjugate carbonyl addition reaction. The second reaction, from the synthesis of ent-hyperforin, uses an
Metal–organic framework (21,288 words) [view diff] exact match in snippet view article find links to article
shown to have a similar catalytic efficiency for the diethylzinc addition reaction as compared to the homogeneous analogue when was pretreated by Ti(OiPr)4
3,9-Divinyl-2,4,8,10-tetraoxaspiro(5.5)undecane (1,011 words) [view diff] exact match in snippet view article
and acids, such as ethanoic acid, can be added in a nucleophilic addition reaction to the allylic double bonds of 3,9-divinyl-2,4,8,10-tetraoxaspiro[5
Cycloparaphenylene (2,667 words) [view diff] exact match in snippet view article find links to article
exchange with p-diiodobenzene followed by a two-fold nucleophilic addition reaction with 1,4-benzoquinone yielded a syn-cyclohexadiene moiety. Borylation
Tissue engineering of heart valves (3,690 words) [view diff] exact match in snippet view article find links to article
various reaction such as free radical polymerization or conjugate addition reaction. Hydrogels are beneficial because they have a high water content,
Methane functionalization (2,164 words) [view diff] exact match in snippet view article find links to article
hydrogen (Figure 5). Similar to sigma bond metathesis is the 1,2 addition reaction, where a four-membered transition state is also formed. However, a
Chao-Jun Li (1,308 words) [view diff] case mismatch in snippet view article find links to article
States (1992–1994) (and discovered the so-called phosphine-catalyzed γ-Addition Reaction). C.-J. Li started as an assistant professor at Tulane University
Function-spacer-lipid Kode construct (3,722 words) [view diff] exact match in snippet view article find links to article
maleimide residue of the FSL (through the well-known Michael nucleophilic addition reaction). Following overnight incubation then vacuum drying, an FSL peptide
Borylene (2,851 words) [view diff] exact match in snippet view article find links to article
bonds, yielding products analogous to an organometallic oxidative addition reaction. Most commonly, these are generated via reduction of an organoborane
Cynaropicrin (2,769 words) [view diff] exact match in snippet view article find links to article
group of the Cys115 in the bacterial enzyme MurA through Michael addition reaction. The unsaturated ester side chain of cynaropicrin appears to mimic
Self-healing hydrogels (3,603 words) [view diff] exact match in snippet view article find links to article
crosslinking agents react with monomer functional groups in a stepwise addition reaction. Condensation polymerization is the second type of step growth polymerization
Biosynthesis of doxorubicin (3,451 words) [view diff] exact match in snippet view article find links to article
fourth ring cyclase (AAME cyclase), catalyzes an intramolecular aldol addition reaction. No cofactors are required and neither aromatization nor dehydration
D-Ribose pyranase (1,588 words) [view diff] exact match in snippet view article find links to article
electron donating group, the pyranose ring opens. Next, a nucleophilic addition reaction occurs. Lastly, a deprotonation takes place, leaving the newly formed